Phenylmagnesium bromide 溴化苯基镁

CAS 100-58-3 MFCD00000038

化学结构图

100-58-3
SMILES: Br[Mg]C1CCCCC1

化学属性

Mol. FormulaC6H5BrMg
Mol. Weight181.32
Density1.161
TSCAYes
Flash Point-11 ºC
Solubility起反应
Stability对空气敏感,对湿度敏感
Mol. FormulaC{6}H{5}BrMg
Mol. Weight181
Appearance liq.
Stabilityair sensitive, moisture sensitive

别名和识别编码

Chemical NamePhenylmagnesium bromide
CAS Number100-58-3
EC Number250-023-7
Beilstein Registry Number3588849
Reaxys-RN606081
PubChem Substance ID160871258
MDL NumberMFCD00000038
Synonym 苯基溴化镁, 3M IN ETHER, PACKAGED UNDER ARGON IN RESEALABL 苯基溴化镁[浸在乙醚中的] PHENYLMAGNESIUM BROMIDE SOL., ~3 M IN DI ETHYL ETHER phenylmagnesium bromide, 3m in ether, packaged under argon in resealable chemseal Phenylmagnesium bromide, 1M solution in THF 苯基溴化镁; 溴化苯基镁 Phenylmagnesium Bromide (32% in Tetrahydrofuran, ca. 2mol/L) Phenylmagnesium Bromide 3.0 M In Diethyl Ether bromophenylmagnesium Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSealTM bottles Magnesium, bromophenyl- PHENYLMAGNESIUM BROMIDE, 3.0M SOLUTION I N DIETHYL ETHER Phenyl magnesium bromide(in ethyl ether) 溴化苯基镁 phenylmagnesiumbromidesolution PhMgBr solution Phenylmagnesium bromide, 2.8M solution in Diethyl ether PHENYLMAGNESIUM BROMIDE, 1.0-1.2M in TETRAHYDROFURAN PHENYLMAGNESIUM BROMIDE, 1.0M SOLUTION I N TETRAHYDROFURAN 溴化苯鎂 苯基溴化镁 溶液 苯基溴化镁, 3M IN ETHER PHENYLMAGNESIUM BROMIDE SOLUTION, ~1 M I N THF PHENYLMAGNESIUM BROMIDE Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal bottles Phenylmagnesiumbromide,3Minether bromophenyl-magnesiu Phenylmagnesium Bromide 1.0 M In Tetrahydrofuran 苯基溴化镁
Chemical Name Translation溴化苯基镁
InChIKeyANRQGKOBLBYXFM-UHFFFAOYSA-M
LabNetwork Molecule IDLN00222974
InChIInChI=1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q-1;;+2/p-1
MDL NumberMFCD00000038
CAS Number100-58-3
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分类

  • {SNA} 12 Principles Aligned Products, Aryl, Chemical Synthesis, Greener Alternative Products, Grignard Reagents, Organometallic Reagents, Synthetic Reagents
  • {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

产品应用

  • 用作芳基格利雅试剂。
  • 相关化学反应 (1)苯基溴化镁与三氯化铁反应,得到偶联产物.环戊二烯基溴化镁与三氯化铁反应得到二茂铁。
  • (2)与三氯化铬在乙醚中反应生成二苯铬。
  • (3)六苯基二铅用作聚苯醚润滑剂的抗氧剂,可由氯化铅与苯基锂或苯基溴化镁反应而得。
  • (4)以四氢呋喃为溶剂,将溴化苯基镁和氯化锗反应而得四苯基锗烷。
  • (5)由氯化铅与苯基溴化镁(或苯基锂)在碘代苯存在下经低温反应而得四苯基铅。
  • (6)四苯硼钠主要用于钾离子、铵离子、铷离子和铯离子的测定,可由苯基溴化镁与三氟化硼/乙醚作用先生成溴化四苯硼镁。

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S8 Keep container dry 保持容器干燥;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P231+P232
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
UN Number 2924 UN2924
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
Storage condition 密封充氩保存 water-free area Air & Moisture Sensitive Light, Air & Moisture Sensitive
Hazard Codes 3 F,C
Hazard Class3/8
Warnings 危化品目录(2015)

其他信息

  • 避免与氧化剂、酸、光、水接触。 储存于阴凉、通风的库房。远离火种、热源、水源、防静电。应与氧化剂、酸性物质分开存放,切忌混储。密封保存。储存在暗处。采用防爆型 照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备和合适的收容材料。

系列性分类