Anisole 苯甲醚

CAS 100-66-3 MFCD00008354

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI 377816
Anisole 苯甲醚
99%, SpcDry, Water≤50 ppm (by K.F.), SpcSeal 100mL 110
LN-CN
中国国内现货 96-99 %
INFI 377816
Anisole 苯甲醚
99%, SpcDry, Water≤50 ppm (by K.F.), SpcSeal 500mL 270
LN-CN
中国国内现货 96-99 %
INFI 377816
Anisole 苯甲醚
99%, SpcDry, Water≤50 ppm (by K.F.), SpcSeal 1L 490
96-99 %
INFI 440705
Anisole 苯甲醚
99%, SpcDry, with molecular sieves, Water≤50 ppm (by K.F.), SpcSeal 100mL 110
LN-CN
中国国内现货 96-99 %
INFI 440705
Anisole 苯甲醚
99%, SpcDry, with molecular sieves, Water≤50 ppm (by K.F.), SpcSeal 500mL 270
LN-CN
中国国内现货 96-99 %
INFI 440705
Anisole 苯甲醚
99%, SpcDry, with molecular sieves, Water≤50 ppm (by K.F.), SpcSeal 1L 490
LN-CN
中国国内现货 96-99 %
INFI 571998
Anisole 苯甲醚
99% 100mL 50
96-99 %
INFI 571998
Anisole 苯甲醚
99% 500mL 110
96-99 %
Innochem 568802
Anisole 苯甲醚
99%, Extra dry, Water≤50 ppm (by K.F.), resealable bottle 100mL 230
96-99%
Innochem 568802
Anisole 苯甲醚
99%, Extra dry, Water≤50 ppm (by K.F.), resealable bottle 500mL 490
96-99%
Innochem 568802
Anisole 苯甲醚
99%, Extra dry, Water≤50 ppm (by K.F.), resealable bottle 1L 680
96-99%
Innochem 568803
Anisole 苯甲醚
99%, Extra dry, with molecular sieves, Water≤50 ppm (by K.F.), resealable bottle 100mL 240
96-99%
Innochem 568803
Anisole 苯甲醚
99%, Extra dry, with molecular sieves, Water≤50 ppm (by K.F.), resealable bottle 500mL 520
96-99%
Innochem 568803
Anisole 苯甲醚
99%, Extra dry, with molecular sieves, Water≤50 ppm (by K.F.), resealable bottle 1L 710
96-99%
Innochem 570818
Anisole
99% 100mL 55
BJ-CN
中国国内现货 96-99%
Innochem 570818
Anisole
99% 250mL 110
BJ-CN
中国国内现货 96-99%
Innochem 570818
Anisole
99% 500mL 180
BJ-CN
中国国内现货 96-99%
Innochem 571848
99% 250mL 110
96-99%
TCI 99639
Anisole >
>99.0%(GC) 25g 105
SH-CN TK-JP
中国国内现货 99
TCI 99639
Anisole >
>99.0%(GC) 500g 400
SH-CN TK-JP
中国国内现货 99
Alfa 99642
Anisole
99% 500g 294
SH-CN BJ-CN CN
中国国内现货 99
Alfa 99642
Anisole
99% 2500g 1,073
SH-CN CN
中国国内现货 99
Alfa 99642
Anisole
99% 10000g 2,108
CN
中国国内现货 99
J&K 99638
Anisole, 99%
99% 250mL 168
HB
中国国内现货 99
J&K 99638
Anisole, 99%
99% 1L 553
HB
中国国内现货 99
J&K 402637
Anisole, 99.7%, SuperDry, water≤20 ppm, J&KSeal;
99.7% 100mL 804
HB
中国国内现货 99e1
J&K 402637
Anisole, 99.7%, SuperDry, water≤20 ppm, J&KSeal;
99.7% 1L 1,319
HB
中国国内现货 99e1
J&K 402637
Anisole, 99.7%, SuperDry, water≤20 ppm, J&KSeal;
99.7% 2.5L 2,199
HB
中国国内现货 99e1
Acros 99640
Anisole, 99%, pure
5mL 215
SH-CN CN
中国国内现货 0
Acros 99640
Anisole, 99%, pure
250mL 418
SH-CN BJ-CN CN
中国国内现货 0
Acros 99640
Anisole, 99%, pure
1L 1,192
SH-CN CN
中国国内现货 0
Acros 99640
Anisole, 99%, pure
2.5L 660
SH-CN CN
中国国内现货 0
Fluka 247381
Anisole
analytical standard 5mL 590
0
Fluka 375238
pharmaceutical secondary standard; traceable to USP 3x1.2mL 697
0
Aladdin 399547
Anisole 苯甲醚
Standard for GC,≥99.5%(GC) 5mL 56
CN-SH
中国国内现货 99e1
Aladdin 399548
苯甲醚
≥99%,FCC 500mL 89
99
Aladdin 399548
苯甲醚
≥99%,FCC 2.5kg 398
99
Aladdin 399548
苯甲醚
≥99%,FCC 10kg 1,290
99
Aladdin 399548
苯甲醚
≥99%,FCC 25kg 2,580
99
Aladdin 399549
苯甲醚
CP,98% 500mL 79
CN-SH
中国国内现货 99
Aladdin 399550
Anisole 苯甲醚
AR,99% 25g 30
CN-SH
中国国内现货 99
Aladdin 399550
Anisole 苯甲醚
AR,99% 100mL 45
CN-SH
中国国内现货 99
Aladdin 399550
Anisole 苯甲醚
AR,99% 500mL 66
CN-SH
中国国内现货 99
Aladdin 399550
Anisole 苯甲醚
AR,99% 2.5L 399
CN-SH
中国国内现货 99
Aladdin 399550
Anisole 苯甲醚
AR,99% 10L 1,276
99
Aladdin 399551
Anisole 苯甲醚
99.7%,无水级 100mL 277
CN-SH
中国国内现货 99e1
Aladdin 399551
Anisole 苯甲醚
99.7%,无水级 1L 733
CN-SH
中国国内现货 99e1
Aladdin 399552
Anisole 苯甲醚
分析标准品,≥99.9%(GC) 5mL 394
CN-SH
中国国内现货 99e1
Acros 402075
AcroSeal? 1L 1,296
0
Acros 407374
AcroSeal? 100mL 686
0
Acros 449479
Anisole, 99%, Extra Dry, AcroSeal?
99% 100mL 178
CN
中国国内现货 0
Acros 449479
Anisole, 99%, Extra Dry, AcroSeal?
99% 1L 1,102
0
Adamas 449480
99%+ 25g 30
SH-CN CN
中国国内现货 99
Adamas 449481
99%+ 100g 66
SH-CN
中国国内现货 99
Adamas 449482
99%+ 500mL 110
SH-CN CN
中国国内现货 99
SIAL 449483
99.7% anhydrous, 99.7% 100mL 1,060
99e1
SIAL 449484
ReagentPlus(R), 99% 100mL 706
99
SIAL 449485
99.7% anhydrous, 99.7% 1L 1,432
99e1
SIAL 449486
99% ReagentPlus?, 99% 1L 1,432
99
SIAL 449487
99.7% anhydrous, 99.7% 2L 2,022
99e1
SIAL 449488
99% ReagentPlus?, 99% 2.5L 2,183
99
SIAL 449489
ReagentPlus?, 99% 20L 691
99
SIAL 449490
99% ReagentPlus?, 99% 250mL 691
99
SIAL 449491
ReagentPlus(R), 99% 4L 3,333
99
TRC 449492
Anisole
250g 1,540
0
TRC 449492
Anisole
500g 1,750
0
TRC 449492
Anisole
1000g 2,800
0
Energy-chemical 488778
Anisole 苯甲醚
99%, Extra Dry,with molecular sieves, Water≤50 ppm (by K.F.), Energyseal 100mL 108
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 488778
Anisole 苯甲醚
99%, Extra Dry,with molecular sieves, Water≤50 ppm (by K.F.), Energyseal 500mL 295
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 488778
Anisole 苯甲醚
99%, Extra Dry,with molecular sieves, Water≤50 ppm (by K.F.), Energyseal 1L 545
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 488779
Anisole 苯甲醚
99% 100mL 45
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 488779
Anisole 苯甲醚
99% 500mL 78
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 488779
Anisole 苯甲醚
99% 20L 1,670
CN-SH
中国国内现货 99
HY 518284
Anisole 苯甲醚
99%, HyDry, Water≤50 ppm (by K.F.), HySeal 100mL -
99
HY 518284
Anisole 苯甲醚
99%, HyDry, Water≤50 ppm (by K.F.), HySeal 500mL -
99
HY 518284
Anisole 苯甲醚
99%, HyDry, Water≤50 ppm (by K.F.), HySeal 1L -
99
HY 518340
Anisole 苯甲醚
99%, HyDry, with molecular sieves, Water≤50 ppm (by K.F.), HySeal 100mL -
99
HY 518340
Anisole 苯甲醚
99%, HyDry, with molecular sieves, Water≤50 ppm (by K.F.), HySeal 500mL -
99
HY 518340
Anisole 苯甲醚
99%, HyDry, with molecular sieves, Water≤50 ppm (by K.F.), HySeal 1L -
99
TRC 538685
Anisole
250g 1,320
TRC 538685
Anisole
500g 1,500
TRC 538685
Anisole
1000g 2,400
Meryer 559528
苯甲醚
分析标准品,99.9% 5mL 461
99e1%
Acros 591632
99% 100mL 522
96-99%
Acros 591632
99% 1L 888
96-99%
Aldrich 606865
250mL 691
Aldrich 606865
1L 1,432
Aldrich 606865
2.5L 2,183
Aldrich 606869
100mL 1,060
Aldrich 606869
1L 1,432
Aldrich 606869
2L 2,022
Aldrich 606876
3x1.2mL 732
Aladdin 627779
1L 449
Aladdin 627780
100mL 108
Aladdin 627781
500mL 67
Aladdin 627782
2.5L 399
Aladdin 627783
5mL 57
Aladdin 627784
5mL 402
3A 633263
Anisole 苯甲醚
99% 100ml -
96-99 %
3A 633263
Anisole 苯甲醚
99% 500ml -
96-99 %
3A 634447
Anisole 苯甲醚
99%, SpcDry, Water≤50 ppm (by K.F.), SpcSeal 100ml 110
96-99 % water 50 ppm
3A 634447
Anisole 苯甲醚
99%, SpcDry, Water≤50 ppm (by K.F.), SpcSeal 500ml 270
96-99 % water 50 ppm
3A 634447
Anisole 苯甲醚
99%, SpcDry, Water≤50 ppm (by K.F.), SpcSeal 1L 490
96-99 % water 50 ppm

分类

  • Amber Glass Bottles, Building Blocks, C2 to C8, Chemical Synthesis, Ethers,
  • {Chemicalbook} 食品添加剂: 食用香料(增香剂): 天然等同香料和人造香料
  • {SNA} A - D, A-B, A-D, Alphabetical Listings, Certified Food Grade Products, Flavors and Fragrances, Follows IFRA Guidelines, Halal Certified Products, Kosher Certified Products
  • {SNA} A-B, A-F, Additional Standards, Alpha Sort, Analytical Standards,
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ether; 1fragment
  • {SNA} Anhydrous Solvents, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents, Sure/Seal Bottles
  • {SNA} Amber Glass Bottles,

产品应用

  • A biochemical for proteomics research.

相关文献及参考

  • Merck:14,669 Beilstein:6(4)548
  • The rate of ortho-lithiation of anisole is accelerated dramatically in the presence of TMEDA, effective also in sub-stoichiometric amounts: Tetrahedron Lett., 35, 385 (1994). For discussion of the mechanism of ortho-lithiation, see: J. Org. Chem., 62, 3024 (1997). Although direct dilithiation with n-BuLi/TMEDA was unsuccessful, a sequence involving monolithiation, silylation and further lithiation at the 6-position gave the 2,6-disilyl derivative in 72% yield: J. Org. Chem., 49, 4657 (1984).
  • Merck:14,669
  • Short: II/19b
  • Widely used as a carbocation scavenger in the deblocking of, e.g. N-Boc or N-Cbz (Z) peptides with acidic reagents. Addition of anisole removes t-butyl or benzyl cations from the reaction mixture; see, e.g.: J. Chem. Soc., Chem. Commun., 922 (1976); Chem. Pharm. Bull., 25, 2929 (1977); Chem. Ber., 101, 3649 (1968).

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment
  • Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P305+351+338+337+313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261305+351+338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+313 IF SKIN irritation occurs: Get medical advice/attention. 如果发生皮肤刺激:获取医疗咨询/就医。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P337+313 IF eye irritation persists: Get medical advice/attention. 如果眼睛刺激持续:获取医疗咨询/就医。
  • P302+352+332+313+362+364
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P301+310+331
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P304+340+311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P304+340+312
Signal word
Safety Statements
Risk Statements
  • R10 Flammable 易燃
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
RTECSBZ8050000
UN Number
Packing GroupIII
Hazard Codes
  • Xn
Storage condition
  • Store at RT.
  • 密封保存。
  • 密封避光保存。
Hazard Class3
Warnings
  • 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3700 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Gastrointestinal - changes in structure or function of salivary glands
   Kidney, Ureter, Bladder - hematuria
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   6,378,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2800 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - excitement
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 88,400,1946

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5000 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 28(6),43,1984

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 25 umol/L
REFERENCE :
   RCOCB8 Research Communications in Chemical Pathology and Pharmacology. (PJD
   Pub. Ltd., P.O. Box 966, Westbury, NY 11590)  V.1-    1970-
   Volume(issue)/page/year: 54,133,1986

其他信息

  • 下游产品:1-甲基-4-咪唑甲酸 --> 4-(羟甲基)咪唑 --> 咪唑-4,5-二羧酸 --> 1-甲基-1H-咪唑-5-甲酸 --> 头孢地尼 --> 1,5-二氮杂双环[4.3.0]壬-5-烯 --> 1-甲基-1H-咪唑-4,5-二羧酸 --> 诱惑红 --> 敌菌净 --> 头孢布烯 --> 2-肼基甲基吡啶 --> 1H-咪唑-4-甲酸 --> 甲基多巴 --> 1-甲基-1H-咪唑-4,5-二甲腈 --> 吡啶-3-亚甲基肼,1-(3-吡啶基)甲基肼 --> 劳森试剂 --> 6-羟基-1-萘甲酸 --> 分散兰BGL --> 1-[4-(4-氨基-6,7-二甲氧基喹唑啉-2-基)-1,4-二氮杂环庚烷-1-基]丁-1-酮盐酸盐 --> 跟踪,示踪,微量 --> 间-油酰氨基-邻-甲氧基苯磺酸钠,净洗剂MA,洗净剂SL -
  • 用途四:用于有机合成,也用作溶剂、香料和驱虫剂。
  • {
  • 毒性分级:中毒
  • {Chemical
  • 常规方法:用铁桶内衬塑料袋包装。每桶净重100kg。贮存于阴凉、通风处。防潮、防晒。按有毒化学品规定贮运。
  • 图谱信息:苯甲醚(100-66-3)红外图谱(IR2) 苯甲醚(100-66-3)核磁图( 13 CNMR) 苯甲醚(100-66-3)质谱(MS) 苯甲醚(100-66-3)Ram
  • Acros Organics:苯甲醚 Anisole, extra pur
  • 下游产品:1-甲基-4-咪唑甲酸 --> 4-(羟甲基)咪唑 --> 咪唑-4,5-二羧酸 --> 1-甲基-1H-咪唑-5-甲酸 --> 头孢地尼 --> 1,5-二氮杂双环[4.3.0]壬-5-烯 --> 1-甲基-1H-咪唑-4,5-二羧酸 --> 诱惑红 --> 敌菌净 --> 头孢布烯 --> 2-肼基甲基吡啶 --> 1H-咪唑-4-甲酸 --> 甲基多巴 --> 1-甲基-1H-咪唑-4,5-二甲腈 --> 吡啶-3-亚甲基肼,1
  • TCI Shanghai:苯甲醚 Anisole,>;99.0%(GC)(100-66-3)
  • 职业标准:STEL 10 毫克/ 立方米
  • 蒸气压:10 mm Hg ( 42.2 °C)
  • 蒸气密度:3.7 (vs air)
  • {Ch
  • 下游产品:1-甲基-4-咪唑甲酸 --> 4-(羟甲基)咪唑 --> 咪唑-4,5-二羧酸 --> 1-甲基-1H-咪唑-5-甲酸 --> 头孢地尼 --> 1,5-二氮杂双环[4.3.0]壬-5-烯 --> 1-甲基-1H-咪唑-4,5-二羧酸 --> 诱惑红 --> 敌菌净 --> 头孢布烯 --> 2-肼基甲基吡啶 --> 1H-咪唑-4-甲酸 --> 甲基多巴 --> 1-甲基-1H-咪唑-4,5-二甲腈 --> 吡啶-3-亚甲基肼,1-(3-吡啶基)甲基肼 --> 劳森试剂 --> 6-羟基-1-萘甲酸 --> 分散兰BGL --> 1-[4-(4-氨基-6,7-二甲氧基喹唑啉-2-基)-1,4-二氮杂环庚烷-1-基]丁-1-酮盐酸盐 --> 跟踪,示踪,微量 --> 间-油酰氨基-邻-甲氧基苯磺酸钠,净洗剂MA,洗净剂SL --> 头孢卡品酯 --> 维拉帕米 --> 6-甲氧基萘甲酸 --> 阿诺克索牟抗氧剂
  • 用途三:GB 2760—1996规定为允许使用的食品用香料。主要用于配制香草、茴香和啤酒型香精。
  • 使用限量:FEMA(mg/kg):软饮料9.0;冷饮16;糖果51;焙烤食品34。 以适度为限(FDA§172.515,2000)。
  • 上游原料:氢氧化钠 --> 硫酸二甲酯 --> 苯酚 --> 二甲酯 --> 二甲醚
  • 防护
  • 参考质量标准:FCC,1996 馏程 154℃士2℃ 折射率(n D 20 ) 1.515~1.518 相对密度(d 25 25 ) 0.990~0.993 酚类试验 阴性
  • 可燃性危险特性:遇明火、高温、强氧化剂可燃;燃烧排放刺激烟雾
  • 急性毒性:口服- 大鼠 L
  • 检测方法:GC

化学结构图

CAS 100-66-3  MFCD00008354
SMILES: COC1C=CC=CC=1

化学属性

Mol. FormulaCH3OC6H5
Mol. Weight108.14
Refractive indexn20/D 1.516(lit.)
Boiling Point154 °C(lit.)
Density0.995 g/mL at 25 °C(lit.)
Melting Point-37 °C(lit.)
Flash Point51°C(lit.)
TSCAYes
Autoignition Point887 °F
Vapor Density3.7 (vs air)
Vapor Pressure10 mmHg ( 42.2 °C)
Solubility不溶于水,溶于乙醇、乙醚。
Stability对光敏感

别名和识别编码

Chemical NameAnisole
Synonym
  • ether,methylphenyl
  • 甲氧基苯
  • Methyl phenyl ether
  • 茴香醚
  • Ether, methyl phenyl-
  • 苯甲醚
  • ANISOLE
  • 苯基甲基醚
  • Methoxybenzene, Methyl phenyl ether
  • 甲基苯基醚
    CAS Number100-66-3
    PubChem Substance ID 24900857
    EC Number202-876-1
    Beilstein Registry Number506892
    MDL NumberMFCD00008354
    Reaxys-RN506892
    Merck Number669
    Chemical Name Translation苯甲醚
    Wiswesser Line Notation1OR
    LabNetwork Molecule IDLN00163734

    系列性分类


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