3-Morpholinopropan-1-amine 4-吗啉基丙胺

CAS 123-00-2 MFCD00006184

化学结构图

123-00-2
SMILES: NCCCN1CCOCC1

化学属性

Mol. FormulaC7H16N2O
Mol. Weight144.21
Density0.987 g/mL at 25 °C(lit.)
Refractive index1.4760 to 1.4780
Boiling Point224°C at 760 mmHg
Melting Point-15°C
Flash Point98.89°C
TSCAYes
Solubility可溶

别名和识别编码

Chemical Name3-Morpholinopropan-1-amine
CAS Number123-00-2
Alfabeta NameMORPHOLINYLPROPANAMINE 341()----
MDL NumberMFCD00006184
Synonym (3-Aminopropyl)morpholine 3-(1-MORPHOLINO)-1-PROPYLAMINE 3-(4-MORPHOLINO)-1-PROPYLAMINE 3-(4-Morpholinyl)-1-propanamine 3-(4-Morpholinyl)propanamine 3-(4-Morpholinyl)propylamine 3-MORPHOLINOPROPYLAMINE 3-Morpholinopropan-1-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number204-590-2
Beilstein Registry Number27(3/4)411
PubChem Substance ID87562044
Reaxys-RN105104
Chemical Name Translation4-吗啉基丙胺
Wiswesser Line NotationT6N DOTJ A3Z
LabNetwork Molecule IDLN00132650
InChIInChI=1S/C7H16N2O/c8-2-1-3-9-4-6-10-7-5-9/h1-8H2
Canonical SMILESNCCCN1CCOCC1
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; nitrogen heterocycle; alicycle; 6RingOnly; 6ring; ether; 1fragment
  • {SNA} Building Blocks, C4 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Morpholines/Thiomorpholines

产品应用

  • 用于合成纤维。

相关文献及参考

  • Beilstein:27(3/4)411
  • Short: EINECS
  • Short: III/38B

安全信息

Warnings IRRITANT
Signal word Danger
GHS Symbol
WGK Germany2
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353+P310+P363
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P303+P361+P353
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P304+P340+P310
  • P301+P330+P331+P310
  • P305+P351+P338+P310
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H312 Harmful in contact with skin 皮肤接触有害
  • H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSQD7700000
Packing GroupIII
UN Number 2735 UN2735 UN 2735 8/PG 2
Storage condition 2-8°C, protect from light Air Sensitive 室温
Hazard Codes C C,Xi
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3560 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 3/25/1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1230 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 4,119,1951

其他信息

  • MOL 文件:123-00-2.mol
  • 储运特性:库房通风低温干燥
  • TCI Shanghai:4-吗啉丙胺 N-(3-Aminopropyl)morpholine,>;99.0%(GC)(123-00-2)
  • 毒性分级:中毒
  • 刺激数据:皮肤-兔子 10 毫克/24小时 重度; 眼睛-兔子 0.25 毫克/24小时 重度
  • 可燃性危险特性:较易燃;燃烧产生有毒氮氧化物烟雾
  • 灭火剂:干粉、泡沫、砂土, 二氧化碳, 雾状水
  • 可溶于水、乙醇、苯、己烷和石油醚。
  • 类别:易燃液体
  • Sigma Aldrich:123-00-2(sigmaaldrich)
  • Alfa Aesar:4-3-氨丙基吗啉,98% 3-(4-Morpholinyl)propylamine, 98%(123-00-2)
  • 急性毒性:口服-大鼠LD50: 3560 毫克/公斤; 皮肤-兔子LD50: 1230 毫克/公斤
  • 图谱信息:N-(3-氨丙基)吗啉(123-00-2)质谱(MS) N-(3-氨丙基)吗啉(123-00-2)核磁图( 1 HNMR) N-(3-氨丙基)吗啉(123-00-2)核磁图( 13 CNMR) N-(3-氨丙基)吗啉(123-00-2)红外图谱(IR1)
  • N-(3-氨丙基)吗啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0409 N-(3-氨丙基)吗啉 N-(3-Aminopropyl)morpholine 25ML 180元 2014/06/02 A0409 N-(3-氨丙基)吗啉 N-(3-Aminopropyl)morpholine 500ML 1260元 2010/06/21 153870010 N-(3-氨丙基)吗啉 N-(3-Aminopropyl)morpholine 98% 1 KG 3322元
  • 用途一:用于合成纤维。
  • F:10-34
  • 检测方法:GC,NMR
  • MSDS 信息:N-氨丙基吗啉(123-00-2).msds
  • 外观性质:无色澄清液体。
  • Acros Organics:N-(3-氨丙基)吗啉 N-(3-Aminopropyl)morpholine, 98%(123-00-2)

系列性分类


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