Tri-tert-butylphosphine 三叔丁基膦

CAS 13716-12-6 MFCD00015006

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H56414
Tri-tert-butylphosphine 三叔丁基膦
98%, SpcSeal 1g 90
96-99 %
INFI H56414
Tri-tert-butylphosphine 三叔丁基膦
98%, SpcSeal 5g 190
96-99 %
INFI H56414
Tri-tert-butylphosphine 三叔丁基膦
98%, SpcSeal 25g 670
96-99 %
INFI H86238
Tri-tert-butylphosphine 三叔丁基膦
10% solution in toluene, SpcSeal 5mL 100
LN-CN
中国国内现货 10+ % solution 甲苯
INFI H86238
Tri-tert-butylphosphine 三叔丁基膦
10% solution in toluene, SpcSeal 25mL 220
LN-CN
中国国内现货 10+ % solution 甲苯
INFI H86238
Tri-tert-butylphosphine 三叔丁基膦
10% solution in toluene, SpcSeal 100mL 650
10+ % solution 甲苯
INFI H93516
Tri-tert-butylphosphine 三叔丁基膦
30% solution in toluene, SpcSeal 5mL 210
LN-CN
中国国内现货 30+ % solution 甲苯
INFI H93516
Tri-tert-butylphosphine 三叔丁基膦
30% solution in toluene, SpcSeal 25mL 610
LN-CN
中国国内现货 30+ % solution 甲苯
INFI H93516
Tri-tert-butylphosphine 三叔丁基膦
30% solution in toluene, SpcSeal 100mL 1,920
30+ % solution 甲苯
INFI H50347
Tri-tert-butylphosphine 三叔丁基膦
10% solution in hexanes,SpcSeal 5mL 100
LN-CN
中国国内现货 10+ % solution 己烷
INFI H50347
Tri-tert-butylphosphine 三叔丁基膦
10% solution in hexanes,SpcSeal 25mL 260
10+ % solution 己烷
INFI H50347
Tri-tert-butylphosphine 三叔丁基膦
10% solution in hexanes,SpcSeal 100mL 820
LN-CN
中国国内现货 10+ % solution 己烷
INFI H94374
Tri-tert-butylphosphine 三叔丁基膦
95% 1g 350
96-99 %
INFI H94374
Tri-tert-butylphosphine 三叔丁基膦
95% 5g 1,000
96-99 %
INFI H94374
Tri-tert-butylphosphine 三叔丁基膦
95% 25g 3,700
96-99 %
INFI H61481
Tri-tert-butylphosphine 三叔丁基膦
20%(1M) solution in toluene, SpcSeal 5mL 170
LN-CN
中国国内现货 20+ % solution 甲苯
INFI H61481
Tri-tert-butylphosphine 三叔丁基膦
20%(1M) solution in toluene, SpcSeal 25mL 480
20+ % solution 甲苯
INFI H61481
Tri-tert-butylphosphine 三叔丁基膦
20%(1M) solution in toluene, SpcSeal 100mL 1,450
20+ % solution 甲苯
INFI H24500
Tri-tert-butylphosphine 三叔丁基膦
10% in pentane, SpcSeal 5mL 70
10% In 戊烷, SpcSeal
INFI H24500
Tri-tert-butylphosphine 三叔丁基膦
10% in pentane, SpcSeal 25mL 240
10% In 戊烷, SpcSeal
INFI H24500
Tri-tert-butylphosphine 三叔丁基膦
10% in pentane, SpcSeal 100mL 670
10% In 戊烷, SpcSeal
INFI H14330
Tri-tert-butylphosphine 三叔丁基膦
50% solution in toluene, SpcSeal 5mL 210
LN-CN
中国国内现货 50+ % solution 甲苯
INFI H14330
Tri-tert-butylphosphine 三叔丁基膦
50% solution in toluene, SpcSeal 25mL 610
LN-CN
中国国内现货 50+ % solution 甲苯
INFI H14330
Tri-tert-butylphosphine 三叔丁基膦
50% solution in toluene, SpcSeal 100mL 1,920
LN-CN
中国国内现货 50+ % solution 甲苯
Innochem T1100
tri-tert-butylphosphine
95% 5g 1,000
99
Innochem T1100
tri-tert-butylphosphine
95% 25g 3,700
99
Innochem T1100
tri-tert-butylphosphine
95% 100g 11,100
99
Alfa 010178
Tri-tert-butylphosphine
98% 1g 556
99
Alfa 010178
Tri-tert-butylphosphine
98% 5g 2,759
99
Wylton 30409
Tri-tert-butylphosphine 三叔丁基膦
0.97 25mL 360
CN
中国国内现货 0
J&K 971046
Tri-tert-butylphosphine, 10 wt.% solution in toluene, J&Kseal;
N/A 10mL 1,146
HB
中国国内现货 10+ % solution 甲苯
J&K 971046
Tri-tert-butylphosphine, 10 wt.% solution in toluene, J&Kseal;
N/A 50mL 3,090
10+ % solution 甲苯
Aldrich 570958
98% 1g 765
99
Aldrich 570958
98% 5g 2,442
99
Aldrich 570958
98% 10g 3,825
99
Acros 36089
Tri-tert-butylphosphine, 95%
1g 1,063
99
Acros 36089
Tri-tert-butylphosphine, 95%
5g 3,413
99
Aldrich 655325
1M IN TOLUENE 10mL 1,211
0
Aldrich 655325
1M IN TOLUENE 25mL 3,423
0
Aldrich 655325
1M IN TOLUENE 50mL 4,423
0
Energy-chemical E010012
Tri-tert-butylphosphine 三叔丁基膦
10% in Pentane(有少量沉淀属正常现象,不影响使用) 25mL 255
CN-BJ
中国国内现货 10
Energy-chemical E010012
Tri-tert-butylphosphine 三叔丁基膦
10% in Pentane(有少量沉淀属正常现象,不影响使用) 100mL 745
CN-BJ CN-SH
中国国内现货 10
Acros 360890010
95% 1g 1,181
99
Adamas 22077C
30% in toluene 100mL 6,318
CN
中国国内现货 30
Adamas 22077D
10% in n-pentane 25mL 477
SH-CN
中国国内现货 10
Adamas 22077E
10% in n-pentane 100mL 1,805
SH-CN CN
中国国内现货 10
Adamas 22077A
30% in toluene 25mL 1,596
SH-CN CN
中国国内现货 30
Adamas 22077B
30% in toluene 50mL 2,926
30
Aldrich 570958-1G
98% 1g 765
99
Aldrich 570958-5G
98% 5g 2,442
99
Aldrich 655325-10ML
1M IN TOLUENE 10mL 1,211
0
Aldrich 655325-50ML
1M IN TOLUENE 50mL 4,423
0
Aldrich 336955-1G
90% 1g 536
90
Aldrich 336955-5G
90% 5g 2,065
90
Aldrich 570958-10G
98% 10g 3,825
99
Aladdin T102752
Tri-tert-butylphosphine 三特丁基膦
1.0M 甲苯溶液 10mL 415
CN-SH
中国国内现货 0
Aladdin T102752
Tri-tert-butylphosphine 三特丁基膦
1.0M 甲苯溶液 50mL 1,218
CN-SH
中国国内现货 0
Strem 15-5810
Tri-t-butylphosphine, 99%
99% 1g 840
0
Strem 15-5810
Tri-t-butylphosphine, 99%
99% 5g 2,730
0
Strem 15-5810
Tri-t-butylphosphine, 99%
99% 25g 10,200
0
Strem 15-5812
Tri-t-butylphosphine, 99% (10 wt% in hexanes) (Sure/Seal? bottle)
99% 50g 3,540
0
Strem 15-5813
Tri-t-butylphosphine, min. 98%
min. 1g 750
0
Strem 15-5813
Tri-t-butylphosphine, min. 98%
min. 5g 2,520
0
Strem 15-5818
Tri-t-butylphosphine, min. 98% (50wt% in toluene)
min. 2g 1,200
0
Strem 15-5818
Tri-t-butylphosphine, min. 98% (50wt% in toluene)
min. 10g 3,120
HB
中国国内现货 0
Adamas 22077F
10% in toluene 25mL 655
10
Adamas 22077G
10% in toluene 100mL 1,962
10
Energy-chemical W830207
Tri-tert-butylphosphine 三叔丁基膦
10% in Toluene,Energyseal 100mL 845
10
Energy-chemical W830206
Tri-tert-butylphosphine 三叔丁基膦
10% in Pentane,Energyseal 100mL 845
CN-BJ CN-SH
中国国内现货 10
Energy-chemical E010430
Tri-tert-butylphosphine 三叔丁基膦
10% in Toluene(有少量沉淀属正常现象,不影响使用) 25mL 255
CN-SH
中国国内现货 10
Energy-chemical E010430
Tri-tert-butylphosphine 三叔丁基膦
10% in Toluene(有少量沉淀属正常现象,不影响使用) 100mL 745
CN-BJ CN-SH
中国国内现货 10
Meryer M32242
三叔丁基膦
10% in Hexane 100g 1,300
CN
中国国内现货 10
Meryer M32242
三叔丁基膦
10% in Hexane 500g 2,680
CN
中国国内现货 10
Aladdin T102752-10ml
10mL 424
Aladdin T102752-50ml
50mL 1,243
3A A11367
Tri-tert-butylphosphine 三叔丁基膦
10% solution in hexanes 5ml 110
10% In 戊烷, SpcSeal
3A A11367
Tri-tert-butylphosphine 三叔丁基膦
10% solution in hexanes 25ml 260
10% In 戊烷, SpcSeal
3A A11367
Tri-tert-butylphosphine 三叔丁基膦
10% solution in hexanes 100ml 870
10% In 戊烷, SpcSeal
3A A11532
Tri-tert-butylphosphine 三叔丁基膦
10% in pentane, SpcSeal 5ml 110
10% In 戊烷, SpcSeal
3A A11532
Tri-tert-butylphosphine 三叔丁基膦
10% in pentane, SpcSeal 25ml 260
10% In 戊烷, SpcSeal
3A A11532
Tri-tert-butylphosphine 三叔丁基膦
10% in pentane, SpcSeal 100ml 870
10% In 戊烷, SpcSeal
3A A11533
Tri-tert-butylphosphine 三叔丁基膦
10% solution in toluene, SpcSeal 5ml 110
10+ % solution Toluene
3A A11533
Tri-tert-butylphosphine 三叔丁基膦
10% solution in toluene, SpcSeal 25ml 260
10+ % solution Toluene
3A A11533
Tri-tert-butylphosphine 三叔丁基膦
10% solution in toluene, SpcSeal 100ml 870
10+ % solution Toluene
3A A11534
Tri-tert-butylphosphine 三叔丁基膦
20%(1M) solution in toluene,SpcSeal 5ml 170
20+ % solution 甲苯
3A A11534
Tri-tert-butylphosphine 三叔丁基膦
20%(1M) solution in toluene,SpcSeal 25ml 480
20+ % solution 甲苯
3A A11534
Tri-tert-butylphosphine 三叔丁基膦
20%(1M) solution in toluene,SpcSeal 100ml 1,450
20+ % solution 甲苯
3A A11535
Tri-tert-butylphosphine 三叔丁基膦
30% solution in toluene, SpcSeal 5ml 210
30+ % solution Toluene
3A A11535
Tri-tert-butylphosphine 三叔丁基膦
30% solution in toluene, SpcSeal 25ml 610
30+ % solution Toluene
3A A11535
Tri-tert-butylphosphine 三叔丁基膦
30% solution in toluene, SpcSeal 100ml 1,920
30+ % solution Toluene
Key Organic STR06767
Tris(tert-butyl)phosphine
>95% 50g 2,730
90+ %
TRC T886495
Tri-?tert-?butylphosphine
500mg 560
TRC T886495
Tri-?tert-?butylphosphine
1g 770
TRC T886495
Tri-?tert-?butylphosphine
5g 1,750
Strem 15-5811
Tri-t-butylphosphine, 99% (10 wt% in hexanes)
99% 10g 1,440
96-99 %
Strem 15-5811
Tri-t-butylphosphine, 99% (10 wt% in hexanes)
99% 50g 3,330
96-99 %

分类

  • {SNA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds, Phosphine Ligands
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/25D
  • Merck: 14,9529 Beilstein:4(3)1771
  • For a brief feature on uses of the reagent in synthesis, see: Synlett, 709 (2005).
  • Short: EINECS
  • Efficient catalyst for the trifluoromethylation of aldehydes, ketones, imides and imines with (Trifluoromethyl)­trimethyl­silane, B20347: Synlett, 267 (2006).
  • Ligand which has been used in conjunction with Tris(dibenzyl­ideneacetone)­dipalladium(0)­, 12760 in promoting Suzuki cross-coupling reactions of arylboronic acids with aryl and vinyl halides under mild conditions. The system is particularly recommended for coupling reactions with normally unreactive aryl chlorides: J. Am. Chem. Soc., 4070 (2000). The same catalyst system has been found to be effective in the room-temperature cyanation of aryl bromides using zinc cyanide: Synlett, 2237 (2003).
  • Merck: 14,9529
  • Ligand which has been used in conjunction with Tris(dibenzyl­ideneacetone)­dipalladium(0)­, 12760 in promoting Suzuki cross-coupling reactions of arylboronic acids with aryl and vinyl halides under mild conditio

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
Personal Protective Equipment
  • Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P222 Do not allow contact with air. 不要与空气接触。
  • P422 Store contents under… 存储目录在…之下。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P231 Handle under inert gas. 在惰性气体中操作。
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S25 Avoid contact with eyes 避免眼睛接触;
Packing GroupI
UN Number
  • UN2845
  • 1993
  • UN2846
Risk Statements
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition
  • 对空气和水分敏感,密封保存。
  • Air & Moisture Sensitive
  • 充氩,储存温度 2-8℃。
Hazard Codes
  • F,C

化学结构图

CAS 13716-12-6  MFCD00015006
SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C

化学属性

Mol. Formula[(CH3)3C]3P
Mol. Weight202.32
Boiling Point102-103 °C/13 mmHg(lit.)
Density0.861
Melting Point30-35 °C(lit.)
Flash Point-16°(-3°F)
TSCANo
Solubility不溶
Stability对空气敏感,对湿度敏感

别名和识别编码

Chemical NameTri-tert-butylphosphine
Synonym
  • tris(1,1-dimethylethyl)phosphine
  • Tri-tert-butylphosphine
  • P(t-Bu)3
  • 三特丁基膦
  • Tri-t-butylphosphine
  • Tri-tert.-butylphosphin
  • 三叔丁基膦
  • Tris(1,1-dimethylethyl)phosphine
    PubChem Substance ID 24860444
    EC Number237-266-4
    Beilstein Registry Number1738613
    MDL NumberMFCD00015006
    CAS Number13716-12-6
    Chemical Name Translation三叔丁基膦
    InChIKeyBWHDROKFUHTORW-UHFFFAOYSA-N
    LabNetwork Molecule IDLN00155764

    系列性分类


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