B-1-Naphthalenyl-boronic Acid 1-萘硼酸

CAS 13922-41-3 MFCD00019722


SMILES: OB(O)c1cccc2ccccc12


Solubility2.5 G/100 ML
Mol. FormulaC10H9BO2
Mol. Weight172
Appearance white to off-white pwdr.
Melting Point208-214


Chemical NameB-1-Naphthalenyl-boronic Acid
Beilstein Registry Number2937504
PubChem Substance ID87573946
Synonym α-Naphthaleneboronic acid α-Naphthylboronic acid 1-naphthalenyl-boronic acid 1-Naphthaleneboronic acid 1-萘基硼酸 NSC 78936 1-Naphthylboronic acid 1-naphthalenyl-boronic acid 1-萘基硼酸 1-萘硼酸 NSC 78936 α-Naphthaleneboronic acid α-Naphthaleneboronic acid α-Naphthylboronic acid 1-naphthalenyl-boronic acid 1-萘基硼酸 1-萘硼酸 NSC 78936 α-Naphthaleneboronic acid, α-Naphthylboronic acid, 1-naphthalenyl-boronic acid, 1-Naphthaleneboronic acid, 1-Naphthylboronic acid α-Naphthylboronic acid 萘-1-硼酸
EC Number250-023-7
Chemical Name Translation1-萘硼酸
LabNetwork Molecule IDLN00116905
MDL NumberMFCD00019722
CAS Number13922-41-3
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  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Unsubstituted Aryl Boronic Acids


  • Beilstein:16(3)1280
  • The Suzuki coupling with a protected L-tyrosine triflate, catalyzed by Tetrakis(triphenyl­phosphine)­palladium(0)­, 10548, occurred in high yield without racemization when anhydrous K2CO3 in toluene was used as the base: J. Org. Chem., 57, 379 (1992). For Ni-catalyzed coupling with allylamines, see: J. Chem. Soc., Perkin 1, 2083 (1995). See Appendix 5.


Signal word Warning {} {} {} {} {} {} {} {} {} {} {} {TCI}
Hazard statements
  • H302+H312+H332
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P312+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
WGK Germany3
GHS Symbol
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi