Lithium aluminum hydride 氢化锂铝

CAS 16853-85-3 MFCD00011075

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INFI 377553
Lithium aluminium hydride 氢化锂铝
2.5 M solution in THF, SpcSeal 100mL 170
BY-CN LN-CN
中国国内现货 2.5 M solution 四氢呋喃
INFI 377553
Lithium aluminium hydride 氢化锂铝
2.5 M solution in THF, SpcSeal 500mL 540
LN-CN
中国国内现货 2.5 M solution 四氢呋喃
INFI 377553
Lithium aluminium hydride 氢化锂铝
2.5 M solution in THF, SpcSeal 1L 920
LN-CN
中国国内现货 2.5 M solution 四氢呋喃
INFI 377554
Lithium aluminium hydride 氢化锂铝
1.0 M solution in THF , SpcSeal 100mL 120
BY-CN LN-CN
中国国内现货 1.0 M solution 四氢呋喃
INFI 377554
Lithium aluminium hydride 氢化锂铝
1.0 M solution in THF , SpcSeal 500mL 380
BY-CN LN-CN
中国国内现货 1.0 M solution 四氢呋喃
INFI 377554
Lithium aluminium hydride 氢化锂铝
1.0 M solution in THF , SpcSeal 1L 400
LN-CN
中国国内现货 1.0 M solution 四氢呋喃
INFI 378900
Lithium aluminum hydride 氢化锂铝
97% 25g 140
96-99 %
INFI 378900
Lithium aluminum hydride 氢化锂铝
97% 100g 380
BY-CN
中国国内现货 96-99 %
INFI 378900
Lithium aluminum hydride 氢化锂铝
97% 500g 1,330
96-99 %
INFI 586997
Lithium aluminium hydride 氢化锂铝
2.0 M solution in THF , SpcSeal 100mL 160
2.0 M solution 四氢呋喃
INFI 586997
Lithium aluminium hydride 氢化锂铝
2.0 M solution in THF , SpcSeal 500mL 520
2.0 M solution 四氢呋喃
INFI 586997
Lithium aluminium hydride 氢化锂铝
2.0 M solution in THF , SpcSeal 1L 890
2.0 M solution 四氢呋喃
INFI 679751
Lithium aluminium hydride 氢化锂铝
1.0 M solution in diethyl ether , SpcSeal 100mL 120
LN-CN
中国国内现货 1.0 M solution 二乙醚
INFI 679751
Lithium aluminium hydride 氢化锂铝
1.0 M solution in diethyl ether , SpcSeal 500mL 380
LN-CN
中国国内现货 1.0 M solution 二乙醚
Innochem 546551
100g 350
Innochem 580591
Lithium aluminum hydride
97% 25g -
BJ-CN
中国国内现货 96-99 %
Innochem 580591
Lithium aluminum hydride
97% 100g 576
BJ-CN
中国国内现货 96-99 %
Alfa 253610
Lithium aluminum hydride
97% 10g 181
99
Alfa 253610
Lithium aluminum hydride
97% 25g 294
99
Alfa 253610
Lithium aluminum hydride
97% 100g 421
99
Alfa 253610
Lithium aluminum hydride
97% 250g 1,297
99
Alfa 253610
Lithium aluminum hydride
97% 1000g 3,558
99
TCI 270812
Lithium Aluminum Hydride (10% in Tetrahydrofuran, ca . 2.5mol/L) >
ca. 2.5mol/L) 100mL 590
SH-CN TK-JP
中国国内现货 0
TCI 289087
Lithium Aluminum Hydride (Powder)
98%,T 25g 350
99
Alfa 372729
Lithium aluminum hydride
4% in THF 500mL 4,198
SH-CN
中国国内现货 0
Alfa 372730
Lithium aluminum hydride
10% in THF 500mL 2,523
10
Alfa 372731
Lithium aluminum hydride
15% in THF/toluene (2.4:1) 500mL 4,254
SH-CN
中国国内现货 10
Alfa 372732
Lithium aluminum hydride
95% min 25g 620
SH-CN
中国国内现货 99
Alfa 372732
Lithium aluminum hydride
95% min 100g 1,435
SH-CN
中国国内现货 99
Alfa 372732
Lithium aluminum hydride
95% min 500g 5,124
SH-CN
中国国内现货 99
Alfa 372732
Lithium aluminum hydride
95% min 1kg 7,602
SH-CN
中国国内现货 99
Alfa 372733
Lithium aluminum hydride
97% 25g 605
SH-CN
中国国内现货 99
Alfa 372733
Lithium aluminum hydride
97% 100g 1,652
SH-CN
中国国内现货 99
Alfa 372733
Lithium aluminum hydride
97% 500g 7,525
SH-CN
中国国内现货 99
J&K 378895
Lithium aluminum hydride, 1.0 M solution in THF, J&KSeal;
N/A 100mL 487
HB
中国国内现货 1.0 M solution THF
J&K 378896
Lithium aluminum hydride, 2.4 M solution in THF, J&KSeal;
N/A 100mL 727
HB
中国国内现货 2.4 M solution THF
J&K 378897
Lithium aluminum hydride, 95%
95% 25g 333
HB
中国国内现货 90+ %
Aldrich 205121
Lithium aluminum hydride 氢化铝锂
95% 25g 484
SH
中国国内现货 99
Aldrich 205121
Lithium aluminum hydride 氢化铝锂
95% 100g 1,334
99
Aldrich 223463
Lithium aluminum hydride solution 氢化铝锂 溶液
0.5 M in 2-methoxyethyl ether 0.5?M in 2-methoxyethyl ether 100mL 845
0.50 M solution in SOLUTION IN DIGLYME
Aldrich 240726
Lithium aluminum hydride 氢化铝锂
reagent grade 1kg 8,336
0
Aldrich 248892
Lithium aluminum hydride 氢化铝锂
95% 500g 4,956
99
Aldrich 249840
Lithium aluminum hydride solution 氢化铝锂 溶液
1.0 M in THF 1.0?M in THF 25mL 263
1.00 M solution in THF
Aldrich 249840
Lithium aluminum hydride solution 氢化铝锂 溶液
1.0 M in THF 1.0?M in THF 100mL 512
SH
中国国内现货 1.00 M solution in THF
Aldrich 249840
Lithium aluminum hydride solution 氢化铝锂 溶液
1.0 M in THF 1.0?M in THF 4x25mL 526
1.00 M solution in THF
Aldrich 249840
Lithium aluminum hydride solution 氢化铝锂 溶液
1.0 M in THF 1.0?M in THF 4x100mL 1,602
1.00 M solution in THF
Aldrich 249840
Lithium aluminum hydride solution 氢化铝锂 溶液
1.0 M in THF 1.0?M in THF 800mL 1,639
SH
中国国内现货 1.00 M solution in THF
Acros 265163
Lithium aluminium hydride, 1M solution in THF, AcroSeal?
1M solution in THF, AcroSeal® 100mL 701
SH-CN BJ-CN CN
中国国内现货 1.00 M solution in THF
Acros 265163
Lithium aluminium hydride, 1M solution in THF, AcroSeal?
1M solution in THF, AcroSeal® 800mL 3,503
SH-CN BJ-CN CN
中国国内现货 1.00 M solution in THF
Acros 294174
Lithium aluminium hydride, 2.4M solution in THF, AcroSeal?
2.4M solution in THF, AcroSeal® 100mL 773
SH-CN BJ-CN CN
中国国内现货 2.40 M solution in THF
Acros 294174
Lithium aluminium hydride, 2.4M solution in THF, AcroSeal?
2.4M solution in THF, AcroSeal® 800mL 3,907
CN
中国国内现货 2.40 M solution in THF
Acros 295951
Lithium aluminium hydride, 95%, tablets (ca. 0.6 g)
95% 25g 241
SH-CN CN
中国国内现货 0
Acros 299668
Lithium aluminium hydride, 95%, powder
95% 10g 250
SH-CN BJ-CN CN
中国国内现货 0
Acros 307761
Lithium aluminium hydride, 95%, in resealable tin cans
10g 294
CN
中国国内现货 0
Acros 307761
Lithium aluminium hydride, 95%, in resealable tin cans
100g 1,189
CN
中国国内现货 0
Acros 312571
Lithium aluminium hydride, 4.0M solution in diethyl ether, AcroSeal?
4.0M solution in diethyl ether, AcroSeal® 100mL 606
BJ-CN CN
中国国内现货 4.00 M solution in Diethyl ether
Acros 312571
Lithium aluminium hydride, 4.0M solution in diethyl ether, AcroSeal?
4.0M solution in diethyl ether, AcroSeal® 800mL 2,463
4.00 M solution in Diethyl ether
Acros 317291
Lithium aluminium hydride, 15% (3.5M) solution in toluene/THF, AcroSeal?
15% (3.5M) solution in toluene/THF, AcroSeal® 100mL 543
SH-CN CN
中国国内现货 0
Acros 317291
Lithium aluminium hydride, 15% (3.5M) solution in toluene/THF, AcroSeal?
15% (3.5M) solution in toluene/THF, AcroSeal® 800mL 3,240
0
Aldrich 321593
Lithium aluminum hydride
>=97.0% (gas-volumetric) ≥97.0% (gas-volumetric), tablets (~0.5 g each) 10g 181
0
Aldrich 323408
Lithium aluminum hydride solution
~3.5 M in THF/toluene, suspension ~3.5?M in THF/toluene, suspension 100mL 632
0
Aldrich 333552
Lithium aluminum hydride solution
2.3 M in 2-methyltetrahydrofuran 2.3?M in 2-methyltetrahydrofuran 100mL 844
0
Aldrich 333552
Lithium aluminum hydride solution
2.3 M in 2-methyltetrahydrofuran 2.3?M in 2-methyltetrahydrofuran 800mL 3,058
0
TRC 378898
Lithium Aluminum Hydride
5g 1,100
Energy-chemical 383790
Lithium aluminium hydride 氢化铝锂
97% 5g 65
CN-BJ CN-SH
中国国内现货 96-99 %
Energy-chemical 383790
Lithium aluminium hydride 氢化铝锂
97% 25g 158
CN-BJ CN-SH
中国国内现货 96-99 %
Energy-chemical 383790
Lithium aluminium hydride 氢化铝锂
97% 100g 462
CN-BJ CN-SH
中国国内现货 96-99 %
Energy-chemical 383790
Lithium aluminium hydride 氢化铝锂
97% 500g 1,680
96-99 %
Energy-chemical 383790
Lithium aluminium hydride 氢化铝锂
97% 1kg 2,250
96-99 %
Acros 406563
AcroSeal? 800mL 2,311
0
Energy-chemical 410355
Lithium aluminium hydride 氢化铝锂
1.0mol/l in THF,EnergySeal 100mL 119
CN-BJ
中国国内现货 1.0 M solution THF
Energy-chemical 410355
Lithium aluminium hydride 氢化铝锂
1.0mol/l in THF,EnergySeal 500mL 397
CN-BJ CN-SH
中国国内现货 1.0 M solution THF
Energy-chemical 410355
Lithium aluminium hydride 氢化铝锂
1.0mol/l in THF,EnergySeal 800mL 1,820
1.0 M solution THF
Energy-chemical 410355
Lithium aluminium hydride 氢化铝锂
1.0mol/l in THF,EnergySeal 1L 745
CN-BJ CN-SH
中国国内现货 1.0 M solution THF
Energy-chemical 410356
Lithium aluminium hydride 氢化铝锂
2.5mol/l in THF,EnergySeal 100mL 168
CN-BJ CN-SH
中国国内现货 2.5 M solution THF
Energy-chemical 410356
Lithium aluminium hydride 氢化铝锂
2.5mol/l in THF,EnergySeal 500mL 545
CN-BJ CN-SH
中国国内现货 2.5 M solution THF
Energy-chemical 410356
Lithium aluminium hydride 氢化铝锂
2.5mol/l in THF,EnergySeal 800mL 2,220
2.5 M solution THF
Energy-chemical 410356
Lithium aluminium hydride 氢化铝锂
2.5mol/l in THF,EnergySeal 1L 975
CN-BJ CN-SH
中国国内现货 2.5 M solution THF
Adamas 461998
97%+ 250g 936
SH-CN CN
中国国内现货 96-99 %
Adamas 461999
97%+ 25g 188
SH-CN
中国国内现货 96-99 %
Adamas 462000
97%+ 100g 498
SH-CN CN
中国国内现货 96-99 %
Shao Yuan 462001
100g 329
SH-CN
中国国内现货
Strem 462002
Lithium aluminum hydride, powder, 95%
95% 10g 420
90+ %
Strem 462002
Lithium aluminum hydride, powder, 95%
95% 50g 770
90+ %
Strem 462002
Lithium aluminum hydride, powder, 95%
95% 250g 2,912
HB
中国国内现货 90+ %
Strem 462002
Lithium aluminum hydride, powder, 95%
95% 1kg 8,736
90+ %
Strem 462003
Lithium aluminum hydride 2.2M (10wt% ±1wt%) in 2-methyltetrahydrofuran
0.05mole 345
2.2 M
Strem 462003
Lithium aluminum hydride 2.2M (10wt% ±1wt%) in 2-methyltetrahydrofuran
0.25mole 1,380
2.2 M
Aladdin 462004
Lithium Aluminium Hydride 氢化铝锂
97% 5g 62
CN-SH
中国国内现货 96-99 %
Aladdin 462004
Lithium Aluminium Hydride 氢化铝锂
97% 25g 177
CN-SH
中国国内现货 96-99 %
Aladdin 462004
Lithium Aluminium Hydride 氢化铝锂
97% 100g 444
CN-SH
中国国内现货 96-99 %
Aladdin 462004
Lithium Aluminium Hydride 氢化铝锂
97% 250g 880
CN-SH
中国国内现货 96-99 %
Aladdin 462004
Lithium Aluminium Hydride 氢化铝锂
97% 1kg 3,549
CN-SH
中国国内现货 96-99 %
Sigma 511542
1.0 M in THF (Aldrich) 100mL 387
1.00 M solution in THF
Sigma 511542
1.0 M in THF (Aldrich) 800mL 1,584
1.00 M solution in THF
HY 518108
Lithium aluminum hydride solution 氢化铝锂 溶液
2.5 M solution in THF, HySeal 100mL -
2.5 M solution THF
HY 518108
Lithium aluminum hydride solution 氢化铝锂 溶液
2.5 M solution in THF, HySeal 500mL -
2.5 M solution THF
HY 518108
Lithium aluminum hydride solution 氢化铝锂 溶液
2.5 M solution in THF, HySeal 800mL -
2.5 M solution THF
HY 518109
Lithium aluminum hydride solution 氢化铝锂 溶液
1.0 M solution in THF, HySeal 100mL -
1.0 M solution THF
HY 518109
Lithium aluminum hydride solution 氢化铝锂 溶液
1.0 M solution in THF, HySeal 500mL -
1.0 M solution THF
HY 518109
Lithium aluminum hydride solution 氢化铝锂 溶液
1.0 M solution in THF, HySeal 800mL -
1.0 M solution THF
Adamas 521550
2.5 M solution in THF, SafeSeal 500mL 800
CN
中国国内现货 2.5 M solution THF
Adamas 521551
2.5 M solution in THF, SafeSeal 100mL 280
CN
中国国内现货 2.5 M solution THF
HY 523762
Lithium aluminum hydride 氢化锂铝
97% 25g -
96-99 %
HY 523762
Lithium aluminum hydride 氢化锂铝
97% 100g -
96-99 %
HY 523762
Lithium aluminum hydride 氢化锂铝
97% 250g -
96-99 %
HY 523762
Lithium aluminum hydride 氢化锂铝
97% 500g -
96-99 %
HY 523762
Lithium aluminum hydride 氢化锂铝
97% 1kg -
96-99 %
Aladdin 544316
Lithium Aluminium Hydride 氢化铝锂
1.0M 四氢呋喃溶液 100mL 119
CN-SH
中国国内现货 1.0 M
Aladdin 544316
Lithium Aluminium Hydride 氢化铝锂
1.0M 四氢呋喃溶液 500mL 396
CN-SH
中国国内现货 1.0 M
Aladdin 544316
Lithium Aluminium Hydride 氢化铝锂
1.0M 四氢呋喃溶液 1L 743
1.0 M
TRC 544334
Lithium Aluminum Hydride
5g 1,320
TRC 544334
Lithium Aluminum Hydride
50g 3,000
TRC 544334
Lithium Aluminum Hydride
250g 12,000
Gelest 544335
LITHIUM ALUMINUM HYDRIDE, pellet…
97% 25g 900
96-99 %
Gelest 544335
LITHIUM ALUMINUM HYDRIDE, pellet…
97% 250g 4,874
96-99 %
Gelest 544335
LITHIUM ALUMINUM HYDRIDE, pellet…
97% 8kg 80,668
96-99 %
Adamas 544342
98%,Can 100g 589
96-99 %
Adamas 544343
2.5 M solution in THF, SafeSeal 800mL 1,600
2.5 M solution THF
Adamas 544344
1 M solution in THF, SafeSeal 100mL 240
CN
中国国内现货 1.0 M solution THF
Adamas 544345
1 M solution in THF, SafeSeal 500mL 500
CN
中国国内现货 1.0 M solution THF
Aladdin 544368
Lithium Aluminium Hydride 氢化铝锂
2.5 M四氢呋喃溶液 100mL 167
CN-SH
中国国内现货 2.5 %
Aladdin 544368
Lithium Aluminium Hydride 氢化铝锂
2.5 M四氢呋喃溶液 500mL 545
CN-SH
中国国内现货 2.5 %
Aladdin 544368
Lithium Aluminium Hydride 氢化铝锂
2.5 M四氢呋喃溶液 1L 2,599
2.5 %
Meryer 559410
氢化铝锂
1.0M 四氢呋喃溶液 100mL 379
1.0 M
Meryer 559410
氢化铝锂
1.0M 四氢呋喃溶液 500mL 1,131
1.0 M
Acros 587108
95% 10g 249
90+ %
Acros 587108
95% 25g 480
90+ %
Acros 587108
95% 50g 432
90+ %
Acros 587108
95% 100g 1,920
90+ %
Acros 587108
95% 250g 1,436
90+ %
Acros 587108
95% 500g 3,303
90+ %
Acros 592993
95% 10g 210
90+ %
Acros 592993
95% 100g 849
90+ %
Acros 592993
95% 500g 1,109
90+ %
Acros 594106
100mL 526
Acros 594106
800mL 2,452
Acros 594107
95% 25g 253
90+ %
Acros 594107
95% 100g 822
90+ %
3A 634245
Lithium aluminium hydride 氢化锂铝
2.5 M solution in THF, SpcSeal 100ml 170
2.5 M solution THF
3A 634245
Lithium aluminium hydride 氢化锂铝
2.5 M solution in THF, SpcSeal 500ml 540
2.5 M solution THF
3A 634245
Lithium aluminium hydride 氢化锂铝
2.5 M solution in THF, SpcSeal 800ml 790
2.5 M solution THF
3A 634249
Lithium aluminium hydride 氢化锂铝
97% 25g 140
96-99 %
3A 634249
Lithium aluminium hydride 氢化锂铝
97% 100g 380
96-99 %
3A 634249
Lithium aluminium hydride 氢化锂铝
97% 500g 1,390
BJ-CN
中国国内现货 96-99 %
3A 634404
Lithium aluminium hydride 氢化锂铝
1.0 M solution in THF , SpcSeal 100ml 120
1.0 M solution THF
3A 634404
Lithium aluminium hydride 氢化锂铝
1.0 M solution in THF , SpcSeal 500ml 380
1.0 M solution THF
3A 634404
Lithium aluminium hydride 氢化锂铝
1.0 M solution in THF , SpcSeal 800ml 490
1.0 M solution THF
3A 634521
Lithium aluminium hydride 氢化锂铝
2.0 M solution in THF , SpcSeal 100ml 160
2.0 M solution THF
3A 634521
Lithium aluminium hydride 氢化锂铝
2.0 M solution in THF , SpcSeal 500ml 520
2.0 M solution THF
3A 634521
Lithium aluminium hydride 氢化锂铝
2.0 M solution in THF , SpcSeal 800ml 730
2.0 M solution THF

分类

  • {SNA} Alternative Energy, Aluminum Hydrides, Chemical Synthesis,
  • {SNA} Aluminum Hydrides, Chemical Synthesis, Reduction, Synthetic Reagents
  • {SNA} Alternative E
  • {SNA} 25mL Sure/Seal Reagents, Aluminum Hydrides,
  • {SNA} Alternative Energy, Aluminum Hydrides, Chemical Synthesis, Materials Science, Materials for Hydrogen Storage, Metal Hydrides, Reduction, Synthetic Reagents
  • {SNA} Alternative Energy, Aluminum Hydrides, Chemical Synthesis, Enabling Products, Greener Alternative Products,
  • {SNA} 25mL Sure/Seal Reagents, Aluminum Hydrides, Chemical Synthesis, Organometallic Reagents, Reduction, Synthetic Reagents

产品应用

  • ⑴.具有高度可燃性,必须隔绝空气、湿气,并最好在氮气氛下保存。 ⑵. 羰基试剂。还原剂。制造其他氢化物及硅烷、硼烷等。在医药、香料、农药、染料及其他精细有机合成中用作还原剂。可将醛酮、酸、酸酐、酯、醌、酰氯等还原为醇,将腈还原为伯胺,将卤化烃还原为烃,芳香硝基化合物还原成偶氮化合物。但通常不能使碳—碳双键氢化。100份乙醚能溶本品30份,100份四氢呋喃能溶13份,100份二甲基溶纤剂能溶10份,100份二丁醚能溶2份,100份二氧六环能溶0.1份。 ⑶. 是有机化学中一个常用的还原试剂,能够还原多种官能 A powerful reagent and reducing agent.

相关文献及参考

  • For reduction of sulfones, see Titanium(IV)­ chloride, 14713.
  • For THF, at least 10ml solvent per gram of reagent is recommended to absorb heat of mixing.
  • The use of water or steam baths, or of electric heating mantles is to be strongly discouraged.
  • The reduction reaction should preferably be controlled by adjusting the rate of addition of the substrate rather than relying on external heating or cooling.
  • Short: IV/19A1
  • Many procedures for reactions with this reagent which have been described in the literature are potentially unsafe on anything other than a very small scale, since often no precautions are given for mixing the reagent with flammable solvents. The following suggestions are offered for laboratory scale reductions:
  • Short: III/14a
  • Merck: 14,349
  • Efficient stirring is essential during mixing, reaction and workup.
  • For phase-transfer reductions in hydrocarbon solvents, see 15-Crown-5, A12265. For formation of lithium tris(diethylamino)aluminum hydride and use in the reduction of esters or amides to aldehydes, see Diethyl­amine, A11716. For formation of a reagent for reduction of carboxylic acids to aldehydes, see 1-Methyl­piperazine, A10837.
  • External heating or cooling, if required, should be by means of a suitable inert oil.
  • Monograph: J. Seyden-Penne, Reductions by the Alumino- and Borohydrides In Organic Synthesis, 2nd ed., Wiley, N.Y. (1997).
  • Mixing with a flammable solvent must always be carried out under an inert atmosphere.
  • Reverse addition (solvent to reagent), if done rapidly, may be safer.
  • The use of Diethoxymethane, B23134 as a reaction solvent has also been recommended.
  • Short: III/35C4

安全信息

GHS Symbol
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+340+310
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P210231+232280370+378402+404403+235
  • P422 Store contents under… 存储目录在…之下。
  • P231+232 Handle under inert gas. Protect from moisture. 在惰性气体中。防止受潮。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P305+351+338+310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+330+331+310
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P223231+232280305+351+338370+378422
  • P304+340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P335+334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. 刷掉皮肤松散颗粒。浸入冷水中/用湿绷带包扎
  • P370 In case of fire: 在发生火灾的情况下:
Signal word
  • Danger
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H318 Causes serious eye damage 严重伤害眼睛
  • H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
  • H351 Suspected of causing cancer 怀疑致癌
WGK Germany1
RTECSBD0100000
Personal Protective Equipment
  • Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
  • Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
  • Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S30 Never add water to this product 切勿将水加入该产品中;
  • S15 Keep away from heat 远离热源;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中,保持干燥;
Packing GroupI
UN Number
  • 3399
Risk Statements
  • R11 Highly flammable 非常易燃
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R34 Causes burns 会导致灼伤
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R48/20
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R20 Harmful by inhalation 吸入有害
  • R60 May impair fertility 可能降低生殖能力
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R12 Extremely flammable 极端易燃
  • R10 Flammable 易燃
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R22 Harmful if swallowed 吞咽有害
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R37 Irritating to respiratory system 刺激呼吸道
  • R35 Causes severe burns 会导致严重灼伤
Storage condition
  • 充氩储存
  • 储存温度2-8℃; 充氩储存
  • Air & Moisture Sensitive
  • 充氩密封
  • 2-8°C
Hazard Codes
  • F,C,Xi,Xn,F+
  • F,T
  • F+,Xn
  • F,C
Hazard Class4.3/3
Warnings
  • 危化品目录(2015)

其他信息

  • ⑴. 储存于阴凉、干燥、通风良好的专用库房内,远离火种、热源。库温不超过32℃,相对湿度不超过75%。包装密封。 ⑵. 应与氧化剂、酸类、醇类等分开存放,切忌混储。储区应备有合适的材料收容泄漏物。

化学结构图

CAS 16853-85-3  MFCD00011075
SMILES: [Li+].[AlH4-]

化学属性

Mol. FormulaLiAlH4
Mol. Weight37.95
Melting Point125 °C (dec.)(lit.)
Density0.906 g/mL at 25 °C
TSCAYes
SolubilityDecomposes in water. Soluble in ether
Flash Point-17 ºC
Boiling Point66
Appearance
  • tablets (~0.5 g each)
    Stability对空气和湿度敏感

    别名和识别编码

    Chemical NameLithium aluminum hydride
    Synonym
    • LITHIUM ALANATE
    • LiAlH4
    • lithiumtetrahydroaluminate
    • Lithium aluminohydride
    • LITHIUM ALUMINUM HYDRIDE
    • Lithium aluminum tetrahydride
    • lithiumaluminumhydride,ethereal
    • LAH
    • lithiumtetrahydroaluminate(lithiumaluminiumhydride)
    • LiAlH4
    • lithium aluminium hydride
    • {Chemi
    • Lithium alanate
    • 四氫化鋁鋰
    • LAH; Lithium tetrahydridoaluminate
    • LAH Lithium alanate Lithium tetrahydro
    • 四氢铝锂,四氢化铝锂,(T-4)-四氢铝酸锂
    • Aluminum lithium hydride
    • 四氢铝锂
    • Lithiumaluminiumhydrid
    • Aluminate(1-), tetrahydro-, lithium, (T-4)-
    • Lithium aluminum hydride (LiAlH4)
    • LAH Lithium alanate
    • Aluminum lithium tetrahydride
    • 氢化锂铝:四氢锂铝
    • 四氢铝酸锂
    • {C
    • {Chem
    • 氢化铝锂, 95% MIN
    • Aluminiumlithiumhydrid
    • Lithium aluminum hydride
    • Aluminate (1-), tetrahydro-, lithium
    • 氢化铝锂
    • 氢化铝锂 溶液
    • LAH Lithium alanate Lithium tetrahydroaluminate
      MDL NumberMFCD00011075
      EC Number240-877-9
      PubChem Substance ID 329761015
      CAS Number16853-85-3
      Merck Number349
      Beilstein Registry Number11460447
      Reaxys-RN11460447
      Chemical Name Translation氢化锂铝
      Wiswesser Line Notation.AL..H4.LI
      LabNetwork Molecule IDLN01341120

      系列性分类


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