(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-恶唑烷酮

CAS 17016-83-0 MFCD00010847

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI 456013
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-恶唑烷酮
98% 1g 50
96-99 %
INFI 456013
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-恶唑烷酮
98% 5g 140
96-99 %
INFI 456013
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-恶唑烷酮
98% 25g 510
96-99 %
INFI 456013
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-恶唑烷酮
98% 100g 1,650
96-99 %
INFI 456014
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-恶唑烷酮
98% 1g 350
96-99 %
INFI 456014
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-恶唑烷酮
98% 5g 1,520
96-99 %
INFI 456014
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-恶唑烷酮
98% 25g 4,900
96-99 %
Alfa 238280
(4S)-(-)-Isopropyl-2-oxazolidinone
98% 1g 44
SH-CN BJ-CN CN
中国国内现货 99
Alfa 238280
(4S)-(-)-Isopropyl-2-oxazolidinone
98% 5g 216
BJ-CN
中国国内现货 99
TCI 309944
( S )-4-Isopropyl-2-oxazolidinone >
>98.0%(GC) 1g 190
SH-CN TJ-CN BJ-CN
中国国内现货 99
TCI 309944
( S )-4-Isopropyl-2-oxazolidinone >
>98.0%(GC) 5g 490
SH-CN TJ-CN BJ-CN TK-JP
中国国内现货 99
TCI 309944
( S )-4-Isopropyl-2-oxazolidinone >
>98.0%(GC) 25g 990
SH-CN TJ-CN BJ-CN TK-JP
中国国内现货 99
J&K 382326
(S)-(-)-4-Isopropyl-2-oxazolidinone, 98%
98% 1g 393
HB
中国国内现货 99
J&K 382326
(S)-(-)-4-Isopropyl-2-oxazolidinone, 98%
98% 5g 1,693
HB
中国国内现货 99
J&K 382326
(S)-(-)-4-Isopropyl-2-oxazolidinone, 98%
98% 25g 5,445
99
TRC 80710
(S)-(-)-4-Isopropyl-2-oxazolidinone
1g 495
0
TRC 80710
(S)-(-)-4-Isopropyl-2-oxazolidinone
2.5g 659
0
TRC 80710
(S)-(-)-4-Isopropyl-2-oxazolidinone
5g 1,500
0
TRC 80710
(S)-(-)-4-Isopropyl-2-oxazolidinone
25g 2,500
0
Acros 286897
(4S)-(-)-4-Isopropyl-2-oxazolidinone, 98%
98% 1g 227
SH-CN
中国国内现货 99
Apollo 382558
(4S)-4-Isopropyl-1,3-oxazolidin-2-one
1g 297
0
Shao Yuan 389046
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-(-)-4-异丙基-2-噁唑烷酮
98% 1g 77
SH-CN
中国国内现货 99
Shao Yuan 389046
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-(-)-4-异丙基-2-噁唑烷酮
98% 5g 148
SH-CN
中国国内现货 99
Shao Yuan 389046
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-(-)-4-异丙基-2-噁唑烷酮
98% 25g 452
SH-CN
中国国内现货 99
Shao Yuan 389046
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-(-)-4-异丙基-2-噁唑烷酮
98% 100g 1,548
99
Adamas 456008
98%+ 1g 100
SH-CN BJ-CN
中国国内现货 99
Adamas 456009
98%+ 5g 180
SH-CN BJ-CN
中国国内现货 99
Adamas 456010
98%+ 25g 560
BJ-CN
中国国内现货 99
Energy-chemical 456011
(4S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-唑烷酮
98% 5g 109
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 456011
(4S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-唑烷酮
98% 25g 503
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 456011
(4S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-唑烷酮
98% 100g 1,764
CN-SH
中国国内现货 99
Aladdin 456012
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-噁唑烷酮
98% 1g 94
CN-SH
中国国内现货 99
Aladdin 456012
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-噁唑烷酮
98% 5g 108
CN-SH
中国国内现货 99
Aladdin 456012
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-噁唑烷酮
98% 25g 381
CN-SH
中国国内现货 99
Aladdin 456012
(S)-(-)-4-Isopropyl-2-oxazolidinone (S)-4-异丙基-2-噁唑烷酮
98% 100g 1,465
99
Ark 553682
98% 1g 68
99
Ark 553682
98% 5g 170
99
Ark 553682
98% 10g 272
99
Ark 553682
98% 25g 448
SH-CN
中国国内现货 99
Ark 553682
98% 100g 1,280
SH-CN
中国国内现货 99
Key Organic 571510
(4S)-4-Isopropyl-1,3-oxazolidin-2-one
>95% 5mg 735
90+%
Aladdin 673823
5g 108
BJ-CN
中国国内现货
Aladdin 673824
25g 381
BJ-CN
中国国内现货
Aladdin 673825
1g 94
BJ-CN
中国国内现货
Acros 710358
1g 331
BJ-CN
中国国内现货
Acros 710359
5g 919
BJ-CN
中国国内现货
Acros 710360
25g 7,308
Accela 710361
1g 46
BJ-CN
中国国内现货
Accela 710361
5g 102
Accela 710361
25g 358
BJ-CN
中国国内现货
Accela 710361
100g 807
BJ-CN
中国国内现货
Aldrich 710362
1g 434
Aldrich 710363
5g 2,159
Key Organics 710364
1mg 630
Key Organics 710364
5mg 735
Key Organics 710364
10mg 1,029
Key Organics 710364
25mg 1,659
Key Organics 710364
50mg 1,785
Key Organics 710364
100mg 2,478
Key Organics 710364
250mg 3,717
Key Organics 710364
25g 3,780
Key Organics 710365
25g 2,148
Key Organics 710365
100g 5,820
药明康德 710366
25g 567
Key Organic 760849
(S)-(-)-4-Isopropyl-2-oxazolidinone
>98% 25g 2,111
96-99 %
Key Organic 760849
(S)-(-)-4-Isopropyl-2-oxazolidinone
>98% 100g 5,720
96-99 %

分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Auxiliaries, Oxazolidinone Derivatives

产品应用

  • 在二铑(II)复合物中用作手性配体,在丁加醇醛(aldol)加成反应中作为手性试剂。非对称合成常用试剂。

相关文献及参考

  • Bromination (NBS), followed by azide displacement, gives a route to chiral amino acids: Tetrahedron Lett ., 28, 1123 (1987). Direct electrophilic azidation with triisopropylbenzenesulfonyl azide has also been used to effect this transformation: J. Am. Chem. Soc., 112, 4011 (1990).
  • The enolates of the N-acyloxazolidinones can also undergo a variety of other enantioselective reactions including alkylation: J. Am. Chem. Soc., 104, 1737 (1982); acylation: J. Am. Chem. Soc., 106, 1154 (1984):
  • Chiral auxiliary introduced by Evans for use in enantioselective reactions.
  • See also (S)-(-)-4-Benzyl-2-oxazolidinone, A18236.
  • Alkyl carboxamides derived from the N-acylation of the oxazolidinone form enolates which undergo highly enantioselective aldol condensation with aldehydes. The products readily undergo hydrolysis, e.g. with base, to give chiral ß -hydroxyacids, with consequent easy recovery and recycle of the chiral auxiliary: J. Am. Chem. Soc., 103, 2127 (1981); Tetrahedron, 27, 897 (1986); Tetrahedron Lett., 31, 4699 (1990); J. Org. Chem., 56, 2489 (1991). For reaction scheme, see (S)-(-)-4-Benzyl-2-oxazolidinone, A18236.

安全信息

WGK Germany3
Personal Protective Equipment
  • Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
Signal word
  • Warning
GHS Symbol
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements

其他信息

  • 不溶于水,微溶于醇。

化学结构图

CAS 17016-83-0  MFCD00010847
SMILES: CC(C)[C@H]1COC(=O)N1

化学属性

Mol. FormulaC6H11NO2
Mol. Weight129.16
Melting Point70-73 °C(lit.)
TSCANo
Solubility不溶
Density1.038

别名和识别编码

Chemical Name(S)-(-)-4-Isopropyl-2-oxazolidinone
MDL NumberMFCD00010847
PubChem Substance ID 24858002
Beilstein Registry Number3588198
CAS Number17016-83-0
Synonym
  • (S)-4-异丙基-2-噁唑烷酮
  • (S)-4-异丙基-2-恶唑烷酮
  • (S)-(-)-4-异丙基-2-噁唑烷酮
    EC Number250-023-7
    Chemical Name Translation(S)-4-异丙基-2-恶唑烷酮
    Reaxys-RN1099716

    系列性分类


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