Vinylmagnesium bromide 乙烯基溴化镁

CAS 1826-67-1 MFCD00000042

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI 377419
Vinylmagnesium bromide 乙烯基溴化镁
1.0 M solution in THF, SpcSeal 100mL 110
BY-CN LN-CN
中国国内现货 1.0 M solution 四氢呋喃
INFI 377419
Vinylmagnesium bromide 乙烯基溴化镁
1.0 M solution in THF, SpcSeal 500mL 280
BY-CN LN-CN
中国国内现货 1.0 M solution 四氢呋喃
INFI 377419
Vinylmagnesium bromide 乙烯基溴化镁
1.0 M solution in THF, SpcSeal 1L 490
BY-CN LN-CN
中国国内现货 1.0 M solution 四氢呋喃
Innochem 547958
Vinylmagnesium bromide,1.0 M solution in THF,in resealable bottle
1.0 M solution in THF,in resealable bottle 100mL 200
BJ-CN
中国国内现货 1.00 M solution in THF
Innochem 547958
Vinylmagnesium bromide,1.0 M solution in THF,in resealable bottle
1.0 M solution in THF,in resealable bottle 500mL 280
1.00 M solution in THF
Innochem 547958
Vinylmagnesium bromide,1.0 M solution in THF,in resealable bottle
1.0 M solution in THF,in resealable bottle 800mL 450
1.00 M solution in THF
TCI 159
Vinylmagnesium Bromide (14% in Tetrahydrofuran, ca . 1mol/L) >
100g 460
SH-CN BJ-CN TK-JP
中国国内现货 0
J&K 152
Vinylmagnesium bromide, 1.0 M solution in THF, J&KSeal;
N/A 100mL 120
HB
中国国内现货 0
J&K 152
Vinylmagnesium bromide, 1.0 M solution in THF, J&KSeal;
N/A 800mL 419
HB
中国国内现货 0
J&K 543473
Vinylmagnesium bromide, 1.0 M solution in 2-MeTHF, J&KSeal;
N/A 25mL 450
HB
中国国内现货 1.00 M solution in THF
J&K 543473
Vinylmagnesium bromide, 1.0 M solution in 2-MeTHF, J&KSeal;
N/A 100mL 1,142
HB
中国国内现货 1.00 M solution in THF
J&K 543473
Vinylmagnesium bromide, 1.0 M solution in 2-MeTHF, J&KSeal;
N/A 500mL 3,769
HB
中国国内现货 1.00 M solution in THF
J&K 543473
Vinylmagnesium bromide, 1.0 M solution in 2-MeTHF, J&KSeal;
N/A 800mL 5,163
HB
中国国内现货 1.00 M solution in THF
Acros 161
Vinylmagnesium bromide, 0.7M solution in THF, AcroSeal?
0.7M solution in THF, AcroSeal® 100mL 321
SH-CN BJ-CN CN
中国国内现货 0
Acros 161
Vinylmagnesium bromide, 0.7M solution in THF, AcroSeal?
0.7M solution in THF, AcroSeal® 800mL 1,397
BJ-CN CN
中国国内现货 0
Aldrich 10268
Vinylmagnesium bromide solution 乙烯基溴化镁 溶液
1.0 M in THF 200mL 1,720
0
Aldrich 10268
Vinylmagnesium bromide solution 乙烯基溴化镁 溶液
1.0 M in THF 1.8L 5,471
0
Energy-chemical 383793
Vinylmagnesium bromide 乙烯基溴化镁
1.0mol/l in THF,EnergySeal 100mL 100
0
Energy-chemical 383793
Vinylmagnesium bromide 乙烯基溴化镁
1.0mol/l in THF,EnergySeal 500mL 240
0
Energy-chemical 383793
Vinylmagnesium bromide 乙烯基溴化镁
1.0mol/l in THF,EnergySeal 800mL 780
CN-SH
中国国内现货 0
Energy-chemical 383793
Vinylmagnesium bromide 乙烯基溴化镁
1.0mol/l in THF,EnergySeal 1L 450
0
Acros 402415
AcroSeal? 100mL 477
BJ-CN
中国国内现货 0
Acros 412826
Vinylmagnesium bromide, 1M solution in 2-MeTHF, AcroSeal
100mL 1,404
SH-CN
中国国内现货 0
Acros 412826
Vinylmagnesium bromide, 1M solution in 2-MeTHF, AcroSeal
800mL 6,348
0
Aladdin 412827
Vinylmagnesium bromide solution 乙烯基溴化镁
1.0M in THF 100mL 99
CN-SH
中国国内现货 0
Aladdin 412827
Vinylmagnesium bromide solution 乙烯基溴化镁
1.0M in THF 500mL 238
CN-SH
中国国内现货 0
Aladdin 412827
Vinylmagnesium bromide solution 乙烯基溴化镁
1.0M in THF 1L 970
0
Adamas 516598
1.0 M solution in THF, SafeSeal 100mL 190
SH-CN CN
中国国内现货 1.00 M solution in THF
Adamas 516599
1.0 M solution in THF, SafeSeal 500mL 356
SH-CN CN
中国国内现货 1.00 M solution in THF
Adamas 516600
1.0 M solution in THF, SafeSeal 800mL 665
SH-CN CN
中国国内现货 1.00 M solution in THF
HY 518125
Vinylmagnesium bromide solution 乙烯基溴化镁 溶液
1.0 M solution in THF, HySeal 100mL -
1.00 M solution in THF
HY 518125
Vinylmagnesium bromide solution 乙烯基溴化镁 溶液
1.0 M solution in THF, HySeal 500mL -
1.00 M solution in THF
HY 518125
Vinylmagnesium bromide solution 乙烯基溴化镁 溶液
1.0 M solution in THF, HySeal 800mL -
1.00 M solution in THF
Meryer 559395
乙烯基溴化镁
1.0M in THF 100mL 331
0
Meryer 559395
乙烯基溴化镁
1.0M in THF 500mL 1,320
0
Aladdin 619891
500mL 238
SH-CN
中国国内现货
Aladdin 619892
100mL 99
SH-CN
中国国内现货
3A 634159
Vinylmagnesium bromide 乙烯基溴化镁
1.0 M solution in THF, SpcSeal 100ml 110
BJ-CN
中国国内现货 1.0 M solution THF
3A 634159
Vinylmagnesium bromide 乙烯基溴化镁
1.0 M solution in THF, SpcSeal 500ml 280
BJ-CN
中国国内现货 1.0 M solution THF
3A 634159
Vinylmagnesium bromide 乙烯基溴化镁
1.0 M solution in THF, SpcSeal 1L 490
1.0 M solution THF
Acros 738362
100mL 1,449
BJ-CN
中国国内现货
Acros 738363
800mL 2,435
BJ-CN
中国国内现货
Acros 738365
800mL 6,604
TRC 738367
25mL 700
TRC 738367
50mL 1,050
TRC 738367
100mL 1,750
TRC 738367
250mL 3,500
Aldrich 738368
1.8L 5,307
Aldrich 738369
4x100mL 1,211
Aldrich 738370
100mL 402
BJ-CN
中国国内现货
Aldrich 738371
200mL 1,674
Aldrich 738372
800mL 1,348
3A 771102
Vinylmagnesium bromide 乙烯基溴化镁
1.0 M solution in THF, 3ASeal 100mL 110
0
3A 771102
Vinylmagnesium bromide 乙烯基溴化镁
1.0 M solution in THF, 3ASeal 500mL 280
0
3A 771102
Vinylmagnesium bromide 乙烯基溴化镁
1.0 M solution in THF, 3ASeal 1L 490
0

分类

  • {uni_hamburg} no charge; metal-organic; 1fragment
  • {SNA} Alkenyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
  • Alkenyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

产品应用

  • ⑴. 由于镁原子直接和碳链相连,极化作用使邻近镁原子的那个碳原子呈负电性,使得C-Mg键极具反应活性。为了保证该产品不发生其他反应,反应一般在醚类溶剂里进行,常用的有乙醚或四氢呋喃。 ⑵. 有强烈的亲核性质,可与物质中的活泼氢(如水、乙醇的羟基氢、乙炔的末端氢)反应,生成相应的烃基。 ⑶. 与CO2或O2的反应,可以与二氧化碳或氧气发生亲核加成反应生成增加一个碳的羧酸或同碳数的过氧化合物.格氏试剂与二氧化碳的加成反应在有机合成中也有着重要的意义,不仅通过生成新的 C-C 键实现了碳链的增长,而且恰到好处地

相关文献及参考

  • Aldrich MSDS 1 , 1837:D / Corp MSDS 1 (2), 3605:B / Structure Index 1 , 483:B:6
  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Signal word
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S29 Do not empty into drains 不要排入下水道;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P304+340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P422 Store contents under… 存储目录在…之下。
  • P231+232 Handle under inert gas. Protect from moisture. 在惰性气体中。防止受潮。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+340+310
  • P241+242+243
  • P261305+351+338
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P305+351+338+310
Storage condition
  • 0-10
  • 储存温度2-8℃,充氩保存
  • 储存温度2-8°C
  • 0-10°C
  • Refrigerator
UN Number
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment
  • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
  • F,C
Packing GroupII
Hazard Class4.3/3

其他信息

  • ⑴. 该品在启用过程中应最大限度的隔绝空气和水份,密封保存在低温、干燥,有氮气保护的容器中。 ⑵.不宜长时间存放。

化学结构图

CAS 1826-67-1  MFCD00000042
SMILES: C=C[Mg]Br

化学属性

Mol. FormulaCH2=CHMgBr
Mol. Weight131.25
Density0.981 g/mL at 25 °C
Flash Point-17 ºC
Solubility剧烈反应
Stability对热和湿度敏感

别名和识别编码

Chemical NameVinylmagnesium bromide
CAS Number1826-67-1
EC Number217-375-3
Beilstein Registry Number3535841
MDL NumberMFCD00000042
Reaxys-RN3535841
PubChem Substance ID 24853507
Synonym
  • Norman reagent
  • Ethenylmagnesium bromide
  • Vinyl magnesium bromide
  • VINYLMAGNESIUM BROMIDE
  • Vinyl-magnesium bromide
  • 0.98g/ml,20℃
  • VINYLMAGNESIUM BROMIDE SOLUTION, ~1.0 M IN THF
  • 乙烯基溴化镁四氢呋喃溶液
  • VINYLMAGNESIUMBROMICLC
  • Vinylmagnesium bromide
  • Bromovinylmagnesium
  • Vinylmagnesium bromide0.7M solution in THFAcroSeal§3
  • Vinylmagnesium bromide(1.0mol/Lsolytion in tetrahydro-furan)
  • Bromvinylmagnesium
  • bromoethenyl-magnesiu
  • Magnesium, bromovinyl-
  • Vinylmagnesium Bromide 0.7 M in Tetrahydrofuran
  • Vinylmagnesium bromide, 0.8-1.0 M in THF
  • 乙烯基溴化镁
  • Vinylmagnesium Bromide (14% in Tetrahydrofuran, ca. 1mol/L)
  • VINYLMAGNESIUM BROMIDE, 1.0M SOLUTION IN TETRAHYDROFURAN
  • 溴化乙烯基镁
  • 乙烯基溴化镁;溴化乙烯镁
  • Vinylmagnesium bromide, 0.8-1.0 M in THF, packaged under Argon in resealable ChemSeal bottles
  • vinylmagnesiumbromidesolution
  • bromovinylmagnesium
  • 溴化乙烯鎂
  • Vinylmagnesium bromide, 0.7M solution in THF
  • 溴化乙烯镁四氢呋喃溶液
  • 溴化乙烯镁(1MOL/L四氢呋喃溶液)
  • 乙烯基溴化镁 溶液
  • Magnesium, bromoethenyl-
    Chemical Name Translation乙烯基溴化镁
    InChIKeyXHHHAXOHMKAOSL-UHFFFAOYSA-M
    LabNetwork Molecule IDLN00223958

    系列性分类


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