Phosphine oxide, diphenylmethyl- 甲基(二苯基)氧化膦

CAS 2129-89-7 MFCD00002081

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H29828
Methyldiphenylphosphine oxide 甲基二苯基氧化膦
98% 1g 60
LN-CN
中国国内现货 96-99 %
INFI H29828
Methyldiphenylphosphine oxide 甲基二苯基氧化膦
98% 5g 180
LN-CN
中国国内现货 96-99 %
INFI H29828
Methyldiphenylphosphine oxide 甲基二苯基氧化膦
98% 25g 580
LN-CN
中国国内现货 96-99 %
INFI H78581
Methyldiphenylphosphine oxide 甲基(二苯基)氧化膦
98% 5g 260
96-99 %
INFI H78581
Methyldiphenylphosphine oxide 甲基(二苯基)氧化膦
98% 25g 950
96-99 %
TCI D2445
Methyl(diphenyl)phosphine Oxide >
>98.0%(GC) 10g 640
SH-CN TJ-CN BJ-CN TK-JP
中国国内现货 99
Alfa A11484
Methyldiphenylphosphine oxide
98+% 5g 353
SH-CN BJ-CN
中国国内现货 99
Alfa A11484
Methyldiphenylphosphine oxide
98+% 25g 1,064
SH-CN BJ-CN
中国国内现货 99
J&K 536265
Methyldiphenylphosphine oxide, 98%
98% 5g 340
HB SH
中国国内现货 96-99 %
J&K 536265
Methyldiphenylphosphine oxide, 98%
98% 25g 1,179
SH
中国国内现货 96-99 %
Matrix 097538
Methyldiphenylphosphine oxide
95+% 5g 195
99
Matrix 097538
Methyldiphenylphosphine oxide
95+% 10g 299
99
Matrix 097538
Methyldiphenylphosphine oxide
95+% 25g 585
99
Aladdin M137520
Methyl diphenyl phosphine oxide 甲基二苯基氧膦
≥98.0%(GC) 5g 156
CN-SH
中国国内现货 96-99 %
Aladdin M137520
Methyl diphenyl phosphine oxide 甲基二苯基氧膦
≥98.0%(GC) 25g 903
CN-SH
中国国内现货 96-99 %
Meryer M10580
Methyl diphenyl phosphine oxide
98% 5g 246
96-99 %
Meryer M10580
Methyl diphenyl phosphine oxide
98% 25g 968
96-99 %
Shao Yuan SY049475
98% 10g 636
96-99 %
3A A00425
Methyldiphenylphosphine oxide 甲基二苯基氧化膦
98% 1g 90
96-99 %
3A A00425
Methyldiphenylphosphine oxide 甲基二苯基氧化膦
98% 5g 280
96-99 %
3A A00425
Methyldiphenylphosphine oxide 甲基二苯基氧化膦
98% 25g 980
96-99 %
Aladdin M137520-25g
25g 903
SH-CN BJ-CN
中国国内现货
Aladdin M137520-5g
5g 156
SH-CN BJ-CN
中国国内现货
TRC M219488
100mg 560
TRC M219488
500mg 770
TRC M219488
1g 1,120
Aladdin M137520-10g
10g 429
Accela SY049475
10g 636
Aldrich 454427-5G
5g 627
Aldrich 454427-25G
25g 1,983

分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: EINECS
  • Short: III/35D2
  • The lithiated derivative undergoes Horner olefination reactions with carbonyl compounds to give, after dehydration, vinyl or allyl phosphine oxides: Synthesis, 64 (1988). The reaction has been use in a useful synthesis of (3Z,6E)-ɑ-farnesene: J. Org. Chem., 60, 6211 (1995); for reaction scheme see Geranyl­ bromide, A14093. Epoxides give -hydroxy propylphosphine oxides: J. Chem. Soc., Perkin 1, 2971 (1988); see also: J. Chem. Soc., Perkin 1, 1963 (1999).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P332+313 IF SKIN irritation occurs: Get medical advice/attention. 如果发生皮肤刺激:获取医疗咨询/就医。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P301+312+330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P302+350 IF ON SKIN: Gently wash with plenty of soap and water. 如果在皮肤上:轻轻地用大量肥皂和水清洗
  • P337+313 IF eye irritation persists: Get medical advice/attention. 如果眼睛刺激持续:获取医疗咨询/就医。
  • P305+351+338+337+313
Signal word
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
RTECSSZ0199480
Personal Protective Equipment
  • dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
Storage condition
  • Moisture Sensitive
Hazard Codes
  • Xn
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 840 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KHFZAN Khimiko-Farmatsevticheskii Zhurnal.  Chemical Pharmaceutical Journal.
    For English translation, see PCJOAU.  (V/O Mezhdunarodnaya Kniga, 113095
   Moscow, USSR)  V.1-    1967-  Volume(issue)/page/year: 24(4),22,1990

其他信息

  • MOL 文件:2129-89-7.mol
  • Sigma Aldrich:2129-89-7(sigmaaldrich)
  • Alfa Aesar:甲基二苯基氧膦,98+% Methyldiphenylphosphine oxide, 98+%(2129-89-7)
  • TCI Shanghai:甲基二苯基氧化膦 Methyl(diphenyl)phosphine Oxide,>;98.0%(GC)(2129-89-7)
  • 图谱信息:甲基二苯基氧化膦(2129-89-7)核磁图( 1 HNMR) 甲基二苯基氧化膦(2129-89-7)质谱(MS) 甲基二苯基氧化膦(2129-89-7)红外图谱(IR2) 甲基二苯基氧化膦(2129-89-7)核磁图( 13 CNMR) 甲基二苯基氧化膦(2129-89-7)红外图谱(IR1)
  • 敏感性:Moisture Sensitive
  • 甲基二苯基氧化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D2445 甲基(二苯基)氧化膦 Methyl(diphenyl)phosphine Oxide 10G 691元 2010/05/25 A11484 甲基二苯基氧膦, 98+% Methyldiphenylphosphine oxide, 98+% 5g 288元 2010/05/25 A11484 甲基二苯基氧膦, 98+% Methyldiphenylphosphine oxide, 98+% 25g 1064元
  • 甲基二苯基氧化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2445 甲基(二苯基)氧化膦 Methyl(diphenyl)phosphine Oxide 10G 636元 2010/05/25 A11484 甲基二苯基氧膦, 98+% Methyldiphenylphosphine oxide, 98+% 5g 288元 2010/05/25 A11484 甲基二苯基氧膦, 98+% Methyldiphenylphosphine oxide, 98+% 25g 1064元

化学结构图

CAS 2129-89-7  MFCD00002081
SMILES: CP(=O)(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC13H13OP
Mol. Weight216.22
Melting Point111.0 to 115.0 deg-C
TSCANo
Boiling Point180°C/1mmHg(lit.)

别名和识别编码

Chemical NameMethyldiphenylphosphine oxide
Synonym
  • Diphenylmethylphosphine oxide Methyldiphenyloxophosphine NSC 407134
  • NSC 407134
  • METHYLDIPHENYLPHOSPHINE OXIDE
  • diphenylmethylphosphineoxide
  • 甲基二苯基氧化膦
  • methyl-diphenyl-phosphane oxide
  • AURORA KA-1600
  • diphenylmethyl-phosphineoxid
  • Methyldiphenylphosphine oxide
  • Methyl(diphenyl)phosphine oxide
  • Methyl diphenyl phosphine oxide, 98+%
  • Methyldiphenyloxophosphine
  • Diphenylmethylphosphine oxide
  • 甲基二苯基膦化氧
  • Diphenyl-methylphosphinoxid
  • Phosphine oxide, methyldiphenyl-
  • (C6H5)2(CH3)P=O
  • methyl-diphenyl-phosphine oxide
  • 甲基二苯基氧膦, 98+%
    MDL NumberMFCD00002081
    CAS Number2129-89-7
    PubChem Substance ID 87568872
    EC Number218-346-8
    Beilstein Registry Number957291
    Reaxys-RN957291
    Chemical Name Translation甲基(二苯基)氧化膦
    InChIKeyPEGCITODQASXKH-UHFFFAOYSA-N

    系列性分类


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