L-(+)-Tartaric acid diisopropyl ester (+)-L-酒石酸-二异丙酯

CAS 2217-15-4 MFCD00064450

化学结构图

2217-15-4
SMILES: CC(C)OC(=O)[C@H](O)[C@@H](O)C(=O)OC(C)C

化学属性

Mol. FormulaC10H18O6
Mol. Weight234
Density1.140
Boiling Point275
Refractive index1.4380 to 1.4400
Flash Point110°C(lit.)
TSCANo
Stability易吸潮
pH:A

别名和识别编码

Chemical NameL-(+)-Tartaric acid diisopropyl ester
Synonym (+)-DIPT Diisopropyl L-(+)-tartrate (+)-diisopropyl L-tartrate Lg-threaric acid diisopropyl ester DIISOPROPYL L-TARTRATE 2,3-dihydroxy- (R-(R*,R*))-butanedioic acid, bis(1-methylethyl) ester L(+)-Weinsäurediisopropylester Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, bis(1-methylethyl) ester (2R,3R)-(+)-diisopropyl tartrate (+)-L-TARTARIC ACID DIISOPROPYL ESTER d(+)-tartaric acid diisopropyl ester 2,3-dihydroxy- R-R*,R*-butanedioic acid, bis1-methylethyl ester (2R,3R)-(+)-Diisopropyltartrat Diisopropyl L-(+)-tartarate L-Tartaric acid diisopropyl ester {uni_hambur L(+)-DIISOPROPYL TARTRATE L-(+)-Diisopropyl tartrate DIISOPROPYL L-(+)-TARTRATE DIISOPROPYL (2R,3R)-2,3-DIHYDROXYSUCCINATE Diisopropyl (2R,3R)-tartrate Diisopropyl (+)-L-tartrate Tartaricacid,diisopropyle (+)-二异丙酯-L-(+)-酒石酸 Lg-threaricaciddiisopropylester 2,3-dihydroxy-succinicaciddiisopropylester {C Weinsäuredipropylester L-(+)-Tartaric acid diisopropyl ester L-(+)-TARTARIC ACID DIISOPROPYL ESTER Butanedioic acid, 2,3-dihydroxy-[R-(R*,R*)]-, bis(1-methyle tartaricaciddiisopropylester 二异丙基酒石酸 Lg-tartaric acid diisopropyl ester dii (R,R)-2,3-dihydroxy-succinicaciddiisopropylester L-DI Lg-tartaricaciddiisopropylester L-(+)-酒石酸二异丙酯 Butanedioic acid, 2,3-dihydroxy- [R-(R Diisopropyl R,R-tartrate (R,R)-2,3-dihydroxy-succinic acid diisopropyl ester L-酒石酸二
CAS Number2217-15-4
EC Number218-709-0
Beilstein Registry Number1727863
MDL NumberMFCD00064450
PubChem Substance ID6453580
Chemical Name Translation(+)-L-酒石酸-二异丙酯
Reaxys-RN1727863
InChIKeyXEBCWEDRGPSHQH-HTQZYQBOSA-N
Wiswesser Line Notation1Y1&OVYQYQVOY1&1
LabNetwork Molecule IDLN00201300
InChIInChI=1S/C10H18O6/c1-5(2)15-9(13)7(11)8(12)10(14)16-6(3)4/h5-8,11-12H,1-4H3/t7-,8-/m1/s1
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分类

  • {uni_hamburg} no charge; ester; alcohol; chiral; 1fragment
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Epoxidation, Esters, Organic Building Blocks

产品应用

  • 用于有机合成。制备手性化合物。通过对映选择环氧化作用，用作外消旋烯丙基醇类的动力拆分。

相关文献及参考

  • Chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols; see tert-Butyl­ hydroperoxide, A13926.
  • Beilstein:3(2)331
  • Short: EINECS
  • Short: IV/1b
  • Short: IV/18B
  • Short: IV/20B

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
RTECSWW8100000
Personal Protective Equipment Eyeshields, Gloves
Storage condition 易吸潮，密封保存。 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 93,26,1948

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >10 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 93,26,1948

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 6300 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 93,26,1948

其他信息

  • 图谱信息:L-(+)-酒石酸二异丙酯(2217-15-4)Raman光谱 L-(+)-酒石酸二异丙酯(2217-15-4)核磁图( 13 CNMR) L-(+)-酒石酸二异丙酯(2217-15-4)红外图谱(IR1) L-(+)-酒石酸二异丙酯(2217-15-4)质谱(MS)
  • 海关编码:29181300
  • 比旋光度:17.25 ° (neat)
  • MOL 文件:2217-15-4.mol
  • TCI Shanghai:L-(+)-酒石酸二异丙酯 Diisopropyl L-(+)-Tartrate,>;98.0%(GC)(2217-15-4)
  • L-(+)-酒石酸二异丙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0621 L-(+)-酒石酸二异丙酯 Diisopropyl L-(+)-Tartrate 25G 279元 2014/06/02 T0621 L-(+)-酒石酸二异丙酯 Diisopropyl L-(+)-Tartrate 500G 2370元 2010/06/21 212030050 L-(+)-酒石酸二异丙酯 (+)-Diisopropyl L-tartrate 99% 5 GR 108元
  • Acros Organics:L-酒石酸二异丙酯 (+)-Diisopropyl L-tartrate, 99%(2217-15-4)
  • 敏感性:Hygroscopic
  • MSDS 信息:(+)-Diisopropyl L-tartrate(2217-15-4).msds
  • Sigma Aldrich:2217-15-4(sigmaaldrich)
  • 用途一:用于有机合成。制备手性化合物。通过对映选择环氧化作用，用作外消旋烯丙基醇类的动力拆分。
  • Alfa Aesar:L-(+)-酒石酸二异丙酯,98+% (+)-Diisopropyl L-tartrate, 98+%(2217-15-4)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Deprotonation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Epoxidation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Epoxidation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Carboxylic Acids - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Epoxides 环氧化物

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