Cyclopropylmagnesium bromide 环丙基溴化镁

CAS 23719-80-4 MFCD00672094

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI 377446
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 100mL 180
BY-CN LN-CN
中国国内现货 0.5 M solution 四氢呋喃
INFI 377446
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 500mL 490
LN-CN
中国国内现货 0.5 M solution 四氢呋喃
INFI 377446
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 1L 850
LN-CN
中国国内现货 0.5 M solution 四氢呋喃
INFI 384345
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in THF, SpcSeal 100mL 260
LN-CN
中国国内现货 1.0 M solution 四氢呋喃
INFI 384345
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in THF, SpcSeal 500mL 750
LN-CN
中国国内现货 1.0 M solution 四氢呋喃
INFI 552063
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in 2-Methyl-THF, SpcSeal 100mL 240
LN-CN
中国国内现货 0.5 M solution 二甲基四氢呋喃
INFI 552063
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in 2-Methyl-THF, SpcSeal 500mL 690
LN-CN
中国国内现货 0.5 M solution 二甲基四氢呋喃
INFI 552063
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in 2-Methyl-THF, SpcSeal 1L 1,180
LN-CN
中国国内现货 0.5 M solution 二甲基四氢呋喃
INFI 552066
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 100mL 320
0.5 M solution 四氢呋喃
INFI 552066
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 500mL 820
0.5 M solution 四氢呋喃
INFI 552066
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 800mL 1,120
0.5 M solution 四氢呋喃
INFI 622921
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in 2-Methyl-THF, SpcSeal 100mL 290
1.0 M solution 二甲基四氢呋喃
INFI 622921
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in 2-Methyl-THF, SpcSeal 500mL 860
LN-CN
中国国内现货 1.0 M solution 二甲基四氢呋喃
INFI 622921
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in 2-Methyl-THF, SpcSeal 1L 1,580
1.0 M solution 二甲基四氢呋喃
Innochem 546330
Cyclopropylmagnesium bromide, 1.0 M solution in THF, in resealable bottle
100mL 380
1.0 M solution 四氢呋喃
Innochem 546330
Cyclopropylmagnesium bromide, 1.0 M solution in THF, in resealable bottle
500mL 1,120
1.0 M solution 四氢呋喃
Innochem 546330
Cyclopropylmagnesium bromide, 1.0 M solution in THF, in resealable bottle
800mL 1,540
1.0 M solution 四氢呋喃
Innochem 546331
100mL 320
Innochem 546331
500mL 820
Innochem 546331
800mL 1,120
Alfa 239036
Cyclopropylmagnesium bromide
0.5M-0.7M in THF 25mL 925
SH-CN BJ-CN CN
中国国内现货 0.5 M solution THF
Alfa 239036
Cyclopropylmagnesium bromide
0.5M-0.7M in THF 100mL 2,586
SH-CN BJ-CN CN
中国国内现货 0.5 M solution THF
TCI 316580
Cyclopropylmagnesium Bromide ( ca . 10% in Tetrahydrofuran, ca . 0.7mol/L) >
ca. 10% in Tetrahydrofuran, ca. 0.7mol/L 100g 1,200
SH-CN BJ-CN CN TK-JP
中国国内现货 10+ % solution THF
Alfa 375366
Cyclopropylmagnesium bromide, 0.5M in MeTHF
50mL 1,806
SH-CN BJ-CN
中国国内现货 0.5 M solution 四氢呋喃
Alfa 375366
Cyclopropylmagnesium bromide, 0.5M in MeTHF
100mL 2,884
SH-CN BJ-CN
中国国内现货 0.5 M solution 四氢呋喃
Alfa 487677
1.0M in 2-MeTHF 25mL 862
SH-CN BJ-CN
中国国内现货 1.0 M solution 四氢呋喃
Alfa 487677
1.0M in 2-MeTHF 100mL 2,421
1.0 M solution 四氢呋喃
J&K 280482
Cyclopropylmagnesium bromide, 0.5 M solution in THF, J&KSeal;
N/A 100mL 286
0.5 M solution THF
J&K 280482
Cyclopropylmagnesium bromide, 0.5 M solution in THF, J&KSeal;
N/A 500mL 1,425
HB
中国国内现货 0.5 M solution THF
J&K 544282
Cyclopropylmagnesium bromide, 1.0 M solution in 2-MeTHF, J&KSeal;
N/A 25mL 1,081
HB
中国国内现货 1.0 M solution 四氢呋喃
J&K 544282
Cyclopropylmagnesium bromide, 1.0 M solution in 2-MeTHF, J&KSeal;
N/A 100mL 3,033
HB
中国国内现货 1.0 M solution 四氢呋喃
Acros 289802
Cyclopropylmagnesium bromide, 0.5M solution in THF, AcroSeal?
0.5M solution in THF, AcroSeal® 100mL 1,415
SH-CN CN
中国国内现货 0.5 M solution THF
Aldrich 357174
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran 1.0?M in 2-methyltetrahydrofuran 25mL 1,218
1.0 M solution 2-Methyl-THF
Aldrich 357174
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran 1.0?M in 2-methyltetrahydrofuran 100mL 3,415
1.0 M solution 2-Methyl-THF
Energy-chemical 398082
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0mol/L in THF,EnergySeal 100mL 295
CN-BJ CN-SH
中国国内现货 1.0 M solution THF
Energy-chemical 398082
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0mol/L in THF,EnergySeal 500mL 845
CN-BJ CN-SH
中国国内现货 1.0 M solution THF
Energy-chemical 398082
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0mol/L in THF,EnergySeal 1L 1,570
CN-SH
中国国内现货 1.0 M solution THF
Aladdin 398083
Cyclopropylmagnesium Bromide 环丙基溴化镁
1mol/L in THF 25mL 790
CN-SH
中国国内现货 1.0 M solution 四氢呋喃
Aladdin 398083
Cyclopropylmagnesium Bromide 环丙基溴化镁
1mol/L in THF 100mL 129
CN-SH
中国国内现货 1.0 M solution 四氢呋喃
Aladdin 398083
Cyclopropylmagnesium Bromide 环丙基溴化镁
1mol/L in THF 500mL 842
CN-SH
中国国内现货 1.0 M solution 四氢呋喃
Aladdin 398083
Cyclopropylmagnesium Bromide 环丙基溴化镁
1mol/L in THF 1L 1,564
1.0 M solution 四氢呋喃
Acros 402290
AcroSeal? 800mL 6,645
Acros 414884
Cyclopropylmagnesium bromide, 0.5M solution in 2-MeTHF, AcroSeal?
1item 1,248
0.5 M solution 四氢呋喃
Acros 414884
Cyclopropylmagnesium bromide, 0.5M solution in 2-MeTHF, AcroSeal?
100mL 919
SH-CN
中国国内现货 0.5 M solution 四氢呋喃
Acros 414884
Cyclopropylmagnesium bromide, 0.5M solution in 2-MeTHF, AcroSeal?
800mL 4,618
0.5 M solution 四氢呋喃
Shao Yuan 414885
0.5MinTHF 500mL 1,937
HY 518152
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
0.5 M solution in THF, HySeal 100mL -
0.5 M solution THF
HY 518152
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
0.5 M solution in THF, HySeal 500mL -
0.5 M solution THF
HY 518152
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
0.5 M solution in THF, HySeal 800mL -
0.5 M solution THF
HY 518198
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M solution in THF, HySeal 100mL -
1.0 M solution THF
HY 518198
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M solution in THF, HySeal 500mL -
1.0 M solution THF
HY 518198
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M solution in THF, HySeal 800mL -
1.0 M solution THF
Adamas 521879
1.0 M solution in THF, SafeSeal 100mL 360
SH-CN BJ-CN
中国国内现货 1.0 M solution THF
Adamas 521880
0.5 M solution in THF, SafeSeal 500mL 855
0.5 M solution THF
Adamas 521881
0.5 M solution in THF, SafeSeal 800mL 1,230
0.5 M solution THF
Adamas 521882
1.0 M solution in THF, SafeSeal 800mL 1,700
1.0 M solution THF
Adamas 521883
1.0 M solution in THF, SafeSeal 500mL 980
1.0 M solution THF
Adamas 521884
0.5 M solution in THF, SafeSeal 100mL 332
SH-CN BJ-CN CN
中国国内现货 0.5 M solution THF
HY 524134
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran 25mL -
1.0 M solution 2-Methyl-THF
HY 524134
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran 100mL -
1.0 M solution 2-Methyl-THF
HY 524135
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran HySeal 25mL -
1.0 M solution 2-Methyl-THF
HY 524135
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran HySeal 100mL -
1.0 M solution 2-Methyl-THF
HY 524135
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran HySeal 500mL -
1.0 M solution 2-Methyl-THF
HY 524135
Cyclopropylmagnesium bromide solution 环丙基溴化镁 溶液
1.0 M in 2-methyltetrahydrofuran HySeal 800mL -
1.0 M solution 2-Methyl-THF
Meryer 559323
环丙基溴化镁
1mol/L THF溶液 100mL 569
1.0 M solution 四氢呋喃
Meryer 559323
环丙基溴化镁
1mol/L THF溶液 500mL 1,511
1.0 M solution 四氢呋喃
Acros 591351
100mL 857
Energy-chemical 594130
Cyclopropylmagnesium bromide 环丙基溴化镁
100mL 198
CN-BJ CN-SH
中国国内现货
Energy-chemical 594130
Cyclopropylmagnesium bromide 环丙基溴化镁
500mL 545
CN-BJ CN-SH
中国国内现货
Energy-chemical 594130
Cyclopropylmagnesium bromide 环丙基溴化镁
1L 975
CN-SH
中国国内现货
3A 634040
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in THF, SpcSeal 100ml 260
1.0 M solution THF
3A 634040
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in THF, SpcSeal 500ml 750
1.0 M solution THF
3A 634040
Cyclopropylmagnesium bromide 环丙基溴化镁
1.0 M solution in THF, SpcSeal 1L 1,320
1.0 M solution THF
3A 634056
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 100ml 180
0.5 M solution THF
3A 634056
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 500ml 490
0.5 M solution THF
3A 634056
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in THF, SpcSeal 1L 850
0.5 M solution THF
3A 634351
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in 2-Methyl-THF, SpcSeal 100ml 240
0.5 M solution 2-Methyl-THF
3A 634351
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in 2-Methyl-THF, SpcSeal 500ml 690
BJ-CN
中国国内现货 0.5 M solution 2-Methyl-THF
3A 634351
Cyclopropylmagnesium bromide 环丙基溴化镁
0.5 M solution in 2-Methyl-THF, SpcSeal 1L 1,180
0.5 M solution 2-Methyl-THF
Aladdin 672831
100mL 271
SH-CN BJ-CN
中国国内现货
Aladdin 672832
500mL 842
SH-CN BJ-CN
中国国内现货
Acros 687665
100mL 1,273
BJ-CN
中国国内现货
Acros 687666
100mL 1,472
BJ-CN
中国国内现货
Aladdin 687668
25mL 359
BJ-CN
中国国内现货
Aldrich 687669
25mL 1,252
Aldrich 687670
100mL 3,054
Aldrich 687671
100mL 3,510
Aldrich 687672
800mL 18,732

分类

  • {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
  • {SNA} 12 Principles Aligned Products, Alkyl, Chemical Synthesis, Greener Alternative Products, Grignard Reagents, Organometallic Reagents, Synthetic Reagents

产品应用

  • ⑴. 由于镁原子直接和碳链相连,极化作用使邻近镁原子的那个碳原子呈负电性,使得C-Mg键极具反应活性。为了保证该产品不发生其他反应,反应一般在醚类溶剂里进行,常用的有乙醚或四氢呋喃。 ⑵. 有强烈的亲核性质,可与物质中的活泼氢(如水、乙醇的羟基氢、乙炔的末端氢)反应,生成相应的烃基。 ⑶. 与CO2或O2的反应,可以与二氧化碳或氧气发生亲核加成反应生成增加一个碳的羧酸或同碳数的过氧化合物.格氏试剂与二氧化碳的加成反应在有机合成中也有着重要的意义,不仅通过生成新的 C-C 键实现了碳链的增长,而且恰到好处地

安全信息

WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Packing GroupI
UN Number
  • 3399
Risk Statements
Storage condition
  • Air & Moisture Sensitive
  • 储存温度2-8℃,充氩保存
Signal word
GHS Symbol
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P305+351+338+310
  • P210223261280305+351+338310
  • P210261280305+351+338
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+330+331+310
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P422 Store contents under… 存储目录在…之下。
  • P231+232 Handle under inert gas. Protect from moisture. 在惰性气体中。防止受潮。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P261305+351+338
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P304+340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P335+334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. 刷掉皮肤松散颗粒。浸入冷水中/用湿绷带包扎
  • P308 IF exposed or concerned: 如果接触或涉及
Hazard Codes
  • F,C
  • F,Xi
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
Hazard Class4.3/3

其他信息

  • ⑴. 该品在启用过程中应最大限度的隔绝空气和水份,密封保存在低温、干燥,有氮气保护的容器中。 ⑵.不宜长时间存放。

化学结构图

CAS 23719-80-4  MFCD00672094
SMILES: Br[Mg]C1CC1

化学属性

Mol. FormulaC3H5BrMg
Mol. Weight145.28
Density0.968 g/mL at 25 °C
Boiling Point65 °C
Flash Point-17°C(lit.)
TSCANo
Stability空气及湿度敏感

别名和识别编码

Chemical NameCyclopropylmagnesium bromide
MDL NumberMFCD00672094
PubChem Substance ID 87558777
CAS Number23719-80-4
EC Number250-023-7
Beilstein Registry Number2384789
Synonym
  • Cyclopropylmagnesium Bromide, 0.5 M in Tetrahydrofuran
  • Cyclopropylmagnesium Bromide 0.75 M In Tetrahydrofuran
  • Cyclopropylmagnesium Bromide (15% in Tetrahydrofuran, ca. 1mol/L)
  • 环丙基溴化镁 溶液
  • Cyclopropylmagnesium bromide, ca 0.5M in THF
  • 环丙基溴化镁, 0.5M于THF中
  • Cyclopropylbromomagnesium
  • CYCLOPROPYLMAGNESIUM BROMIDE
  • CYCLOPROPYLMAGNESIUM BROMIDE, 0.5 M IN THF
  • 环丙基溴化镁
  • Bromocyclopropylmagnesium
  • cyclopropylmagnesium bromide solution
    Reaxys-RN3647938
    Chemical Name Translation环丙基溴化镁
    LabNetwork Molecule IDLN01314448

    系列性分类


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