Allylmagnesium chloride 烯丙基氯化镁

CAS 2622-05-1 MFCD00000473

化学结构图

2622-05-1
SMILES: C=CC[Mg]Cl

化学属性

Mol. FormulaC3H5ClMg
Mol. Weight100.83
Density1.01
Flash Point-17 ºC
Melting Point-21°C
Boiling Point66°C
Solubility剧烈反应
TSCAYes
Density1.01
Mol. Weight101

别名和识别编码

Chemical NameAllylmagnesium chloride
CAS Number2622-05-1
EC Number250-023-7
Beilstein Registry Number3587316
MDL NumberMFCD00000473
PubChem Substance ID75804
Synonym chloro-2-propenyl-magnesiu Allylchloromagnesium Allylmagnesium chloride, 1.7M solution in THF 烯丙基氯化镁 溶液 ALLYLMAGNESIUM CHLORIDE Allylmagnesium Chloride 1.5 M in Tetrahydrofuran 氯丙烯镁 烯丙基氯化镁(订作2周) 烯丙基氯化镁 Chloroallylmagnesium Allylmagnesium chloride solution Allylmagnesium chloride1.7M solution in THFAcroSeal§3 丙烯基氯化镁 Magnesium, chloro-2-propenyl- 氯丙烯镁; 丙烯基氯化镁 ALLYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N TETRAHYDROFURAN 2-Propenylmagnesium chloride ALLYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I Allylmagnesium Chloride (10% in Tetrahydrofuran, ca. 1mol/L) Allylmagnesiumchlorid ALLYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF 烯丙基氯化镁(10%的四氢呋喃溶液,约1MOL/L) solutionpurum,2mintetrahydrofuran Allylmagnesium Chloride 1.0 M In Tetrahydrofuran
Reaxys-RN3693919
Chemical Name Translation烯丙基氯化镁
InChIKeyPLYLAFITHJUEGX-UHFFFAOYSA-M
LabNetwork Molecule IDLN01314288
InChIInChI=1S/C3H5.ClH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q-1;;+2/p-1
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分类

  • {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

产品应用

  • Grignard 试剂

相关文献及参考

  • Beilstein:4(3)1995

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中;
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中,保持干燥;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P231+P232
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P310
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 4.3 F,C
UN Number 3399
Packing GroupI
Storage condition water-free area Air & Moisture Sensitive
Hazard Class4.3/3

其他信息

  • EPA化学物质信息:Magnesium, chloro-2-propenyl-(2622-05-1)
  • 和水剧烈反应。
  • HazardClass:4.2
  • MOL 文件:2622-05-1.mol
  • F:1-3-10
  • 氯丙烯镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 XW26220511 烯丙基氯化镁 100ml 298元 2011/08/23 XW26220512 烯丙基氯化镁 500ml 698元 2011/04/16 A1554 烯丙基氯化镁(约9%的四氢呋喃溶液,约0.8mol/L) Allylmagnesium Chloride (ca. 9% in Tetrahydrofuran, ca. 0.8mol/L) 100G 691元
  • PackingGroup:I

系列性分类


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