Phosphine, tricyclohexyl- 三环己基磷

CAS 2622-14-2 MFCD00003853

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H23635
Tricyclohexylphosphine 三环己基膦
96% 5g 130
LN-CN
中国国内现货 96-99 %
INFI H23635
Tricyclohexylphosphine 三环己基膦
96% 25g 360
LN-CN
中国国内现货 96-99 %
INFI H23635
Tricyclohexylphosphine 三环己基膦
96% 100g 1,170
96-99 %
INFI H82628
Tricyclohexylphosphine 三环己基磷
1.0 M solution in THF, SpcSeal 50mL 980
1.0 M solution 四氢呋喃
INFI H82628
Tricyclohexylphosphine 三环己基磷
1.0 M solution in THF, SpcSeal 100mL 1,580
1.0 M solution 四氢呋喃
Innochem T1201
¥1000.00
Tricyclohexylphosphine, 97% 三环己基磷 5g 620
96-99 %
Innochem T1201
¥1000.00
Tricyclohexylphosphine, 97% 三环己基磷 10g 1,000
96-99 %
Innochem T1201
¥1000.00
Tricyclohexylphosphine, 97% 三环己基磷 25g 2,294
96-99 %
Innochem T1201
¥1000.00
Tricyclohexylphosphine, 97% 三环己基磷 50g 4,000
96-99 %
Innochem T1201
¥1000.00
Tricyclohexylphosphine, 97% 三环己基磷 100g 6,882
96-99 %
Innochem A11254
¥询价
Tricyclohexyl phosphine 三环己基膦 1g 190
96-99 %
Innochem A11254
¥询价
Tricyclohexyl phosphine 三环己基膦 5g 580
BJ-CN
中国国内现货 96-99 %
Innochem A11254
¥询价
Tricyclohexyl phosphine 三环己基膦 25g 1,900
BJ-CN
中国国内现货 96-99 %
Alfa 044854
Tricyclohexylphosphine
technical grade 1g 97
SH-CN BJ-CN
中国国内现货 0
Alfa 044854
Tricyclohexylphosphine
technical grade 5g 397
SH-CN BJ-CN
中国国内现货 0
Alfa 030386
Tricyclohexylphosphine
96% 1g 229
SH-CN BJ-CN
中国国内现货 99
Alfa 030386
Tricyclohexylphosphine
96% 5g 625
SH-CN BJ-CN
中国国内现货 99
Alfa 030386
Tricyclohexylphosphine
96% 25g 2,788
SH-CN BJ-CN
中国国内现货 99
Alfa 041952
Tricyclohexylphosphine
98% 5g 776
SH-CN BJ-CN
中国国内现货 99
Alfa 041952
Tricyclohexylphosphine
98% 25g 3,496
SH-CN BJ-CN
中国国内现货 99
J&K 128983
Tricyclohexylphosphine, 97%
97% 1g 186
HB SH
中国国内现货 96-99 %
J&K 128983
Tricyclohexylphosphine, 97%
97% 5g 744
HB SH
中国国内现货 96-99 %
J&K 128983
Tricyclohexylphosphine, 97%
97% 25g 2,766
HB SH
中国国内现货 96-99 %
Wylton 30410
Tricyclohexyl phosphine 三环己基膦
0.98 1g 118
CN
中国国内现货
Wylton 30410
Tricyclohexyl phosphine 三环己基膦
0.98 5g 348
CN
中国国内现货
Wylton 30410
Tricyclohexyl phosphine 三环己基膦
0.98 10g 718
CN
中国国内现货
Wylton 30410
Tricyclohexyl phosphine 三环己基膦
0.98 25g 2,154
CN
中国国内现货
Acros 42161
Tricyclohexylphosphine, 97%
1g 252
SH-CN BJ-CN CN
中国国内现货 0
Acros 42161
Tricyclohexylphosphine, 97%
5g 1,551
SH-CN BJ-CN
中国国内现货 0
Acros 42161
Tricyclohexylphosphine, 97%
25g 5,302
0
Acros 42783
¥1129.00
Tricyclohexylphosphine, 1M solution in THF, AcroSeal? 三环己基膦,1M 四氢呋喃溶液 运输条件:Air 保存条件:Flammables 下载MSDS 100mL 907
CN
中国国内现货 0
Acros 42842
¥2119.00
Tricyclohexylphosphine, 1M solution in toluene, AcroSeal? 三环己基膦,1M 甲苯溶液 运输条件:Air 下载MSDS 100mL 816
0
Fluka 91487
technical, >=90% (GC) 5g 1,193
90+ %
Fluka 91487
technical, >=90% (GC) 25g 3,929
90+ %
Energy-chemical E010014
Tricyclohexyl phosphine 三环己基膦
98% 5g 139
CN-BJ CN-SH
中国国内现货 96-99 %
Energy-chemical E010014
Tricyclohexyl phosphine 三环己基膦
98% 25g 465
CN-BJ CN-SH
中国国内现货 96-99 %
Energy-chemical E010014
Tricyclohexyl phosphine 三环己基膦
98% 100g 1,480
CN-BJ CN-SH
中国国内现货 96-99 %
Aladdin T115366
Tricyclohexyl phosphine 三环己基膦
96% 1g 66
CN-SH
中国国内现货 96-99 %
Aladdin T115366
Tricyclohexyl phosphine 三环己基膦
96% 5g 138
CN-SH
中国国内现货 96-99 %
Aladdin T115366
Tricyclohexyl phosphine 三环己基膦
96% 25g 460
CN-SH
中国国内现货 96-99 %
Aladdin T115366
Tricyclohexyl phosphine 三环己基膦
96% 100g 1,465
CN-SH
中国国内现货 96-99 %
Acros 428421000
AcroSeal? 100mL 832
0
Matrix 089904
Tricyclohexylphosphine
96% 25g 1,235
BJ-CN
中国国内现货 96-99 %
Matrix 089904
Tricyclohexylphosphine
96% 100g 3,744
BJ-CN
中国国内现货 96-99 %
TRC T774600
Tricyclohexyl Phosphine (90%)
1g 495
90+ %
TRC T774600
Tricyclohexyl Phosphine (90%)
5g 605
90+ %
TRC T774600
Tricyclohexyl Phosphine (90%)
25g 1,500
90+ %
TRC T774600
Tricyclohexyl Phosphine (90%)
100g 4,250
90+ %
Adamas 42821A
Tricyclohexyl Phosphine,98%+ 三环己基膦 1g 259
SH-CN BJ-CN
中国国内现货 96-99 %
Adamas 42821B
Tricyclohexyl Phosphine,98%+ 三环己基膦 5g 511
SH-CN CN
中国国内现货 96-99 %
Adamas 42821C
Tricyclohexyl Phosphine,98%+ 三环己基膦 25g 2,267
SH-CN BJ-CN CN
中国国内现货 96-99 %
Strem 15-6150
Tricyclohexylphosphine, 97%
97% 5g 840
96-99 %
Strem 15-6150
Tricyclohexylphosphine, 97%
97% 25g 3,120
96-99 %
Strem 15-6150
Tricyclohexylphosphine, 97%
97% 250g 14,790
96-99 %
Strem 15-6151
Tricyclohexylphosphine (20% in toluene), min. 88%
min. 100g 1,050
20+ % solution 甲苯
Strem 15-6151
Tricyclohexylphosphine (20% in toluene), min. 88%
min. 500g 3,735
20+ % solution 甲苯
TRC TRC-T774600
Tricyclohexyl Phosphine (90%)
5g 1,320
90+ %
TRC TRC-T774600
Tricyclohexyl Phosphine (90%)
25g 1,800
90+ %
TRC TRC-T774600
Tricyclohexyl Phosphine (90%)
100g 5,100
90+ %
Ark AK-94844
97% 1g 160
96-99 %
Ark AK-94844
97% 5g 480
96-99 %
Ark AK-94844
97% 10g 960
96-99 %
Ark AK-94844
97% 25g 676
96-99 %
Ark AK-94844
97% 100g 2,435
96-99 %
Meryer M12344
三环己基膦
96% 1g 171
96-99 %
Meryer M12344
三环己基膦
96% 5g 556
96-99 %
Meryer M12344
三环己基膦
96% 25g 2,356
96-99 %
Acros C4216
97% 1g 364
96-99 %
Aladdin T115366-1g
Tricyclohexyl phosphine 三环己基膦 运输条件:低温加冰 1g 66
BJ-CN
中国国内现货
Aladdin T115366-5g
Tricyclohexyl phosphine 三环己基膦 运输条件:低温加冰 5g 138
BJ-CN
中国国内现货
Aladdin T115366-25g
Tricyclohexyl phosphine 三环己基膦 运输条件:低温加冰 25g 460
BJ-CN
中国国内现货
3A A10416
Tricyclohexyl phosphine 三环己基膦
96% 1g -
96-99 %
3A A10416
Tricyclohexyl phosphine 三环己基膦
96% 5g -
96-99 %
3A A10416
Tricyclohexyl phosphine 三环己基膦
96% 25g -
96-99 %
Acros 427831000
100mL 1,118
BJ-CN
中国国内现货
Acros 421610010
1g 375
BJ-CN
中国国内现货
Acros 421610050
5g 1,702
Acros 421610250
25g 5,821
Aladdin T115366-100g
100g 1,465
Aldrich 592285-100ML
100mL 3,433
Aldrich 261971-1G
1g 247
Aldrich 261971-5G
5g 610
BJ-CN
中国国内现货
Aldrich 261971-25G
25g 2,601
Aldrich 455164-100G
100g 837
Aldrich 261971-250G
250g 11,436
Aldrich 455164-500G
500g 2,727
药明康德 WXCD00902186
1g 460
药明康德 WXCD00902186
5g 874
药明康德 WXCD00902186
25g 3,722

分类

  • {SNA} Catalysis, Basic Phosphine Ligands, Catalysis and Inorganic Chemistry,
  • {SNA} Basic Phosphine Ligands, Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Development Quantities for Research, Phosphine Compounds, Phosphine Ligands, Related Palladacycles
  • {SNA} Related Palladacycles, Basic Phosphine Ligands, Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Development Quantities for Research, Phosphine Compounds, Phosphine Ligands
  • {SNA} Basic Phosphine Lig
  • {SNA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry,

产品应用

  • 金属催化剂。

相关文献及参考

  • Beilstein: 16,IV,947

安全信息

Signal word
  • Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R48/20
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R36 Irritating to eyes 刺激眼睛
Precautionary statements
  • P261280301+312302+352305+351+338
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 如果食入:立即呼叫中毒控制中心或医生/医师。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P331 Do NOT induce vomiting.. 不要催吐。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335+336
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
Personal Protective Equipment
  • Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
  • dust mask type N95 (US), Eyeshields, Gloves
Storage condition
  • -20°C
  • 储存温度2-8℃,充氩保存
  • 对空气敏感
  • Air Sensitive
Hazard Codes
  • Xn
  • F,Xn
  • Xi
  • Xi,Xn,F
Packing GroupIII
UN Number
  • UN 2056 3/PG 2

其他信息

  • 存储注意事项:空气敏感;氮气保护
  • Alfa Aesar:三环己基膦,96% Tricyclohexylphosphine, 96%(2622-14-2)
  • TCI Shanghai:三环己基膦(约18%的甲苯溶液,约0.60mol/L)(含三环己基氧化膦) Tricyclohexylphosphine (contains Tricyclohexylphosphine Oxide) (ca. 18% in Toluene, ca. 0.60mol/L)(2622-14-2)
  • 敏感性:Air Sensitive
  • 下游产品:二氯二(三环己基瞵)钯
  • 上游原料:乙醚 --> 氯化铵 --> 镁 --> 三氯化磷 --> 溴代环己烷
  • MOL 文件:2622-14-2.mol
  • Acros Organics:三环己基膦 Tricyclohexyl phosphine, 97%(2622-14-2)
  • 三环己基膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A26197103 三环己基膦 25g 2860元 2010/06/21 421610010 三环己基膦 Tricyclohexylphosphine 97% 1 GR 363元 2010/06/21 421610050 三环己基膦 Tricyclohexylphosphine 97% 5 GR 1622元
  • 图谱信息:三环己基膦(2622-14-2)质谱(MS) 三环己基膦(2622-14-2)核磁图( 13 CNMR)
  • 用途一:作为配体,用于Buchwald, Suzuki等偶联反应中
  • 用途二:金属催化剂。
  • Sigma Aldrich:2622-14-2(sigmaaldrich)
  • MSDS 信息:Tricyclohexyl phosphine(2622-14-2).msds

化学结构图

CAS 2622-14-2  MFCD00003853
SMILES: c1ccc(P(C2CCCCC2)C2CCCCC2)cc1

化学属性

Mol. Formula(C6H11)3P
Mol. Weight280.43
Density0.901 g/mL at 25 °C
Melting Point77-83
TSCAYes
Stability对空气敏感
Boiling Point110°C
Flash Point48 °F
Appearance
  • 白色晶体

    别名和识别编码

    Chemical NameTricyclohexylphosphine
    MDL NumberMFCD00003853
    CAS Number2622-14-2
    EC Number220-069-2
    Beilstein Registry Number957171
    Synonym
    • 三环己基膦
    • Tricyclohexylphosphine,97%
    • TCHP
    • TRICYCLOHEXYL PHOSPHINE (TCHP)
    • TRICYCLOHEXYLPHOSPHINE, DISSOLVED IN TOLUENE (20% CONCENTRATION)
    • TRICYCLOHEXYLPHOSPHINE, 20 WT. % SOLUTI&
    • Phosphine, tricyclohexyl-
    • 三环己基磷
    • 三环已基磷
    • PHOSPHORUS TRICYCLOHEXYL
    • P(Cy)3 PCy3
    • Tricyclohexylphosphine, technical grade
    • tricyclohexylphosphine solution
    • tricyclohexyl-phosphin
    • TRICYCLOHEXYLPHOSPHINE
    • Tricyclohexylphosphine (contains Tricyclohexylphosphine Oxide) (ca. 18% in Toluene, ca. 0.60mol/L)
    • TRICYCLOHEXYLPHOSPHINE, 1M IN TOLUENE
    • NSC 158657 PCy3
    • Tricyclohexylphosphine, 20% Toluene Solution
    • P(Cy)3
    • TRICYCLOHEXYLPHOSPHINE, 1M IN TETRAHYDR&
    • Tricyclohexylphosphine(20%intoluene),min.88%
    • tricyclohexylphospine
    • 三環己[基]膦
    • TRICYCLOHEXYL-PHOSPHANE
    • TRICYCLOHEXYLPHOSPHINE: (20% IN TOLUENE)
    • PCY3
    • 三环己基磷 溶液
    • 三环己基膦,工业级
      PubChem Substance ID 24869033
      Chemical Name Translation三环己基磷
      InChIKeyWLPUWLXVBWGYMZ-UHFFFAOYSA-N
      LabNetwork Molecule IDLN00010018

      系列性分类


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