(S)-(-)-α-Methylbenzylamine (S)-(-)- α-甲基苄胺

CAS 2627-86-3 MFCD00064406

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现货筛选
产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI 461507
(S)-(-)-1-Phenylethylamine (S)-(-)- α-甲基苄胺
99% 5g 60
99e1
INFI 461507
(S)-(-)-1-Phenylethylamine (S)-(-)- α-甲基苄胺
99% 25g 120
99e1
INFI 461507
(S)-(-)-1-Phenylethylamine (S)-(-)- α-甲基苄胺
99% 100g 260
LN-CN
中国国内现货 99e1
INFI 461507
(S)-(-)-1-Phenylethylamine (S)-(-)- α-甲基苄胺
99% 500g 650
LN-CN
中国国内现货 99e1
Innochem 582918
L-1-Phenylethylamine
98% 25g 82
BJ-CN
中国国内现货 96-99 %
Innochem 582918
L-1-Phenylethylamine
98% 100g 160
96-99 %
Innochem 582918
L-1-Phenylethylamine
98% 500g 558
BJ-CN
中国国内现货 96-99 %
TCI 172721
( S )-(-)-1-Phenylethylamine >
>98.0%(GC) 25mL 395
SH-CN TJ-CN TK-JP
中国国内现货 99
TCI 172721
( S )-(-)-1-Phenylethylamine >
>98.0%(GC) 100mL 990
SH-CN TK-JP
中国国内现货 99
TCI 172721
( S )-(-)-1-Phenylethylamine >
>98.0%(GC) 500mL 2,950
SH-CN TJ-CN TK-JP
中国国内现货 99
Alfa 172727
(S)-(-)-1-Phenylethylamine
98% 25g 455
SH-CN BJ-CN
中国国内现货 99
Alfa 172727
(S)-(-)-1-Phenylethylamine
98% 100g 1,470
SH-CN
中国国内现货 99
Alfa 172727
(S)-(-)-1-Phenylethylamine
98% 500g 5,981
SH-CN
中国国内现货 99
Alfa 172728
(S)-(-)-1-Phenylethylamine, ChiPros 99+%, ee 99.5%
99+% 5g 164
SH-CN BJ-CN
中国国内现货 99e1
Alfa 172728
(S)-(-)-1-Phenylethylamine, ChiPros 99+%, ee 99.5%
99+% 25g 394
SH-CN BJ-CN
中国国内现货 99e1
Alfa 172728
(S)-(-)-1-Phenylethylamine, ChiPros 99+%, ee 99.5%
99+% 100g 1,094
SH-CN
中国国内现货 99e1
J&K 172719
(S)-(-)-1-Phenylethylamine, 99%, ee: 98%
99% 25g 68
HB
中国国内现货 99
J&K 172719
(S)-(-)-1-Phenylethylamine, 99%, ee: 98%
99% 100g 265
HB
中国国内现货 99
J&K 172719
(S)-(-)-1-Phenylethylamine, 99%, ee: 98%
99% 500g 1,300
HB
中国国内现货 99
Matrix 66513
(S)-(-)-1-Phenylethylamine
95+% 100g 396
99
Matrix 66513
(S)-(-)-1-Phenylethylamine
95+% 500g 1,815
99
TRC 82144
(S)-(-)-α-Methylbenzylamine
25g 495
0
TRC 82144
(S)-(-)-α-Methylbenzylamine
50g 825
0
TRC 82144
(S)-(-)-α-Methylbenzylamine
100g 1,250
0
TRC 82144
(S)-(-)-α-Methylbenzylamine
250g 2,750
0
TRC 82144
(S)-(-)-α-Methylbenzylamine
500g 4,950
0
Apollo 172720
(1S)-(-)-1-Phenylethylamine
100g 396
0
Acros 172722
L(-)-alpha-Methylbenzylamine, 99+%, (99% ee)
25g 452
99
Acros 172722
L(-)-alpha-Methylbenzylamine, 99+%, (99% ee)
100g 1,390
SH-CN
中国国内现货 99
Acros 172722
L(-)-alpha-Methylbenzylamine, 99+%, (99% ee)
500g 5,013
99
Acros 172723
(S)-(-)-1-Phenylethylamine, 99+%, produced by BASF AG
99+% 50g 295
SH-CN
中国国内现货 0
Acros 172723
(S)-(-)-1-Phenylethylamine, 99+%, produced by BASF AG
99+% 250g 2,580
SH-CN
中国国内现货 0
Acros 172723
(S)-(-)-1-Phenylethylamine, 99+%, produced by BASF AG
99+% 1kg 7,360
0
Aldrich 172725
(S)-(-)-α-Methylbenzylamine (S)-(-)-α-甲基苄胺
98% 25g 548
99
Aldrich 172725
(S)-(-)-α-Methylbenzylamine (S)-(-)-α-甲基苄胺
98% 100g 1,763
99
Aldrich 172726
(S)-(?)-α-Methylbenzylamine
>=99.0% ChiPros?, produced by BASF, ≥99.0% 100g 1,141
99
Aldrich 172726
(S)-(?)-α-Methylbenzylamine
>=99.0% ChiPros?, produced by BASF, ≥99.0% 500g 5,032
99
Fluka 296323
purum, >=98.0% (sum of enantiomers, GC) 10mL 290
99
Fluka 296323
purum, >=98.0% (sum of enantiomers, GC) 50mL 660
99
Fluka 296323
purum, >=98.0% (sum of enantiomers, GC) 250mL 2,661
99
Shao Yuan 385195
(S)-(-)-1-Phenylethylamine S-1-苯乙胺
98% 97+% 25g 65
SH-CN
中国国内现货 99
Shao Yuan 385195
(S)-(-)-1-Phenylethylamine S-1-苯乙胺
98% 97+% 25mL 395
99
Shao Yuan 385195
(S)-(-)-1-Phenylethylamine S-1-苯乙胺
98% 97+% 100g 100
SH-CN
中国国内现货 99
Shao Yuan 385195
(S)-(-)-1-Phenylethylamine S-1-苯乙胺
98% 97+% 100mL 990
99
Shao Yuan 385195
(S)-(-)-1-Phenylethylamine S-1-苯乙胺
98% 97+% 500g 280
SH-CN
中国国内现货 99
Shao Yuan 385195
(S)-(-)-1-Phenylethylamine S-1-苯乙胺
98% 97+% 500mL 2,950
99
Shao Yuan 385195
(S)-(-)-1-Phenylethylamine S-1-苯乙胺
98% 97+% 1000g 550
99
Energy-chemical 397608
(S)-(-)-α-Methylbenzylamine S-1-苯乙胺
99% 25mL 55
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 397608
(S)-(-)-α-Methylbenzylamine S-1-苯乙胺
99% 100mL 108
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 397608
(S)-(-)-α-Methylbenzylamine S-1-苯乙胺
99% 500mL 395
CN-BJ CN-SH
中国国内现货 99
Aladdin 397609
(S)-(-)-1-Phenylethylamine (S)-(-)- α-甲基苄胺
>99.0%(GC) 25mL 54
CN-SH
中国国内现货 99
Aladdin 397609
(S)-(-)-1-Phenylethylamine (S)-(-)- α-甲基苄胺
>99.0%(GC) 100mL 108
CN-SH
中国国内现货 99
Aladdin 397609
(S)-(-)-1-Phenylethylamine (S)-(-)- α-甲基苄胺
>99.0%(GC) 500mL 394
99
Aladdin 397610
(S)-(-)-α-Methylbenzylamine (S)-(-)- α-甲基苄胺
>98.0%(GC) 25mL 102
CN-SH
中国国内现货 99
Aladdin 397610
(S)-(-)-α-Methylbenzylamine (S)-(-)- α-甲基苄胺
>98.0%(GC) 100mL 271
CN-SH
中国国内现货 99
Aladdin 397610
(S)-(-)-α-Methylbenzylamine (S)-(-)- α-甲基苄胺
>98.0%(GC) 500mL 1,026
CN-SH
中国国内现货 99
Acros 402977
(99% ee) 100g 1,580
99
Adamas 421679
99%+ 25g 140
SH-CN CN
中国国内现货 99
Adamas 421680
99%+ 100g 192
SH-CN CN
中国国内现货 99
Adamas 421681
99%+ 500g 663
SH-CN CN
中国国内现货 99
Adamas 421682
99.5%+ 25g 271
99e1
Adamas 421683
99%+ 5g 62
SH-CN CN
中国国内现货 99
Key Organic 500712
(1S)-(-)-1-Phenylethylamine
>95% 5mg 735
99
Ark 547883
97% 10g 80
99
Ark 547883
97% 25g 120
SH-CN
中国国内现货 99
Ark 547883
97% 100g 400
SH-CN
中国国内现货 99
Ark 547883
97% 500g 960
SH-CN
中国国内现货 99
Ark 547883
97% 1000g 1,600
SH-CN
中国国内现货 99
Aladdin 624919
100mL 398
Aladdin 624920
100mL 108
Aladdin 624921
500mL 1,580
Aladdin 624922
25mL 118
Aladdin 624923
25mL 54
3A 633024
L-1-Phenylethylamine S-1-苯乙胺
98% 25g -
96-99 %
3A 633024
L-1-Phenylethylamine S-1-苯乙胺
98% 100g -
96-99 %
3A 633024
L-1-Phenylethylamine S-1-苯乙胺
98% 500g -
96-99 %

分类

  • {SNA} Amines, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
  • Chiral Reagents
  • {SNA} Analytical Reagents, Analytical/Chromatography, Chiral, Chiral Derivatization Reagents, Chiral GC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC
  • Amines
  • {SNA} Amines, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks
  • Aromatics

产品应用

  • Used in a one-pot, multi-component synthesis of a highly substituted, chiral pyrrole

相关文献及参考

  • For use as a chiral auxiliary in the asymmetric synthesis of (R)-(-)-10-methyl-1(9)-octal-2-one, see: Org. Synth. Coll., 9, 610 (1998):
  • Merck: 13,6054 Beilstein:12,1093
  • Merck: 13,6054

安全信息

Warnings
  • IRRITANT
Signal word
  • Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R35 Causes severe burns 会导致严重灼伤
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261305+351+338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+351+338+310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+330+331+310
  • P280305+351+338308+313314310
  • P303+361+353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. 如果沾上皮肤(或头发):删除/立即脱掉所有被污染的衣服。清洗/淋浴冲洗皮肤。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P304+340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. 如果吸入:转移到空气新鲜处,休息,保持一个适合呼吸的姿势。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P304+340+310
  • P403+235 Store in a well-ventilated place. Keep cool. 存放在通风良好的地方。保持凉爽。
  • P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. 如果吞咽:漱口。不要催吐。
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
Packing GroupII
UN Number
  • 2735
  • UN2735
  • UN 2922 8/PG 2
Storage condition
  • 储存温度 2-8°C
  • 2-8°C
  • Air Sensitive
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment
  • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
  • C
  • C,Xi
RTECSDP5775000
Hazard Class8/6.1

其他信息

  • MSDS 信息:L(-)-alpha-Methylbenzylamine(2627-86-3).msds
  • 上游原料:氢氧化钠 --> 甲醇 --> 乙醚 --> 左旋酒石酸 --> alpha-甲基苄胺
  • 比旋光度:-40 ° (neat)
  • 海关编码:29214980
  • 敏感性:Air Sensitive
  • S-1-苯乙胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0793 (S)-(-)-1-苯乙胺 (S)-(-)-1-Phenylethylamine 25ML 424元 2014/06/02 P0793 (S)-(-)-1-苯乙胺 (S)-(-)-1-Phenylethylamine 500ML 3140元 2010/06/21 151831000 S-1-苯乙胺 L(-)-alpha-Methylbenzylamine , 99+%, (99% ee) 100 GR 1555元
  • 食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称 允许使用该种添加剂的食品中文名称 添加剂功能 最大允许使用量(g/kg) 最大允许残留量(g/kg) 苯乙胺 食品 食品用香料 用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
  • Alfa Aesar:(S)-(-)-1-苯基乙胺,ChiPros99+%,ee99.5% (S)-(-)-1-Phenylethylamine, ChiPros 99+%, ee 99.5%(2627-86-3)
  • 下游产品:(R)-(+)-叔丁基亚磺酰胺 --> (S)-(-)-2-羧基环丁胺 --> R-1,1'-联-2-萘酚 --> R-3-氨基奎宁环二盐酸盐 --> S-1,1'-联-2-萘酚 --> (R)-(+)-降冰片胺 --> S-氰戊菊酯 --> (S,S)-(-)-双(Α-甲基苄基)胺盐酸盐 --> (S)-(-)-N-苄基-alpha-甲基苄胺 --> (S,S)-双-(1-苯基乙基)胺 --> (R)-(+)-N-苄基-1-苯乙胺
  • MOL 文件:2627-86-3.mol
  • Sigma Aldrich:2627-86-3(sigmaaldrich)
  • F:3-10-23-34
  • 蒸气压:0.5 mm Hg ( 20 °C)
  • 图谱信息:S-1-苯乙胺(2627-86-3)红外图谱(IR2) S-1-苯乙胺(2627-86-3)红外图谱(IR1) S-1-苯乙胺(2627-86-3)质谱(MS) S-1-苯乙胺(2627-86-3)Raman光谱 S-1-苯乙胺(2627-86-3)核磁图( 1 HNMR) S-1-苯乙胺(2627-86-3)核磁图( 13 CNMR)
  • Hazard Note:Irritant
  • 微溶于水,溶于大多数有机溶剂,和醇及醚混溶。
  • Acros Organics:L(-)-alpha-甲基苄胺 L(-)-alpha-Methylbenzylamine, 99+%, (99% ee)(2627-86-3)
  • TCI Shanghai:(S)-(-)-1-苯基乙胺 (S)-(-)-1-Phenylethylamine,>;98.0%(GC)(2627-86-3)
  • 存储注意事项:空气敏感

化学结构图

CAS 2627-86-3  MFCD00064406
SMILES: C[C@@H](N)C1C=CC=CC=1 |&1:1|

化学属性

Mol. FormulaC6H5CH(CH3)NH2
Mol. Weight121.18
Density0.95
Refractive indexn20/D 1.526(lit.)
Flash Point79°C(lit.)
TSCAYes
Boiling Point187
Melting Point-10
Vapor Pressure0.5 mmHg ( 20 °C)
Solubility略溶于水

别名和识别编码

Chemical Name(S)-(-)-1-Phenylethylamine
CAS Number2627-86-3
Alfabeta NamePHENYLETHYLAMINE S1(())----
MDL NumberMFCD00064406
Synonym
  • S-(-)-ALPHA-PHENYLETHYLAMINE
  • (R)-(-)-Α-甲基苄基胺
  • S-1-苯乙胺,S(-)-α-苯乙胺,甲基苄胺
  • S-1-苯乙胺
  • (S)-(-)-1-METHYLBENZYLAMINE
  • S-ALFA-METHYLBENZYLAMINE
  • L-(-)-ALPHA-PHENYLETHYLAMINE
  • (S)-1-PHENYLETHYLAMINE
  • L-PHENYLETHYLAMINE
  • S(-)-alpha-甲基苄胺
  • (-)-alpha-Phenethylamine
  • (S)-1-Amino-1-phenylethane
  • (1S)-1-PHENYLETHYLAMINE
  • L-ALPHA-PHENYLETHYLAMINE
  • 苯乙胺
  • L-(-)-alpha-Methylbenzylamine
  • S(-)-1-苯基乙胺
  • (S)-(-)-α-甲基苄胺
  • S(-)-A-甲基苄胺
  • L(-)-ALPHA-甲基苄胺
  • (S)-(-)-1-PHENYLETHYLAMINE
  • (-)-?-Phenethylamine
  • (S)-A-苯丙氨酸
  • L(-)-ALPHA-苯乙胺
  • (S)-(-)-ALPHA-METHYLBENZYLAMINE
  • L-ALPHA-METHYLBENZYLAMINE
  • L-(-)-1-PHENYLETHYLAMINE
  • L-A-苯乙胺
  • (S)(-)-ALPHA-PHENETHYLAMINE
  • (-)-L-ALPHA-METHYLBENZYLAMINE
  • (S)-(-)-A-METHYLBENZYLAMINE
  • (S)-(-)-1-苯乙胺
  • (S)-(-)-1-Phenylethylamine; L(-)-alpha-Methylbenzylamine; (-)-PEA
  • L-(-)-A-METHYLBENZYLAMINE
  • S(-)-α-甲基苄胺
  • (S)-(-)-1-苯基乙胺,98%
  • L-(-)-Α-甲基苄胺
  • 1-PHENYLETHYLAMINE
  • L(-)-ALPHA-METHYLBENZYLAMINE
  • (S)-(-)- α-甲基苄胺
  • (S)-(-)--Methylbenzylamine
  • (S)-(-)-1-苯基乙胺, CHIPROS 99+%, EE 99.5%
  • (S)-(-)-1-苯乙胺 (S)-(-)-alpha-Methylbenzylamine
  • (S)-1-PHENYLETHANAMINE
  • (?S)-?-Methyl-benzenemethanamine
  • S-(-)-苯乙胺
    EC Number220-098-0
    Beilstein Registry Number2204907
    Merck Number14,6026
    PubChem Substance ID 24847225
    Reaxys-RN3648466
    Chemical Name Translation(S)-(-)- α-甲基苄胺
    LabNetwork Molecule IDLN00179043

    系列性分类


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    • HB
    • CN-SH
    100-46-9, MFCD00008106, 	Benzylamine
	苄胺
    100-46-9 / MFCD00008106
    Benzylamine
    苄胺
    • SH-CN
    • TJ-CN
    • TK-JP
    • LN-CN
    • SH
    • BJ-CN
    • L2
    • HB
    • CN-SH
    • CN
    7789-78-8, MFCD00010897, 	Calcium hydride
	氢化钙
    7789-78-8 / MFCD00010897
    Calcium hydride
    氢化钙
    • SH-CN
    • BJ-CN
    • LN-CN
    • CN-BJ
    • SH
    • L2
    • HB
    • CN-SH
    • CN
    2001-45-8, MFCD00011916, 	Tetraphenylphosphonium chloride	四苯基氯化膦
    2001-45-8 / MFCD00011916
    Tetraphenylphosphonium chloride
    四苯基氯化膦
    • SH-CN
    • TJ-CN
    • BJ-CN
    • LN-CN
    • CN-BJ
    • SH
    • TK-JP
    • HB
    • CN-SH
    • CN
    4341-76-8, MFCD00015182, 	Ethyl 2-butynoate	2-丁炔酸乙酯
    4341-76-8 / MFCD00015182
    Ethyl 2-butynoate
    2-丁炔酸乙酯
    • SH-CN
    • TJ-CN
    • BJ-CN
    • CN
    • SH
    • CN-BJ
    • TK-JP
    • L2
    • HB
    • CN-SH
    3886-69-9, MFCD00064405, 	(R)-(+)-α-Methylbenzylamine	R(+)-α-甲基苄胺
    3886-69-9 / MFCD00064405
    (R)-(+)-α-Methylbenzylamine
    R(+)-α-甲基苄胺
    • SH-CN
    • TJ-CN
    • TK-JP
    • LN-CN
    • SH
    • CN-BJ
    • BJ-CN
    • L2
    • HB
    • CN-SH
    • CN