Diethyl (chloromethyl)phosphonate, 98% 氯甲基膦酸二乙酯

CAS 3167-63-3 MFCD00010189

化学结构图

3167-63-3
SMILES: CCOP(=O)(CCl)OCC

化学属性

Mol. FormulaC5H12ClO3P
Mol. Weight186.57
Density1.2
Refractive index1.4380 to 1.4420
Boiling Point242.9°C at 760 mmHg
Flash Point86°C(lit.)

别名和识别编码

Chemical NameDiethyl (chloromethyl)phosphonate, 98%
Synonym Chloromethylphosphonic acid diethyl ester Chloromethylphosphonic acid diethyl ester NSC 67753 Diethyl (chloromethyl)phosphonate {uni_hamburg} Diethyl chloromethylphosphonate diethyl (chloromethyl)phosphonate {} {} {} {} {} {} {} {uni_hamburg} 氯甲基膦酸二乙酯
MDL NumberMFCD00010189
CAS Number3167-63-3
Beilstein Registry Number1363361
EC Number221-632-5
PubChem Substance ID76633
Chemical Name Translation氯甲基膦酸二乙酯
Reaxys-RN1363361
InChIKeyMZBIWKMCTWJLPT-UHFFFAOYSA-N
LabNetwork Molecule IDLN01070281
InChIInChI=1S/C5H12ClO3P/c1-3-8-10(7,5-6)9-4-2/h3-5H2,1-2H3
Canonical SMILESClCP(OCC)(OCC)=O
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: EINECS
  • Short: III/20a

安全信息

WGK Germany3
GHS Symbol
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, stored under nitrogen

系列性分类


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