4-Fluorophenylmagnesium bromide 4-氟苯基溴化镁

CAS 352-13-6 MFCD00009667

化学结构图

352-13-6
SMILES: Fc1ccc([Mg]Br)cc1

化学属性

Mol. FormulaC6H4BrFMg
Mol. Weight199.31
Density1.01
TSCAYes
Melting Point5
Flash Point-20°C(lit.)
Stability对湿度敏感
Density1.01
Mol. FormulaC6H4BrFMg
Mol. Weight199.31

别名和识别编码

Chemical Name4-Fluorophenylmagnesium bromide
CAS Number352-13-6
EC Number250-023-7
Beilstein Registry Number636802
MDL NumberMFCD00009667
PubChem Substance ID2734897
Synonym 4-氟苯基溴化镁 溶液 4-氟苯基溴化镁
Reaxys-RN636802
Chemical Name Translation4-氟苯基溴化镁
InChIKeyQYBFFRXNNFXREA-UHFFFAOYSA-M
LabNetwork Molecule IDLN00220943
InChIInChI=1S/C6H4F.BrH.Mg/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q-1;;+2/p-1
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分类

  • {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

相关文献及参考

  • Beilstein: 16,II,650

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S8 Keep container dry 保持容器干燥;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+P378
  • P403+P235
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P303+P361+P353
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P405 Store locked up. 上锁保管。
  • P403+P233
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H351 Suspected of causing cancer 怀疑致癌
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,C
Packing GroupII
UN Number 3399
Storage condition Air & Moisture Sensitive 充氩密封
Hazard Class3/8

其他信息

  • www.aladdin-reagent.com密度:1.021

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