4-Bromofluorobenzene 对氟溴苯

CAS 460-00-4 MFCD00000342

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H55232
4-Bromofluorobenzene 对氟溴苯
98% 25g ¥ 44
库存 辽宁
中国国内现货 96-99 %
INFI H55232
4-Bromofluorobenzene 对氟溴苯
98% 100g ¥ 86
库存 辽宁
中国国内现货 96-99 %
INFI H55232
4-Bromofluorobenzene 对氟溴苯
98% 500g ¥ 232
库存 辽宁
中国国内现货 96-99 %
Innochem A05910
1-Bromo-4-fluorobenzene
98% 25g ¥ 57
库存 北京
中国国内现货 96-99 %
Innochem A05910
1-Bromo-4-fluorobenzene
98% 100g ¥ 117
库存 北京
中国国内现货 96-99 %
Innochem A05910
1-Bromo-4-fluorobenzene
98% 500g ¥ 402
库存 北京
中国国内现货 96-99 %
TCI B0884
4-Bromofluorobenzene >
>98.0%(GC) 25g ¥ 105
库存 上海市 Tokyo, Japan
中国国内现货 96-99 %
TCI B0884
4-Bromofluorobenzene >
>98.0%(GC) 100g ¥ 490
库存 上海市 Tokyo, Japan
中国国内现货 96-99 %
TCI B0884
4-Bromofluorobenzene >
>98.0%(GC) 500g ¥ 640
库存 上海市 Tokyo, Japan
中国国内现货 96-99 %
Alfa A11630
1-Bromo-4-fluorobenzene
99% 100g ¥ 305
库存 上海市 北京 China, PRC
中国国内现货 96-99 %
Alfa A11630
1-Bromo-4-fluorobenzene
99% 500g ¥ 602
库存 上海市 China, PRC
中国国内现货 96-99 %
Alfa A11630
1-Bromo-4-fluorobenzene
99% 2500g ¥ 2,408
库存 上海市 China, PRC
中国国内现货 96-99 %
J&K 187086
1-Bromo-4-fluorobenzene, 99%
99% 25mL ¥ 159
库存 HB
中国国内现货 96-99 %
J&K 187086
1-Bromo-4-fluorobenzene, 99%
99% 100mL ¥ 359
库存 HB
中国国内现货 96-99 %
J&K 187086
1-Bromo-4-fluorobenzene, 99%
99% 500mL ¥ 1,090
库存 HB
中国国内现货 96-99 %
Matrix 076202
1-Bromo-4-fluorobenzene
95+% 10g ¥ 138
96-99 %
Matrix 076202
1-Bromo-4-fluorobenzene
95+% 25g ¥ 195
96-99 %
Matrix 076202
1-Bromo-4-fluorobenzene
95+% 100g ¥ 325
库存 SH
中国国内现货 96-99 %
Supelco 442404
1item ¥ 264
Supelco 48083
1item ¥ 345
Supelco 48800
1item ¥ 446
Apollo PC1420
4-Fluorobromobenzene 99%
100g ¥ 396
96-99 %
Apollo PC1420
4-Fluorobromobenzene 99%
500g ¥ 283
96-99 %
Apollo PC1420
4-Fluorobromobenzene 99%
1kg ¥ 459
96-99 %
TRC B684545
4-Bromofluorobenzene
10g ¥ 1,680
TRC B684545
4-Bromofluorobenzene
100g ¥ 3,850
Shao Yuan SY001876
4-Bromofluorobenzene 对氟溴苯
≥98% 25g ¥ 55
库存 上海市 济南市
中国国内现货 96-99 %
Shao Yuan SY001876
4-Bromofluorobenzene 对氟溴苯
≥98% 100g ¥ 115
库存 上海市 济南市
中国国内现货 96-99 %
Shao Yuan SY001876
4-Bromofluorobenzene 对氟溴苯
≥98% 500g ¥ 290
库存 上海市
中国国内现货 96-99 %
Shao Yuan SY001876
4-Bromofluorobenzene 对氟溴苯
≥98% 1000g ¥ 558
96-99 %
Energy-chemical D050054
4-Bromofluorobenzene 对溴氟苯
98% 25g ¥ 55
库存 上海市 北京市
中国国内现货 96-99 %
Energy-chemical D050054
4-Bromofluorobenzene 对溴氟苯
98% 100g ¥ 108
库存 上海市 北京市
中国国内现货 96-99 %
Energy-chemical D050054
4-Bromofluorobenzene 对溴氟苯
98% 500g ¥ 295
库存 上海市 北京市
中国国内现货 96-99 %
Aladdin B107758
1-Bromo-4-fluorobenzene 1-溴-4-氟苯
98% 25g ¥ 55
库存 上海市
中国国内现货 96-99 %
Aladdin B107758
1-Bromo-4-fluorobenzene 1-溴-4-氟苯
98% 100g ¥ 108
库存 上海市
中国国内现货 96-99 %
Aladdin B107758
1-Bromo-4-fluorobenzene 1-溴-4-氟苯
98% 500g ¥ 290
库存 上海市
中国国内现货 96-99 %
Aladdin B107758
1-Bromo-4-fluorobenzene 1-溴-4-氟苯
98% 2.5kg ¥ 2,499
库存 上海市
中国国内现货 96-99 %
Aladdin B128182
1-Bromo-4-fluorobenzene Standard 1-溴-4-氟苯标准溶液
1000μg/ml,溶于吹扫-捕集甲醇溶液中 1mL ¥ 369
库存 上海市
中国国内现货 96-99 %
Acros 107011000
99% 100mL ¥ 443
96-99 %
Adamas 58496A
98%+ 25g ¥ 50
库存 上海市 China, PRC
中国国内现货 96-99 %
Adamas 58496B
98%+ 100g ¥ 105
库存 上海市 China, PRC
中国国内现货 96-99 %
Adamas 58496C
98%+, 500g ¥ 290
库存 上海市 China, PRC
中国国内现货 96-99 %
Supelco 000000000000442404
analytical standard 1SAMPLE ¥ 234
96-99 %
Supelco 000000000000442404
analytical standard 1item ¥ 240
96-99 %
Supelco 000000000000442404
analytical standard 1000mg ¥ -
96-99 %
Supelco 000000000000047937
1000?μg/mL in methanol, analytical standard 1SAMPLE ¥ 359
96-99 %
Supelco 000000000000047937
1000?μg/mL in methanol, analytical standard 1item ¥ 369
96-99 %
Supelco 000000000000047937
1000?μg/mL in methanol, analytical standard 1mL ¥ -
96-99 %
Supelco 000000000000048083
2000?μg/mL in methanol, analytical standard 1SAMPLE ¥ 305
96-99 %
Supelco 000000000000048083
2000?μg/mL in methanol, analytical standard 1item ¥ 314
96-99 %
Supelco 000000000000048083
2000?μg/mL in methanol, analytical standard 1mL ¥ -
96-99 %
Supelco 000000000000048800
25,000?μg/mL in methanol, analytical standard 1SAMPLE ¥ 395
96-99 %
Supelco 000000000000048800
25,000?μg/mL in methanol, analytical standard 1item ¥ 406
96-99 %
Supelco 000000000000048800
25,000?μg/mL in methanol, analytical standard 1mL ¥ -
96-99 %
TRC TRC-B684545
4-Bromofluorobenzene
10g ¥ 1,440
96-99 %
TRC TRC-B684545
4-Bromofluorobenzene
100g ¥ 3,300
96-99 %
Ark AK-73130
98% 5g ¥ 64
96-99 %
Ark AK-73130
98% 10g ¥ 48
96-99 %
Ark AK-73130
98% 25g ¥ 64
96-99 %
Ark AK-73130
98% 100g ¥ 136
96-99 %
Ark AK-73130
98% 500g ¥ 384
96-99 %
3A A11895
1-Bromo-4-fluorobenzene 对氟溴苯
98% 25g ¥ -
96-99 %
3A A11895
1-Bromo-4-fluorobenzene 对氟溴苯
98% 100g ¥ -
96-99 %
3A A11895
1-Bromo-4-fluorobenzene 对氟溴苯
98% 500g ¥ -
96-99 %
Aladdin B107758-25g
98% 25g ¥ 55
96-99 %
Aladdin B107758-500g
98% 500g ¥ 290
96-99 %
Aladdin B128182-1ml
1mL ¥ 369
Aladdin B107758-100g
98% 100g ¥ 108
96-99 %
Aladdin B107758-2.5kg
98% 2.5kg ¥ 2,499
96-99 %
Acros 107010100
99% 10mL ¥ 126
96-99 %
Acros 107015000
99% 500mL ¥ 1,610
96-99 %
Aladdin B298671-1.2ml
1000μg/ml in methanol 1.2mL ¥ 179
Accela SY001876
≥98% 25g ¥ 55
96-99 %
Accela SY001876
≥98% 100g ¥ 131
96-99 %
Supelco 47937
1item ¥ 405
Aldrich B67201-25G
99% 25g ¥ 328
96-99 %
Aldrich B67201-100G
99% 100g ¥ 680
96-99 %
Aldrich B67201-500G
99% 500g ¥ 2,389
96-99 %
Key Organics PS-11962
95%'>>95% 1mg ¥ 630
90+ %
Key Organics PS-11962
95%'>>95% 5mg ¥ 777
90+ %
Key Organics PS-11962
95%'>>95% 10mg ¥ 1,071
90+ %
Key Organics PS-11962
95%'>>95% 25mg ¥ 1,617
90+ %
Key Organics PS-11962
95%'>>95% 50mg ¥ 1,743
90+ %
Key Organics PS-11962
95%'>>95% 100mg ¥ 2,520
90+ %
Key Organics PS-11962
95%'>>95% 250mg ¥ 3,717
90+ %
Aladdin B298671
1-Bromo-4-fluorobenzene 1-溴-4-氟苯标准溶液
浓度:1000μg/ml,基体:甲醇 1.2mL ¥ 179
库存 上海市
中国国内现货

分类

  • {SA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis,
  • {Chemicalbook} 农药中间体: 杀菌剂中间体: 三唑类杀菌剂
  • {uni_hamburg} no charge; carbocycle; arom
  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • 600 Series Wastewater Methods, 8000 Series Solidwaste Methods, A-B, Alpha Sort, Alphabetic, Analytical Standards, Analytical/Chromatography, B, BI - BZ, Bromo,

产品应用

  • 有机合成中间体。

相关文献及参考

  • Short: III/20b
  • Short: III/31b
  • The Br undergoes selective displacement with Na alkoxides in NMP, in the presence of CuBr: Tetrahedron, 48, 3633 (1992).
  • Lithiation with LDA at -75o results mainly in deprotonation ortho to F; subsequent reaction with CO2 gives 5-bromo-2-fluorobenzoic acid: Tetrahedron Lett., 33, 7495 (1992). Improved yields are obtained by the use of Li 2,2,6,6-tetramethylpiperidide (LTMP) as base: Tetrahedron Lett., 37, 6551 (1996).
  • Beilstein: 5,IV,678

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn
RTECSCY9033750
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P337+P313
  • P305+P351+P338+P337+P313
  • P303+P361+P353
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P403+P235
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P241+P242+P243
  • P233 Keep container tightly closed. ?保持容器密闭。
Signal word
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition <;0 <0°C 储存温度2-8℃ 0-6°C
UN Number 1993
Packing GroupIII
Hazard Class3

其他信息

  • 方法二:将干燥的溴素滴加入沸腾的氟苯和吡啶的混合物中,反应产生的溴化氢用水吸收。然后继续加热2h。冷却,加入氢氧化钠溶液,用乙醚萃取,萃取液加无水碳酸钾干燥,分馏。75-90℃的馏分为未反应的氟苯,148-154℃的馏分为对溴氟苯。产率约49%。
  • 下游产品:4-氟-3-(羟甲基)苯基硼酸
  • MSDS 信息:1-Bromo-4-fluorobenzene(460-00-4).msds
  • 上游原料:碳酸钾 --> 溴 --> 氟化苯
  • 用途二:1-溴-4-氟苯是杀菌剂氟硅唑的中间体。
  • Alfa Aesar:1-溴-4-氟苯,99% 1-Bromo-4-fluorobenzene, 99%(460-00-4)
  • Sigma Aldrich:460-00-4(sigmaaldrich)
  • Hazard Note:Flammable/Irritant
  • 方法一:其制备方法是在反应器中加入氟苯和少许铁粉为催化剂,在5~15℃加入溴,而在40℃反应,直到溴消失为止,得到产品。
  • 图谱信息:对溴氟苯(460-00-4)质谱(MS) 对溴氟苯(460-00-4)红外图谱(IR1) 对溴氟苯(460-00-4)核磁图( 13 CNMR)
  • 对溴氟苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010392 对溴氟苯 50ml 198元 2011/04/16 S0675 4-溴氟苯(1mg/ml的甲醇溶液)[水分析用内部标准] 4-Bromofluorobenzene (1mg/ml in Methanol) [Internal standard for Water Analysis] 1ML 198元 2011/04/16 B0884 4-溴氟苯 4-Bromofluorobenzene 25G 202元
  • 海关编码:29036990
  • 不溶于水,溶于甲醇、乙醇、乙醚、丙酮和2-丙醇。
  • 用途一:用于医药、农药的合成
  • 内标液和替代液
  • Acros Organics:对溴氟苯 4-Bromofluorobenzene, 99%(460-00-4)
  • 用途三:有机合成中间体。
  • TCI Shanghai:4-溴氟代苯(1mg/ml的甲醇溶液)[水分析用内部标准] 4-Bromofluorobenzene (1mg/ml in Methanol) [Internal standard for Water Analysis](460-00-4)
  • MOL 文件:460-00-4.mol

化学结构图

CAS 460-00-4  MFCD00000342
SMILES: Fc1ccc(Br)cc1

化学属性

Mol. FormulaC6H4BrF
Mol. Weight175.00
Refractive index1.5260 to 1.5290
Boiling Point153°C(lit.)
Density1.593
Melting Point-16
Flash Point56°C(lit.)
TSCAYes
Appearance 1.5270,相对密度 1.593,不溶于水,溶于苯、甲苯、醚等有机溶剂。 1-溴-4-氟苯是无色液体,m.p.-16℃,b.p.150℃,n 20

别名和识别编码

Chemical Name4-Bromofluorobenzene
CAS Number460-00-4
Alfabeta NameBROMOFLUOROBENZENE 14---
MDL NumberMFCD00000342
PubChem Substance ID9993
EC Number207-300-2
Beilstein Registry Number5,209
Reaxys-RN774102
Synonym 4-Fluorobromobenzene P-BROMOFLUOROBENZENE 4-Fluorophenyl bromide 1-bromo-4-fluoro-benzen 1-Bromo-4-fluorobenzene 对氟溴苯;4-溴氟苯;1-溴-4-氟苯 p-fluorophenylbromide p-Fluorbrombenzol 1-Fluoro-4-bromobenzene 1-氟-4-溴苯 nsc10268 4-bromofluorobenzene 4-FLUOROBROMOBENZENE 4-Bromo-1-fluorobenzene Benzene, 1-bromo-4-fluoro- 1-溴-4-氟苯 1-Bromo-4-fluorobenzene; p-Bromofluorobenzene Benzene,1-bromo-4-fluoro- 4-fluorophenylbromide 4-Bromofluorobenzene
Chemical Name Translation对氟溴苯
InChIKeyAITNMTXHTIIIBB-UHFFFAOYSA-N
LabNetwork Molecule IDLN00176996
InChIInChI=1S/C6H4BrF/c7-5-1-3-6(8)4-2-5/h1-4H

系列性分类


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