Tetrahydrofurfurylamine 2-四氢糠胺

CAS 4795-29-3 MFCD00005373

化学结构图

4795-29-3
SMILES: NCC1CCCO1

化学属性

Mol. FormulaC₅H₁₁NO
Mol. Weight101.15
Refractive index1.4540 to 1.4580
Boiling Point-
Density0.98
Flash Point-
TSCAYes
SolubilityMISCIBLE
Stability对空气和湿度敏感

别名和识别编码

Chemical Name2-Tetrahydrofurfurylamine
Synonym (±)-2-(Aminomethyl)tetrahydrofuran (+/-)-2-(Aminomethyl)tetrahydrofuran (+/-)-TETRAHYDROFURFURYLAMINE (+/-)-四氢呋喃胺/2-四氢糠胺 (n)-tetrahydrofurfurylamine (±)-2-(Aminomethyl)tetrahydrofuran (±)-四氢糠胺 2-(Aminomethyl)tetrahydrofuran 2-AMINOMETHYL-TETRAHYDROFURAN 2-Aminomethyltetrahydrofuran 2-Furanmethanamine, tetrahydro- 2-Furanmethanamine,tetrahydro- 2-Tetrahydrofufurylamine 2-Tetrahydrofurfurylamin 2-Tetrahydrofurylmethylamine 2-四氢 2-氨甲基四氢呋喃 Furfurylamine, tetrahydro- Tetrahydro-2-furanmethanamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number4795-29-3
PubChem Substance ID253298
EC Number225-351-9
Beilstein Registry Number102729
MDL Number-
Reaxys-RN102729
Chemical Name Translation2-四氢糠胺
Wiswesser Line NotationT5OTJ B1Z
LabNetwork Molecule IDLN00190824
InChIInChI=1S/C5H11NO/c6-4-5-2-1-3-7-5/h5H,1-4,6H2
InChIKeyYNOGYQAEJGADFJ-UHFFFAOYSA-N
Canonical SMILES-
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; alicycle; 5ring; ether; 1fragment
  • {SNA} Building Blocks, C4 to C7, Chemical Synthesis, Furans, Heterocyclic Building Blocks

产品应用

  • Tetrahydrofurfurylamine was used to study specific interactions between unlike molecules by calculating the molar excess enthalpies

相关文献及参考

  • Beilstein:18(2)415
  • Short: IV/10A
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSLV0175000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
UN Number 2943 UN 2943 3/PG 3 UN2943
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Packing GroupIII
Storage condition +4 4 4°C, Hygroscopic Air Sensitive & Hygroscopic Flammables area 密封保存
Hazard Class3
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

Restrict 危险品

其他信息

  • 可燃性危险特性:易燃; 高热放出有毒氮氧化物气体
  • 图谱信息:2-四氢糠胺(4795-29-3)红外图谱(IR1) 2-四氢糠胺(4795-29-3)质谱(MS)
  • 见光、接触空气、受热或久贮易变质。能与乙醇、乙醚、水相混溶。有腐蚀性。
  • 储运特性:库房通风低温干燥; 与氧化剂分开储运
  • MOL 文件:4795-29-3.mol
  • 毒性分级:高毒
  • 急性毒性:腹注-小鼠 LD50: 200 毫克/公斤
  • Acros Organics:2-（胺甲基）四氢呋喃 Tetrahydrofurfurylamine, 97%(4795-29-3)
  • 灭火剂:干粉, 二氧化碳, 砂土, 泡沫
  • 外观性质:无色至黄色液体, 有氨味。
  • Sigma Aldrich:4795-29-3(sigmaaldrich)
  • 类别:易燃液体
  • Alfa Aesar:(±)-四氢呋喃-2-甲胺,97% (+/-)-Tetrahydrofurfurylamine, 97%(4795-29-3)
  • MSDS 信息:四氢糠胺(4795-29-3).msds
  • 海关编码:29321900
  • 2-四氢糠胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1072 四氢糠胺 Tetrahydrofurfurylamine 500ML 1190元 2014/06/02 T1072 四氢糠胺 Tetrahydrofurfurylamine 25ML 163元 2010/06/21 157820050 2-四氢糠胺 Tetrahydrofurfurylamine 97% 5 GR 251元
  • TCI Shanghai:四氢糠胺 Tetrahydrofurfurylamine,>;95.0%(T)(4795-29-3)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Coumarins 香豆素
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Furans 呋喃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Furans 呋喃
  5. C4 to C7 - Furans

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