Tetrahydrofurfurylamine 四氢糠胺

CAS 4795-29-3 MFCD00005373

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分类

  • {uni_hamburg} no charge; oxygen heterocycle; alicycle; 5ring; ether; 1fragment
  • {SNA} Building Blocks, C4 to C7, Chemical Synthesis, Furans, Heterocyclic Building Blocks

产品应用

  • Tetrahydrofurfurylamine was used to study specific interactions between unlike molecules by calculating the molar excess enthalpies

相关文献及参考

  • Beilstein:18(2)415
  • Short: IV/10A
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSLV0175000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
UN Number 2943 UN 2943 3/PG 3 UN2943
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Packing GroupIII
Storage condition Air Sensitive & Hygroscopic 密封保存 Flammables area
Hazard Class3
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

其他信息

  • 可燃性危险特性:易燃; 高热放出有毒氮氧化物气体
  • 图谱信息:2-四氢糠胺(4795-29-3)红外图谱(IR1) 2-四氢糠胺(4795-29-3)质谱(MS)
  • 见光、接触空气、受热或久贮易变质。能与乙醇、乙醚、水相混溶。有腐蚀性。
  • 储运特性:库房通风低温干燥; 与氧化剂分开储运
  • MOL 文件:4795-29-3.mol
  • 毒性分级:高毒
  • 急性毒性:腹注-小鼠 LD50: 200 毫克/公斤
  • Acros Organics:2-(胺甲基)四氢呋喃 Tetrahydrofurfurylamine, 97%(4795-29-3)
  • 灭火剂:干粉, 二氧化碳, 砂土, 泡沫
  • 外观性质:无色至黄色液体, 有氨味。
  • Sigma Aldrich:4795-29-3(sigmaaldrich)
  • 类别:易燃液体
  • Alfa Aesar:(±)-四氢呋喃-2-甲胺,97% (+/-)-Tetrahydrofurfurylamine, 97%(4795-29-3)
  • MSDS 信息:四氢糠胺(4795-29-3).msds
  • 海关编码:29321900
  • 2-四氢糠胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1072 四氢糠胺 Tetrahydrofurfurylamine 500ML 1190元 2014/06/02 T1072 四氢糠胺 Tetrahydrofurfurylamine 25ML 163元 2010/06/21 157820050 2-四氢糠胺 Tetrahydrofurfurylamine 97% 5 GR 251元
  • TCI Shanghai:四氢糠胺 Tetrahydrofurfurylamine,>;95.0%(T)(4795-29-3)

化学结构图

4795-29-3
SMILES: NCC1CCCO1

化学属性

Mol. FormulaC5H11NO
Mol. Weight101.15
Refractive index1.4540 to 1.4580
Boiling Point153-154
Density0.98
Flash Point48°C(lit.)
TSCAYes
SolubilityMISCIBLE
Stability对空气和湿度敏感

别名和识别编码

Chemical NameTetrahydrofurfurylamine
Synonym tetrahydro-2-furanmethanamin Tetrahydro-2-furanylmethylamine 2-四氢 (+/-)-2-(Aminomethyl)tetrahydrofuran (±)-四氢糠胺 tetrahydro-furfurylamin 2-Furanmethanamine,tetrahydro- 2-(Aminomethyl)tetrahydrofuran Furfurylamine, tetrahydro- Tetrahydrofurfurylamine (±)-2-(Aminomethyl)tetrahydrofuran (+/-)-四氢呋喃胺/2-四氢糠胺 2-AMINOMETHYL-TETRAHYDROFURAN 2-Tetrahydrofurylmethylamine 2-氨甲基四氢呋喃 (n)-tetrahydrofurfurylamine 2-Furanmethanamine, tetrahydro- (±)-2-(Aminomethyl)tetrahydrofuran 2-Tetrahydrofurfurylamin 四氢呋喃胺 2-Aminomethyltetrahydrofuran 2-Tetrahydrofufurylamine (+/-)-TETRAHYDROFURFURYLAMINE
CAS Number4795-29-3
PubChem Substance ID253298
EC Number225-351-9
Beilstein Registry Number102729
MDL NumberMFCD00005373
Reaxys-RN102729
Chemical Name Translation四氢糠胺
Wiswesser Line NotationT5OTJ B1Z
LabNetwork Molecule IDLN00190824
InChIInChI=1S/C5H11NO/c6-4-5-2-1-3-7-5/h5H,1-4,6H2
InChIKeyYNOGYQAEJGADFJ-UHFFFAOYSA-N

系列性分类


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