4-Bromophenylboronic acid 4-溴苯硼酸

CAS 5467-74-3 MFCD00002104

化学结构图

5467-74-3
SMILES: OB(O)c1ccc(Br)cc1

化学属性

Mol. FormulaC6H6BBrO2
Mol. Weight200.83
Melting Point284-288°C
TSCAT
Density1.67
Boiling Point315°C at 760 mmHg

别名和识别编码

Chemical Name4-Bromophenylboronic Acid (contains varying amounts of Anhydride)
CAS Number5467-74-3
Alfabeta NameBROMOPHENYLBORONICACID 4-
MDL NumberMFCD00002104
Synonym p-Bromophenylboric acid {LY} p-Bromophenylboric acid para-bromophenylboric acid {} {LY} p-Bromophenylboric acid {} {} {LY} p-Bromophenylboric acid {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} p-Bromop
PubChem Substance ID79599
EC Number226-779-9
Beilstein Registry Number2936347
Reaxys-RN2936347
Chemical Name Translation4-溴苯硼酸
InChIKeyQBLFZIBJXUQVRF-UHFFFAOYSA-N
Wiswesser Line NotationQBQR DE
LabNetwork Molecule IDLN00159009
InChIInChI=1S/C6H6BBrO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
Canonical SMILESBrC1=CC=C(B(O)O)C=C1
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分类

  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents

产品应用

  • 4-Bromophenylboric acid

相关文献及参考

  • Weston, G.S., et al.: J. Med. Chem., 41, 4577 (1998),
  • Carbonylative cross-coupling with iodobenzenes and CO, catalyzed by trans-Dichlorobis(triphenyl­phosphine)­palladium(II)­, 10491, gives unsymmetrical diaryl ketones: Tetrahedron Lett., 34, 7595 (1993); J. Org. Chem., 63, 4726 (1998). For reactions of boronic acids, see Appendix 5.
  • 7. Zhang, J.; et al. , Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Green Chem. 4th ed., 14 , 912-916, (2012)
  • Beilstein:16(2)638
  • 5. Qi, Q.; Shen, Q.; Lu, L., Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature J. Am. Chem. Soc. 15th ed., 134 , 6548-6551, (2012) 摘要
  • GC reagent for diols: J. Chromat., 158, 33 (1978); 186, 307 (1979).
  • 6. Shen, K.; Han, X.; Lu, X., Cationic Pd(II)-Catalyzed Highly Enantioselective Arylative Cyclization of Alkyne-Tethered Enals or Enones Initiated by Carbopalladation of Alkynes with Arylboronic Acids Org. Lett. 7th ed., 14 , 1756-1759, (2012) 摘要

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
RTECSCY8650000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03201

其他信息

  • Sigma Aldrich:5467-74-3(sigmaaldrich)
  • TCI Shanghai:4-溴苯硼酸(含有数量不等的酸酐) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride)(5467-74-3)
  • TSCA:T
  • MSDS 信息:4-Bromobenzeneboronic acid(5467-74-3).msds
  • 4-溴苯硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1858 4-溴苯硼酸(含有数量不等的酸酐) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride) 1G 80元 2014/06/02 B1858 4-溴苯硼酸(含有数量不等的酸酐) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride) 25G 735元 2014/06/02 B1858 4-溴苯硼酸(含有数量不等的酸酐) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride) 5G 210元
  • MOL 文件:5467-74-3.mol
  • Hazard Note:Irritant
  • Acros Organics:4-Bromophenylboronic acid, 98%(5467-74-3)
  • Alfa Aesar:4-溴苯硼酸,97+% 4-Bromobenzeneboronic acid, 97+%(5467-74-3)

系列性分类


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