(R)-beta-Aminophenethyl alcohol (R)-(-)-2-苯甘氨醇

CAS 56613-80-0 MFCD00008062

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI 447069
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯甘氨醇
98% 5g 90
LN-CN
中国国内现货 96-99 %
INFI 447069
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯甘氨醇
98% 25g 270
96-99 %
INFI 447069
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯甘氨醇
98% 100g 760
LN-CN
中国国内现货 96-99 %
Innochem 580770
(R)-(-)-2-Phenylglycinol
99% 5g 98
BJ-CN
中国国内现货 96-99 %
Innochem 580770
(R)-(-)-2-Phenylglycinol
99% 25g 258
96-99 %
Innochem 580770
(R)-(-)-2-Phenylglycinol
99% 100g 732
96-99 %
TCI 131356
(R)-(-)-2-Phenylglycinol
98.0%(GC&T;) 5g 690
SH-CN TJ-CN TK-JP
中国国内现货 99
TCI 131356
(R)-(-)-2-Phenylglycinol
98.0%(GC&T;) 25g 2,360
SH-CN TJ-CN TK-JP
中国国内现货 99
Alfa 131358
(R)-(-)-2-Phenylglycinol, 98%
98% 1g 255
SH-CN CN
中国国内现货 99
Alfa 131358
(R)-(-)-2-Phenylglycinol, 98%
98% 5g 836
SH-CN CN
中国国内现货 99
Alfa 131358
(R)-(-)-2-Phenylglycinol, 98%
98% 25g 3,004
SH-CN CN
中国国内现货 99
J&K 292495
D-Phenylglycinol, 98%, ee: 99%
98% 1g 60
SH
中国国内现货 99
J&K 292495
D-Phenylglycinol, 98%, ee: 99%
98% 5g 213
HB SH
中国国内现货 99
J&K 292495
D-Phenylglycinol, 98%, ee: 99%
98% 25g 849
SH
中国国内现货 99
Matrix 65841
(R)-(-)-2-Phenylglycinol
95+% 25g 452
99
Matrix 65841
(R)-(-)-2-Phenylglycinol
95+% 100g 1,250
99
TRC 86090
D-Phenylglycinol
1g 495
0
TRC 86090
D-Phenylglycinol
5g 550
0
TRC 86090
D-Phenylglycinol
10g 770
0
TRC 86090
D-Phenylglycinol
25g 1,500
0
TRC 86090
D-Phenylglycinol
100g 5,500
0
Aldrich 131270
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯甘氨醇
98% 5g 782
SH
中国国内现货 99
Acros 319086
(R)-(-)-2-Phenylglycinol, 98%
98% 5g 428
SH-CN
中国国内现货 99
Fluka 325270
>=98.0% (sum of enantiomers, HPLC) 5g 1,383
99
Shao Yuan 386126
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯基甘氨醇
97+% 5g 90
SH-CN
中国国内现货 99
Shao Yuan 386126
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯基甘氨醇
97+% 25g 239
SH-CN
中国国内现货 99
Shao Yuan 386126
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯基甘氨醇
97+% 100g 774
SH-CN
中国国内现货 99
Adamas 447062
99% 1g 76
SH-CN
中国国内现货 99
Adamas 447063
99% 5g 122
SH-CN
中国国内现货 99
Adamas 447064
99% 25g 358
SH-CN
中国国内现货 99
Adamas 447065
99% 100g 920
SH-CN
中国国内现货 99
Sigma 447066
1g 366
0
Sigma 447066
5g 1,279
0
Energy-chemical 447067
D-Plenylglycinol D-苯甘氨醇
99% 5g 65
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 447067
D-Plenylglycinol D-苯甘氨醇
99% 25g 168
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 447067
D-Plenylglycinol D-苯甘氨醇
99% 100g 545
CN-BJ CN-SH
中国国内现货 99
Aladdin 447068
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯基乙醇胺
98% 5g 64
CN-SH
中国国内现货 99
Aladdin 447068
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯基乙醇胺
98% 25g 167
CN-SH
中国国内现货 99
Aladdin 447068
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯基乙醇胺
98% 100g 524
CN-SH
中国国内现货 99
Ark 553667
98% 5g 80
SH-CN
中国国内现货 99
Ark 553667
98% 10g 120
SH-CN
中国国内现货 99
Ark 553667
98% 25g 240
SH-CN
中国国内现货 99
Ark 553667
98% 100g 600
SH-CN
中国国内现货 99
Ark 553667
98% 500g 2,400
SH-CN
中国国内现货 99
Acros 592960
98% 5g 525
96-99 %
Acros 592960
98% 25g 1,808
96-99 %
Aladdin 624324
25g 167
Aladdin 624326
5g 64
Aladdin 624329
100g 545
3A 633567
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯基甘氨醇
99% 5g -
96-99 %
3A 633567
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯基甘氨醇
99% 25g -
96-99 %
3A 633567
(R)-(-)-2-Phenylglycinol (R)-(-)-2-苯基甘氨醇
99% 100g -
96-99 %
Key Organic 760779
(R)-(-)-2-Amino-2-phenylethanol
>98% 100g 2,975
96-99 %
Amethyst 789342
D-Phenylglycinol, 98%, ee: 99%
98% 1g 54
SH
中国国内现货 96-99 %
Amethyst 789342
D-Phenylglycinol, 98%, ee: 99%
98% 5g 192
SH
中国国内现货 96-99 %

分类

  • {SNA} Amino Acid Derivatives, Amino Alcohols, Chemical Biology, Chemical Synthesis, Peptide Chemistry
  • Catalyst
  • {SA} Amino Acid Derivatives, Amino Alcohols, Chemical Biology, Chemical Synthesis, Peptide Chemistry
  • Chiral Reagents
  • {SNA} Amino Acids & Derivatives, Amino Alcohols, Chemical Biology, Chemical Synthesis, Peptide Chemistry
  • Pharmaceuticals
  • Amines
  • Intermediates & Fine Chemicals
  • Aromatics

产品应用

  • 作为合成的结构单元使用的手性 β-氨基醇。 本氨基醇可用于由三氟丙酮酸乙酯制备手性亚胺或噁唑烷。然后,可将这些中间体用于合成 α-三氟甲基脯氨酸的两种对映体。

相关文献及参考

  • Tetrahedron Lett. 45 , 5287, (2004)
  • Condensation with glutaraldehyde gives a useful intermediate in asymmetric synthesis of alkaloids: Org. Synth. Coll., 9, 176 (1998):
  • Beilstein:13(4)1835
  • Condensation with glutaraldehyde gives a useful intermediate in asymmetric synthesis of alkaloids: Org. Synth. Coll., 9, 176 (1998):
  • Kristensen, T. E. et al.: Eur. J. Org. Chem., 30, 5185 (2009); Liu, W. et al.: You. Xua., 26, 518 (2006);
  • Starting material for the enantioselective synthesis of 2,6-disubstituted piperazines: Synthesis, 833 (1996), and for chiral ɑ-amino phosphonates: Org. Synth., 75, 19 (1997).
  • Starting material for the enantioselective synthesis of 2,6-disubstituted piperazines: Synthesis, 833 (1996), and for chiral ɑ-amino phosphonates: Org. Synth., 75, 19 (1997).

安全信息

Warnings
  • IRRITANT
WGK Germany3
Personal Protective Equipment
  • Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word
  • Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261305+351+338
  • P332+313 IF SKIN irritation occurs: Get medical advice/attention. 如果发生皮肤刺激:获取医疗咨询/就医。
  • P305+351+338+337+313
  • P302+350 IF ON SKIN: Gently wash with plenty of soap and water. 如果在皮肤上:轻轻地用大量肥皂和水清洗
  • P337+313 IF eye irritation persists: Get medical advice/attention. 如果眼睛刺激持续:获取医疗咨询/就医。
  • P302+352+332+313+362+364
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition
  • Air Sensitive
  • 0-10°C
GHS Symbol

化学结构图

CAS 56613-80-0  MFCD00008062
SMILES: N[C@@H](CO)c1ccccc1

化学属性

Mol. FormulaC8H11NO
Mol. Weight137.18
Melting Point75-77
TSCANo
Density1.104
Stability对空气敏感

别名和识别编码

Chemical Name(R)-(-)-2-Phenylglycinol
CAS Number56613-80-0
Alfabeta NamePHENYLGLYCINOL R2(())----
MDL NumberMFCD00008062
Synonym
  • (R)-(-)-2-Amino-2-phenylethanol
  • (R)-(-)-2-氨基-2-苯基乙醇;(R)-(-)-2-苯基-2-氨基乙醇
  • (R)-2-氨基-2-苯乙醇 D-(-)-α-苯甘氨醇
  • (R)-2-氨基-2-苯乙醇 D-(-)-α-苯甘氨醇
  • R-苯甘氨醇,右旋苯甘氨醇,2-苯甘氨酸
  • D-(-)-α-苯甘氨醇
    Beilstein Registry Number2935848
    PubChem Substance ID 87575300
    EC Number260-287-5
    Reaxys-RN2935848
    Chemical Name Translation(R)-(-)-2-苯甘氨醇
    LabNetwork Molecule IDLN00009350
    InChIKeyIJXJGQCXFSSHNL-UHFFFAOYSA-N

    系列性分类