Cobalt(II) chloride hexahydrate 氯化钴(II)六水合物

CAS 7791-13-1 MFCD00149652

化学结构图

7791-13-1
SMILES: O.O.O.O.O.O.[Cl-].[Cl-].[Co+2]

化学属性

Mol. FormulaCl2CoH12O6
Mol. Weight237.93
Density1.92
Vapor Pressure40 mmHg ( 0 °C)
SolubilitySoluble in water (970 g/ml at 20 °C), acetone, ether, and alcohols.
TSCAYes
Melting Point86 °C
Boiling Point1049 °C at 760 mmHg
Stability易吸潮

别名和识别编码

Chemical NameCobalt(II) chloride hexahydrate
Synonym Cobalt(II) chloride hexahydrate {LY} Cobalt(II) chloride hexahydrate {} {LY} Cobalt(II) chloride hexahydrate {} {} {LY} Cobalt(II) chloride hexahydrate {} {} {} {LY} Cobalt(II) chloride hexahydrate {} {} {} {} {LY} Cobalt(II) chloride hexahydrate {} {} {} {} {} {LY} Cobalt(II) chloride hexahydrate {} {} {} {} {} {} {LY} Cobalt(II) chloride hexahydrate {} {} {} {} {} {} {} {LY} Cobalt(II) chloride hexahydrate {} {} {} {} {} {} {} {} {LY} Cobalt(II) chloride hexahydrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cobalt(II) chloride hexahydrate {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Cobalt(II) chloride hexahydrate {} {} {} {} {} {} {} {} {} {} {} {LY} Cobalt(II) chloride hexahydrate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cobalt(II) chloride hexahydrate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cobalt(II) chloride hexahydrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Coba
CAS Number7791-13-1
PubChem Substance ID87561574
EC Number231-589-4
MDL NumberMFCD00149652
Beilstein Registry Number2384789
Merck Number2437
Chemical Name Translation氯化钴(II)六水合物
Reaxys-RN8127941
Wiswesser Line NotationCO G2 &QH 6
LabNetwork Molecule IDLN00196073
Canonical SMILESCl[Co]Cl.O.[6]
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分类

  • {SNA} Miscellaneous Reagents and Supplements, 细胞培养, 试剂和添加剂
  • {SA} Cell Culture, Miscellaneous Reagents and Supplements, Reagents and Supplements
  • {SNA} Analytical Reagents, Analytical/Chromatography, Cobalt Salts, Drying Agents, Essential Chemicals, Research Essentials, Salts, 特定应用试剂
  • {SNA} Cell Culture, Miscellaneous Reagents and Supplements, Reagents and Supplements
  • {uni_hamburg} no charge; 3fragments; ionic
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Cobalt, Cobalt Salts, Essential Chemicals, Research Essentials, Salts
  • {SNA} Cobalt Salts, Essential Chemicals, Research Essentials,
  • {SNA} Companion Products and Rea

产品应用

  • An inducer of HIF-1 production used to study apoptotic effects in HepG2 cells.

相关文献及参考

  • Short: II/25A
  • Merck: 14,2437
  • Short: III/20b

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 9 T,N
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H350 May cause cancer 可能致癌
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSGG0200000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P333+P313+P362+P364
  • P304+P340+P342+P311
  • P305+P351+P338
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R42/43
  • R49 May cause cancer by inhalation 吸入会致癌
  • R50/53
  • R60 May impair fertility 可能降低生殖能力
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Packing GroupIII
UN Number 2923 3077 UN 3260 8/PG 2 UN3077
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class9 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 25400 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EQSSDX Environmental Quality and Safety, Supplement.  (Stuttgart, Fed. Rep.
   Ger.)  V.1-5, 1975-76. Discontinued.  Volume(issue)/page/year: 1,1,1975

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EQSSDX Environmental Quality and Safety, Supplement.  (Stuttgart, Fed. Rep.
   Ger.)  V.1-5, 1975-76. Discontinued.  Volume(issue)/page/year: 1,1,1975

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EQSSDX Environmental Quality and Safety, Supplement.  (Stuttgart, Fed. Rep.
   Ger.)  V.1-5, 1975-76. Discontinued.  Volume(issue)/page/year: 1,1,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 26 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATXKA8 Archiv fuer Toxikologie.  (Berlin, Fed. Rep. Ger.)  V.15-31, 1954-74.
    For publisher information, see ARTODN.  Volume(issue)/page/year:
   24,235,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION

TYPE OF TEST            : Phage inhibition capacity
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 25 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 286,173,1993

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Mammary gland
DOSE/DURATION           : 2 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 261,131,1991

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 4500 ug/L
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 18,177,1997

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 1932 mg/kg
SEX/DURATION            : male 12 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
   Reproductive - Paternal Effects - other effects on male
   Endocrine - androgenic
REFERENCE :
   REPTED Reproductive Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1987-  Volume(issue)/page/year:
   2,45,1988

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 182 mg/kg
SEX/DURATION            : male 13 week(s) pre-

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 6056 mg/kg
SEX/DURATION            : male 12 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - male fertility index (e.g. # males impregnating
   females per # males exposed to fertile nonpregnant females)
REFERENCE :
   REPTED Reproductive Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1987-  Volume(issue)/page/year:
   2,45,1988

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 143 mg/kg
SEX/DURATION            : male 3 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
REFERENCE :
   REPTED Reproductive Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1987-  Volume(issue)/page/year:
   2,45,1988

其他信息

  • 所属类别二:饲料添加剂: 矿物质添加剂
  • {
  • 毒性分级:中毒
  • 可燃性危险特性:不燃; 高热分解有毒氯化物烟雾
  • 参考质量标准一:GB8255-87 含量(CoCl2·6H2O)/% ≥98.0 钴(Co)/% ≥24.3 水不溶物/% ≤0.03 铅(以Pb计)/% ≤0.00l 砷(以As计)/% ≤0.0005 细度(过800μm筛)/% ≥95
  • 敏感性:Hyg
  • 六水氯化钴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 10007290 氯化钴;六水合氯化钴;二氯化钴;氯化亚钴 100g 416元 2011/08/23 10007216 氯化钴;六水合氯化钴;二氯化钴;氯化亚钴 100g 37元 2011/08/23 10007226 氯化钴;六水合氯化钴;二氯化钴;氯化亚钴 100g 35元
  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • MOL 文件:7791-13-1.mol
  • {Chem
  • Acros Organics:六水合二氯化钴 Cobalt(II) chloride hexahyd
  • 外观性质:红色单斜晶
  • 方法二:氯化钴的生产采用金属钴法和含钴废料法。工业上一般采用金属加工和以电子工业的含钴废料为原料，用混酸（盐酸和硝酸）溶解而得。 将盐酸加入反应器，再投入含钴废料于80℃下进行反应，并视金属
  • 防护措施:吸入氯化钴的粉尘，有时出现支气管哮喘。如一天内进入体内500mg时，引起食欲不振、呕吐、腹泻、面部和四肢发红。研磨氯化钴时能引起急性皮炎，出现大量的散在的红色丘疹和小结节、水肿；有时表面形成溃疡。 生产工人应穿工作服、戴防毒口罩，防止粉尘吸
  • 急性毒性:口服- 大鼠 LD50 766 毫克/ 公斤; 腹腔- 小鼠 LD50: 90 毫克/公斤
  • 用途四:用于制气压计、比重计、隐显墨水等。氯化钴试纸在干燥时是蓝色，潮湿时转变为粉红色。硅胶中加一定量的氯化钴，可指示硅胶的吸湿程度。也可用于电镀工业，还可用作饲料添加剂。
  • 用途一:用作油漆催干剂、军用毒气和氨气吸收剂、啤酒泡沫稳定剂、变色硅胶干燥指示剂、玻璃和陶瓷着色剂等
  • 用
  • Alfa Aesar:六水合氯化钴(II),Puratronic|r,99.998%(metalsbasis) Cobalt(II) chloride hexahydrate, Puratronic, 99.998% (metals basis)(7791-13-1)
  • Sigma A
  • 所属类别一:无机化工产品: 无机盐: Ce液化物及氯酸盐
  • 方法一:金属钴法将盐酸加人反应器中，再逐渐加入金属钴，使其溶解并加热至80℃进行反应，并视金属钴溶解情况适当地加入硝酸，把生成的氯化钴溶液用过氧化氢净化除铁，必要时加入碳酸钠或氨水调节，以保证净化完全。经净化后的氯化钴溶液用盐酸调节至Ph2～3。经过滤、蒸发至沸腾、冷却结晶、离心分离、干燥，制得氯化钴成品。其 Co+2HCl→CoC12+H2 含钴废料法 将各种含钴废料(下脚料)，经硝酸、盐酸、硫酸溶解，加人硫化钠转化成NiS·CoS。经通入空气氧化得到NiS()4·(30S()4，加人烧碱，通入氯气，分离得到氢氧化钴和硫酸镍溶液，将氢氧化钴加入盐酸进行反应生成氯化钴，过滤后水洗，得到粗制氯化钻，加入过氧化氢精制，再经蒸发浓缩、冷却结晶、离心分离、干燥，制得氯化钴成品。其 Co(OH)2+2HCl→CoCl2+2H2O
  • Cobalt chloride hexahydrate is the most common form of this inorganic compound which is a deep rose color in the hydrated form. The dramatic color change of blue-purple Cobalt(II) chloride to the rose color when hydrated makes Cobalt(II) c

系列性分类

  1. Life Science 生命科学
  2. Cell Culture 细胞培养
  3. Reagents and Supplements - Cell Culture
  4. Miscellaneous Reagents and Supplements - Reagents and Supplements
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cobalt Catalysis 钴催化剂
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Inorganic Salts, Solutions and Reagents - Essential Chemicals
  4. ACS Grade - Inorganic Salts, Solutions and Reagents
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Inorganic Salts, Solutions and Reagents - Essential Chemicals
  4. Reagent Grade - Inorganic Salts, Solutions and Reagents
  1. Life Science 生命科学
  2. Cell Culture 细胞培养
  3. Serum-free Media - Cell Culture
  4. Insect Platform - Serum-free Media
  5. Companion Products and Reagents - Insect Platform
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  5. C-D, Puriss p.a. ACS - Puriss p.a. ACS
  1. CVD & ALD Precursors
  1. CVD & ALD Precursors

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