(-)-DIP-Chloride (-)-B-Chlorodiisopinocampheylborane (-)-二异松蒎基氯硼烷

CAS 85116-37-6 MFCD00074807

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H78932
(-)-DIP-Chloride (-)-B-Chlorodiisopinocampheylborane (-)-二异松蒎基氯硼烷
1.7 M solution in heptane, SpcSeal 25mL ¥ 90
1.7 M solution 庚烷
INFI H78932
(-)-DIP-Chloride (-)-B-Chlorodiisopinocampheylborane (-)-二异松蒎基氯硼烷
1.7 M solution in heptane, SpcSeal 100mL ¥ 230
1.7 M solution 庚烷
INFI H78932
(-)-DIP-Chloride (-)-B-Chlorodiisopinocampheylborane (-)-二异松蒎基氯硼烷
1.7 M solution in heptane, SpcSeal 500mL ¥ 740
库存 白银市
中国国内现货 1.7 M solution 庚烷
INFI H85621
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.8 M solution in hexanes, SpcSeal 25mL ¥ 230
1.8 M solution 己烷
INFI H85621
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.8 M solution in hexanes, SpcSeal 100mL ¥ 490
1.8 M solution 己烷
INFI H85621
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.8 M solution in hexanes, SpcSeal 500mL ¥ 1,240
1.8 M solution 己烷
Innochem C2301
200mL ¥ 850
Bellen Bellen10017442
(-)-DIP-Chloride (-)-B-Chlorodiisopinocampheylborane (-)-二异松蒎基氯硼烷
25mL ¥ 110
Bellen Bellen10017442
(-)-DIP-Chloride (-)-B-Chlorodiisopinocampheylborane (-)-二异松蒎基氯硼烷
100mL ¥ 290
Bellen Bellen10017442
(-)-DIP-Chloride (-)-B-Chlorodiisopinocampheylborane (-)-二异松蒎基氯硼烷
500mL ¥ 930
TCI C2023
(-)- B -Chlorodiisopinocampheylborane (55-65% in Heptane, ca . 1.7mol/L) >
100mL ¥ 935
库存 上海市 Tokyo, Japan
中国国内现货 50+ % solution 庚烷
TCI C1615
(-)-B-Chlorodiisopinocampheylborane (60% in Hexane, ca. 1.7mol/L)
100mL ¥ 940
库存 上海市 北京 Tokyo, Japan
中国国内现货 60+ % solution 己烷
J&K 593715
(-)-B-Chlorodiisopinocampheylborane, 60 wt.% solution in heptane, ca.1.7 M, J&KSeal;
N/A 25g ¥ 287
库存 HB
中国国内现货 96-99 %
J&K 593715
(-)-B-Chlorodiisopinocampheylborane, 60 wt.% solution in heptane, ca.1.7 M, J&KSeal;
N/A 100g ¥ 946
库存 HB
中国国内现货 96-99 %
Aldrich 317020
(?)-DIP-Chloride
- 5g ¥ 366
96-99 %
Aldrich 317020
(?)-DIP-Chloride
- 25g ¥ 954
96-99 %
Aldrich 317020
(?)-DIP-Chloride
- 100g ¥ 2,698
库存 SH
中国国内现货 96-99 %
Aldrich 655295
(?)-DIP-Chloride? solution
65-75?wt. 25mL ¥ 1,534
96-99 %
Aldrich 655295
(?)-DIP-Chloride? solution
65-75?wt. 100mL ¥ 4,583
96-99 %
Aldrich 648426
(-)-DIP-Chloride™ solution (-)-DIP-Chloride™ 溶液
50-65 wt. % in hexanes 50-65?wt. % in hexanes 25mL ¥ 1,646
96-99 %
Aldrich 648426
(-)-DIP-Chloride™ solution (-)-DIP-Chloride™ 溶液
50-65 wt. % in hexanes 50-65?wt. % in hexanes 100mL ¥ 4,726
96-99 %
Energy-chemical E060104
(-)-Diisopinocampheyl chloroborane (-)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L 25mL ¥ 108
库存 上海市 北京市
中国国内现货 60
Energy-chemical E060104
(-)-Diisopinocampheyl chloroborane (-)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L 100mL ¥ 295
库存 上海市 北京市
中国国内现货 60
Energy-chemical E060104
(-)-Diisopinocampheyl chloroborane (-)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L 500mL ¥ 975
库存 上海市 北京市
中国国内现货 60
Aladdin C104780
(-)-B-Chlorodiisopinocampheylborane (-)二异松蒎基氯硼烷
60% in Heptane,ca. 1.7mol/L 25mL ¥ 107
库存 上海市
中国国内现货 96-99 %
Aladdin C104780
(-)-B-Chlorodiisopinocampheylborane (-)二异松蒎基氯硼烷
60% in Heptane,ca. 1.7mol/L 100mL ¥ 294
库存 上海市
中国国内现货 96-99 %
Aladdin C104780
(-)-B-Chlorodiisopinocampheylborane (-)二异松蒎基氯硼烷
60% in Heptane,ca. 1.7mol/L 500mL ¥ 974
96-99 %
Aladdin C120993
(-)-B-Chlorodiisopinocampheylborane (-)二异松蒎基氯硼烷
60% in Hexane, ca. 1.7mol/L 25mL ¥ 107
库存 上海市
中国国内现货 96-99 %
Aladdin C120993
(-)-B-Chlorodiisopinocampheylborane (-)二异松蒎基氯硼烷
60% in Hexane, ca. 1.7mol/L 100mL ¥ 294
库存 上海市
中国国内现货 96-99 %
Aladdin C120993
(-)-B-Chlorodiisopinocampheylborane (-)二异松蒎基氯硼烷
60% in Hexane, ca. 1.7mol/L 500mL ¥ 974
96-99 %
Adamas 86376A
60% in Heptane, ca. 1.7Mol/L 100mL ¥ 290
库存 上海市 北京
中国国内现货 60
Adamas 86376B
60% in Heptane, ca. 1.7Mol/L 500mL ¥ 979
库存 北京
中国国内现货 60
TRC D486930
(-)-DIP-chloride (~60% in Heptane)
5g ¥ 1,100
TRC D486930
(-)-DIP-chloride (~60% in Heptane)
25g ¥ 1,500
TRC D486930
(-)-DIP-chloride (~60% in Heptane)
100g ¥ 4,750
TRC TRC-D486930
(-)-DIP-chloride (~60% in Heptan…
5g ¥ 1,320
96-99 %
TRC TRC-D486930
(-)-DIP-chloride (~60% in Heptan…
25g ¥ 1,800
96-99 %
TRC TRC-D486930
(-)-DIP-chloride (~60% in Heptan…
100g ¥ 5,700
96-99 %
Energy-chemical E060938
(-)-Diisopinocampheyl chloroborane (-)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L,Energyseal 100mL ¥ 362
库存 上海市 北京市
中国国内现货 60
Energy-chemical E060938
(-)-Diisopinocampheyl chloroborane (-)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L,Energyseal 500mL ¥ 1,170
库存 上海市 北京市
中国国内现货 60
Meryer M27959
(-)二异松蒎基氯硼烷
60%正己烷溶液, ca. 1.7mol/L 25mL ¥ 566
60
Meryer M27959
(-)二异松蒎基氯硼烷
60%正己烷溶液, ca. 1.7mol/L 100mL ¥ 893
60
Adamas 86376E
60% hexane solution 100mL ¥ 290
库存 上海市
中国国内现货 60+ %
3A A00060
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.7 M solution in heptane, SpcSeal 25mL ¥ 140
1.7 M solution Heptane
3A A00060
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.7 M solution in heptane, SpcSeal 100mL ¥ 380
1.7 M solution Heptane
3A A00060
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.7 M solution in heptane, SpcSeal 500mL ¥ 1,150
1.7 M solution Heptane
Aladdin C104780-100ml
60% in Heptane,ca. 1.7mol/L 100mL ¥ 294
库存 北京
中国国内现货 60+ % solution 庚烷
Aladdin C104780-25ml
60% in Heptane,ca. 1.7mol/L 25mL ¥ 107
库存 北京
中国国内现货 60+ % solution 庚烷
Aladdin C120993-25ml
60% in Hexane, ca. 1.7mol/L 25mL ¥ 107
库存 上海市 北京
中国国内现货 60+ % solution 己烷
Aladdin C120993-100ml
60% in Hexane, ca. 1.7mol/L 100mL ¥ 294
60+ % solution 己烷
Aladdin C104780-500ml
60% in Heptane,ca. 1.7mol/L 500mL ¥ 974
60+ % solution 庚烷
Aladdin C120993-500ml
60% in Hexane, ca. 1.7mol/L 500mL ¥ 974
60+ % solution 己烷
Aldrich 648418-25ML
50-65 wt. % in heptane 25mL ¥ 358
50+ % solution 庚烷
Aldrich 648426-25ML
50-65 wt. % in hexanes 25mL ¥ 1,733
50+ % solution 己烷
Aldrich 655295-25ML
65-75 wt. % in alpha-pinene 25mL ¥ 1,615
60+ %
Aldrich 648418-100ML
50-65 wt. % in heptane 100mL ¥ 1,040
50+ % solution 庚烷
Aldrich 648426-100ML
50-65 wt. % in hexanes 100mL ¥ 4,975
50+ % solution 己烷
Aldrich 317020-5G
5g ¥ 395
Aldrich 317020-25G
25g ¥ 1,030
Aldrich 317020-100G
100g ¥ 2,919
BD BD1282
Chlorobis((1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane (-)-二异松蒎基氯硼烷
90+% 25g ¥ 286
90+ %
BD BD1282
Chlorobis((1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane (-)-二异松蒎基氯硼烷
90+% 100g ¥ 791
90+ %
BD BD1282
Chlorobis((1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane (-)-二异松蒎基氯硼烷
90+% 500g ¥ 3,947
90+ %

分类

  • {uni_hamburg} no charge; carbocycle; alicycle; fused rings; 4ring; 6ring; chiral; 1fragment
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Reduction

相关文献及参考

  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.

安全信息

WGK Germany3
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 如果食入:立即呼叫中毒控制中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261305+351+338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P308+313 IF exposed or concerned: Get medical advice/attention. 如接触到或有疑虑:求医/就诊。
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P305+351+338+310
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P301+330+331+310
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P304+340+310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P210273280301+310
  • P241+242+243
  • P303+361+353+310+363
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Signal word
GHS Symbol
Personal Protective Equipment
  • Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
  • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
  • C
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R50/53
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R34 Causes burns 会导致灼伤
  • R10 Flammable 易燃
  • R37 Irritating to respiratory system 刺激呼吸道
Packing GroupII
Storage condition
  • 0-10
  • 0-10°C
  • 密封2-8°C保存
  • 2-8°C
UN Number
  • UN 3261 8/PG 2
Hazard Class3/8

其他信息

  • MOL 文件:85116-37-6.mol
  • F:10-21
  • Sigma Aldrich:85116-37-6(sigmaaldrich)
  • (-)-二异松蒎基氯硼烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1615 (-)-B-二异松蒎基氯硼烷(60%的己烷溶液,约1.7mol/L) (-)-B-Chlorodiisopinocampheylborane (60% in Hexane, ca. 1.7mol/L) 100ML 2570元 2014/06/02 C2023 (-)-B-二异松蒎基氯硼烷(60%的庚烷溶液,约1.7mol/L) (-)-B-Chlorodiisopinocampheylborane (60% in Heptane, ca. 1.7mol/L) 100ML 989元
  • 和水反应
  • TCI Shanghai:(-)-二异松蒎基氯硼烷(60%的正己烷溶液,约1.7mol/L) (-)-B-Chlorodiisopinocampheylborane (60% in Hexane, ca. 1.7mol/L)(85116-37-6)

化学结构图

CAS 85116-37-6  MFCD00074807
SMILES: C[C@H]1[C@H](B(Cl)[C@@H]2C[C@@H]3C[C@H]([C@H]2C)C3(C)C)C[C@@H]2C[C@H]1C2(C)C

化学属性

Mol. FormulaC20H34BCl
Mol. Weight320.75
Density0.929
Melting Point52-56 °C(lit.)
Flash Point82 °F
Boiling Point66-69°C
Refractive index-51 ° (C=neat)

别名和识别编码

Chemical Name(-)-DIP-Chloride (-)-B-Chlorodiisopinocampheylborane
Synonym
  • {uni_hamburg}
  • (-)-DIP-CHLORIDE
  • (-)-IPC2BCL
  • (-)-BETA-CHLORODIISOPINOCAMPHEYLBORANE
  • (-)-β-Chlordiisopinocampheylboran
  • (-)-B-DIISOPINOCAMPHEYL-CHLOROBORANE
  • (-)-DIP-CHLORIDE(TM)
  • (-)-B-CHLORODIISOPINOCAMPHEYLBORANE
  • Borane, chlorobis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]-
  • (-)-二异松蒎基氯硼烷
  • (-)-B-Chlorodiisopinocampheylborane
  • (-)-B-CHLORODIISOPINOCAMPHENYLBORANE
  • (-)二异松蒎基氯硼烷
  • (-)-DIP-Chloride™
  • 氯化二异松香芹硼烷
  • Diisopinocampheylchloroborane
  • (+)-二异松蒎基氯硼烷
  • (-)-DIP-CHLORIDE, 50-65 WT% IN HEPTANE
  • (-)-Diisopinocampheyl chloroborane
  • (-)-DIP-CHLORIDE, 60-75 WT% IN HEXANES
  • (-)-SS-CHLORODIISOPINOCAMPHEYLBORANE
  • (-)-dip-chloride tm solution
  • C20H34BCl
  • (-)-B-chlorodiisopinocampheylborane
  • (-)-b-chlorodiisopinocampherylborane
  • (-)-Diisopinocampheylchloroborane, in heptanes, 2M solution
  • (-)-DIP-Chloride
  • (-)-diisopinocampheylchloroborane,(-)-dpc,inheptanes
  • (-)-Diisopinocampheylchloroborane, in hexanes, 2M solution
  • (-)-DIP CHLORIDE, 65-75 WT% IN ALPHA-PI&
  • (-)-DIP-Cl
  • (-)-Dip-chloride
  • (-)-DIP-Chloride™ 溶液
  • (-)-Chlorodiisopinocampheylborane
  • (-)-diisopinocampheylchloroborane,(-)-dpc,inhexanes
  • (-)-B-二异松蒎基氯硼烷 (-)-Ipc2BCl
  • (-)-Diisopinocampheylboron chloride
  • Borane, chlorobis(2,6,6-trimethylbicyclo[3.1.1]hept-3-yl)-, [1R-[1α,2β,3α(1R*,2S*,3R*,5R*),5α]]-
    MDL NumberMFCD00074807
    PubChem Substance ID11131038
    Beilstein Registry Number5937756
    CAS Number85116-37-6
    EC Number250-023-7
    Reaxys-RN5937756
    Chemical Name Translation(-)-二异松蒎基氯硼烷
    InChIInChI=1S/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12-,13+,14+,15-,16-,17-,18-/m1/s1

    系列性分类


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