(-)-DIP-Chloride™ solution (-)-B-氯化二异松香芹硼烷

CAS 85116-37-6 MFCD00074807

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI 377604
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.7 M solution in heptane, SpcSeal 25mL 140
LN-CN
中国国内现货 1.7 M solution 庚烷
INFI 377604
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.7 M solution in heptane, SpcSeal 100mL 380
BY-CN LN-CN
中国国内现货 1.7 M solution 庚烷
INFI 377604
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.7 M solution in heptane, SpcSeal 500mL 1,150
BY-CN
中国国内现货 1.7 M solution 庚烷
INFI 540235
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.8 M solution in hexanes, SpcSeal 25mL 230
1.8 M solution 己烷
INFI 540235
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.8 M solution in hexanes, SpcSeal 100mL 490
1.8 M solution 己烷
INFI 540235
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.8 M solution in hexanes, SpcSeal 500mL 1,240
1.8 M solution 己烷
Innochem 572919
200mL 850
0
TCI 293363
(-)- B -Chlorodiisopinocampheylborane (55-65% in Heptane, ca . 1.7mol/L) >
100mL 935
SH-CN TK-JP
中国国内现货 0
TCI 296700
(-)- B -Chlorodiisopinocampheylborane (60% in Hexane, ca . 1.7mol/L) >
100mL 940
SH-CN TK-JP
中国国内现货 0
J&K 379542
(-)-B-Chlorodiisopinocampheylborane, 60 wt.% solution in heptane, ca.1.7 M, J&KSeal;
N/A 25g 304
HB
中国国内现货 0
J&K 379542
(-)-B-Chlorodiisopinocampheylborane, 60 wt.% solution in heptane, ca.1.7 M, J&KSeal;
N/A 100g 1,001
HB
中国国内现货 0
Aldrich 275530
(?)-DIP-Chloride
- 5g 366
0
Aldrich 275530
(?)-DIP-Chloride
- 25g 954
0
Aldrich 275530
(?)-DIP-Chloride
- 100g 2,698
0
Aldrich 290753
(?)-DIP-Chloride? solution
65-75?wt. 25mL 1,534
0
Aldrich 290753
(?)-DIP-Chloride? solution
65-75?wt. 100mL 4,583
0
Aldrich 324156
(-)-DIP-Chloride™ solution (-)-DIP-Chloride™ 溶液
50-65 wt. % in hexanes 50-65?wt. % in hexanes 25mL 1,646
0
Aldrich 324156
(-)-DIP-Chloride™ solution (-)-DIP-Chloride™ 溶液
50-65 wt. % in hexanes 50-65?wt. % in hexanes 100mL 4,726
0
Energy-chemical 400508
(-)-Diisopinocampheyl chloroborane (-)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L 25mL 108
CN-BJ CN-SH
中国国内现货 60
Energy-chemical 400508
(-)-Diisopinocampheyl chloroborane (-)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L 100mL 295
CN-BJ CN-SH
中国国内现货 60
Energy-chemical 400508
(-)-Diisopinocampheyl chloroborane (-)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L 500mL 975
CN-BJ CN-SH
中国国内现货 60
Aladdin 400509
(-)-B-Chlorodiisopinocampheylborane (-)二异松蒎基氯硼烷
60%正庚烷溶液, ca. 1.7mol/L 25mL 202
CN-SH
中国国内现货 0
Aladdin 400509
(-)-B-Chlorodiisopinocampheylborane (-)二异松蒎基氯硼烷
60%正庚烷溶液, ca. 1.7mol/L 100mL 361
CN-SH
中国国内现货 0
Aladdin 400509
(-)-B-Chlorodiisopinocampheylborane (-)二异松蒎基氯硼烷
60%正庚烷溶液, ca. 1.7mol/L 500mL 924
0
Aladdin 400510
(-)-B-Chlorodiisopinocampheylborane (-)二异松蒎基氯硼烷
60%正己烷溶液, ca. 1.7mol/L 25mL 108
CN-SH
中国国内现货 0
Aladdin 400510
(-)-B-Chlorodiisopinocampheylborane (-)二异松蒎基氯硼烷
60%正己烷溶液, ca. 1.7mol/L 100mL 295
CN-SH
中国国内现货 0
Adamas 404688
60% in Heptane, ca. 1.7Mol/L 100mL 461
SH-CN
中国国内现货 60
Adamas 487549
60% in Heptane, ca. 1.7Mol/L 500mL 1,250
60
TRC 513507
(-)-DIP-chloride (~60% in Heptane)
5g 1,100
0
TRC 513507
(-)-DIP-chloride (~60% in Heptane)
25g 1,500
0
TRC 513507
(-)-DIP-chloride (~60% in Heptane)
100g 4,750
0
TRC 544208
(-)-DIP-chloride (~60% in Heptan…
5g 1,320
0
TRC 544208
(-)-DIP-chloride (~60% in Heptan…
25g 1,800
0
TRC 544208
(-)-DIP-chloride (~60% in Heptan…
100g 5,700
0
Energy-chemical 553447
(-)-Diisopinocampheyl chloroborane (-)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L,Energyseal 100mL 362
CN-BJ CN-SH
中国国内现货 60
Energy-chemical 553447
(-)-Diisopinocampheyl chloroborane (-)-二异松蒎基氯硼烷
60% in Heptane, ca. 1.7mol/L,Energyseal 500mL 1,170
CN-BJ CN-SH
中国国内现货 60
Meryer 558872
(-)二异松蒎基氯硼烷
60%正己烷溶液, ca. 1.7mol/L 25mL 566
60
Meryer 558872
(-)二异松蒎基氯硼烷
60%正己烷溶液, ca. 1.7mol/L 100mL 893
60
Adamas 591260
60% hexane solution 100mL 395
SH-CN
中国国内现货 60+ %
3A 648479
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.7 M solution in heptane, SpcSeal 25mL 140
1.7 M solution Heptane
3A 648479
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.7 M solution in heptane, SpcSeal 100mL 380
1.7 M solution Heptane
3A 648479
(-)-B-Chlorodiisopinocampheylborane (-)-B-氯化二异松香芹硼烷
1.7 M solution in heptane, SpcSeal 500mL 1,150
1.7 M solution Heptane
Aladdin 672876
100mL 361
Aladdin 672877
25mL 289
Aladdin 672878
25mL 289
SH-CN
中国国内现货
Aladdin 672879
100mL 799

分类

  • {uni_hamburg} no charge; carbocycle; alicycle; fused rings; 4ring; 6ring; chiral; 1fragment
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Reduction

相关文献及参考

  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.

安全信息

WGK Germany3
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 如果食入:立即呼叫中毒控制中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261305+351+338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P308+313 IF exposed or concerned: Get medical advice/attention. 如接触到或有疑虑:求医/就诊。
  • P403+233 Store in a well-ventilated place. Keep container tightly closed. 存放在通风良好的地方。保持容器密闭。
  • P305+351+338+310
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P301+330+331+310
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+378 In case of fire: Use … for extinction. 如果发生火灾:使用...灭火。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Signal word
GHS Symbol
Personal Protective Equipment
  • Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
  • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
  • C
  • 3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R10 Flammable 易燃
  • R37 Irritating to respiratory system 刺激呼吸道
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
  • R50/53
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
Packing GroupII
Storage condition
  • 0-10
  • 0-10°C
  • 密封2-8°C保存
  • 2-8°C
UN Number
  • UN 3261 8/PG 2
  • 2924
Hazard Class3/8

其他信息

  • MOL 文件:85116-37-6.mol
  • F:10-21
  • Sigma Aldrich:85116-37-6(sigmaaldrich)
  • (-)-二异松蒎基氯硼烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1615 (-)-B-二异松蒎基氯硼烷(60%的己烷溶液,约1.7mol/L) (-)-B-Chlorodiisopinocampheylborane (60% in Hexane, ca. 1.7mol/L) 100ML 2570元 2014/06/02 C2023 (-)-B-二异松蒎基氯硼烷(60%的庚烷溶液,约1.7mol/L) (-)-B-Chlorodiisopinocampheylborane (60% in Heptane, ca. 1.7mol/L) 100ML 989元
  • 和水反应
  • TCI Shanghai:(-)-二异松蒎基氯硼烷(60%的正己烷溶液,约1.7mol/L) (-)-B-Chlorodiisopinocampheylborane (60% in Hexane, ca. 1.7mol/L)(85116-37-6)

化学结构图

CAS 85116-37-6  MFCD00074807
SMILES: CC1(C)[C@@H]2C[C@H]1C[C@@H](B(Cl)[C@@H]1C[C@@H]3C[C@H]([C@H]1C)C3(C)C)[C@@H]2C |&1:3,5,7,10,12,14,15,20|

化学属性

Mol. FormulaC20H34BCl
Mol. Weight320.75
Density0.89
Melting Point52-56 °C(lit.)
Flash Point82 °F
Boiling Point66-69°C
Refractive index-51 ° (C=neat)

别名和识别编码

Chemical Name(-)-B-Chlorodiisopinocampheylborane
Synonym
  • {uni_hamburg}
  • (-)-DIP-CHLORIDE
  • (-)-IPC2BCL
  • (-)-BETA-CHLORODIISOPINOCAMPHEYLBORANE
  • (-)-β-Chlordiisopinocampheylboran
  • (-)-B-DIISOPINOCAMPHEYL-CHLOROBORANE
  • (-)-DIP-CHLORIDE(TM)
  • (-)-B-CHLORODIISOPINOCAMPHEYLBORANE
  • Borane, chlorobis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]-
  • (-)-二异松蒎基氯硼烷
  • (-)-B-Chlorodiisopinocampheylborane
  • (-)-B-CHLORODIISOPINOCAMPHENYLBORANE
  • (-)二异松蒎基氯硼烷
  • (-)-DIP-Chloride™
  • 氯化二异松香芹硼烷
  • Diisopinocampheylchloroborane
  • (+)-二异松蒎基氯硼烷
  • (-)-DIP-CHLORIDE, 50-65 WT% IN HEPTANE
  • (-)-Diisopinocampheyl chloroborane
  • (-)-DIP-CHLORIDE, 60-75 WT% IN HEXANES
  • (-)-SS-CHLORODIISOPINOCAMPHEYLBORANE
  • (-)-dip-chloride tm solution
  • C20H34BCl
  • (-)-B-chlorodiisopinocampheylborane
  • (-)-b-chlorodiisopinocampherylborane
  • (-)-Diisopinocampheylchloroborane, in heptanes, 2M solution
  • (-)-DIP-Chloride
  • (-)-diisopinocampheylchloroborane,(-)-dpc,inheptanes
  • (-)-Diisopinocampheylchloroborane, in hexanes, 2M solution
  • (-)-DIP CHLORIDE, 65-75 WT% IN ALPHA-PI&
  • (-)-DIP-Cl
  • (-)-Dip-chloride
  • (-)-DIP-Chloride™ 溶液
  • (-)-Chlorodiisopinocampheylborane
  • (-)-diisopinocampheylchloroborane,(-)-dpc,inhexanes
  • (-)-B-二异松蒎基氯硼烷 (-)-Ipc2BCl
  • (-)-Diisopinocampheylboron chloride
  • Borane, chlorobis(2,6,6-trimethylbicyclo[3.1.1]hept-3-yl)-, [1R-[1α,2β,3α(1R*,2S*,3R*,5R*),5α]]-
    MDL NumberMFCD00074807
    PubChem Substance ID 87558100
    Beilstein Registry Number5937756
    CAS Number85116-37-6
    EC Number250-023-7
    Reaxys-RN5937756
    Chemical Name Translation(-)-B-氯化二异松香芹硼烷

    系列性分类


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