2,2,6,6-Tetramethylpiperidinylmagnesium Chloride lithium Chloride 2,2,6,6-四甲基哌啶基氯化镁氯化锂

CAS 898838-07-8 MFCD12546030


SMILES: CC1(C)CCCC(C)(C)N1[Mg]Cl.[Cl-].[Li+]


Mol. FormulaC9H18Cl2LiMgN
Mol. Weight242.4


Chemical Name2,2,6,6-Tetramethylpiperidinylmagnesium Chloride lithium Chloride
MDL NumberMFCD12546030
Synonym TMPMgCl·LiCl 2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物 溶液
Chemical Name Translation2,2,6,6-四甲基哌啶基氯化镁氯化锂
PubChem Substance ID329762048
CAS Number898838-07-8
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  • {SNA} Chemical Synthesis, Grignard Reagents, Heteroaryl, Organometallic Reagents
  • {SNA} 25mL Sure/Seal Reagents, Chemical Synthesis, Grignard Reagents, Heteroaryl, Organometallic Reagents



WGK Germany3
GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P235
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word Danger
Hazard Codes 4.3 F,C
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
UN Number 3399
Packing GroupI
Restrict 危险品