Binap, (+)- 2,2'-双(二苯基膦基)-1,1'-联萘

CAS 98327-87-8 MFCD00010805

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI 377705
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)- 2,2'-双(二苯基膦)-1,1'-联萘
98% 250mg 330
0
INFI 377705
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)- 2,2'-双(二苯基膦)-1,1'-联萘
98% 1g 1,000
0
INFI 377705
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)- 2,2'-双(二苯基膦)-1,1'-联萘
98% 5g 4,010
0
INFI 440760
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 2,2'-双(二苯基膦基)-1,1'-联萘
98% 1g 80
96-99 %
INFI 440760
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 2,2'-双(二苯基膦基)-1,1'-联萘
98% 5g 250
96-99 %
INFI 440760
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 2,2'-双(二苯基膦基)-1,1'-联萘
98% 25g 890
96-99 %
INFI 440760
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 2,2'-双(二苯基膦基)-1,1'-联萘
98% 100g 2,880
96-99 %
INFI 440761
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl R-(+)-1,1'-联萘-2,2'-双二苯膦
98% 1g 180
96-99 %
INFI 440761
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl R-(+)-1,1'-联萘-2,2'-双二苯膦
98% 5g 570
96-99 %
INFI 440761
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl R-(+)-1,1'-联萘-2,2'-双二苯膦
98% 25g 1,980
96-99 %
INFI 450906
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene (R)-(+)-2,2'-双(二苯膦基)-1,1'-联萘
97% 5g 950
96-99 %
INFI 450906
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene (R)-(+)-2,2'-双(二苯膦基)-1,1'-联萘
97% 25g 2,740
96-99 %
INFI 450906
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene (R)-(+)-2,2'-双(二苯膦基)-1,1'-联萘
97% 100g 5,610
96-99 %
INFI 526781
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)-2,2'-双(二苯膦基)-1,1'-联萘
97% 1g 450
96-99 %
INFI 526781
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)-2,2'-双(二苯膦基)-1,1'-联萘
97% 5g 1,390
96-99 %
INFI 526781
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)-2,2'-双(二苯膦基)-1,1'-联萘
97% 25g 4,760
96-99 %
INFI 581768
2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 2,2'-双(二苯基膦基)-1,1'-联萘
98% 250mg 60
96-99 %
INFI 581768
2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 2,2'-双(二苯基膦基)-1,1'-联萘
98% 1g 140
96-99 %
INFI 581768
2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 2,2'-双(二苯基膦基)-1,1'-联萘
98% 5g 450
96-99 %
INFI 581768
2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 2,2'-双(二苯基膦基)-1,1'-联萘
98% 25g 1,480
96-99 %
Innochem 545805
98% 5g 980
99
Innochem 545805
98% 25g 3,626
99
Innochem 545805
98% 100g 10,878
99
Innochem 557102
98% 5g 960
96-99 %
Innochem 557102
98% 25g 3,552
96-99 %
Innochem 557102
98% 100g 10,656
96-99 %
Innochem 669179
1g 208
BJ-CN
中国国内现货
Innochem 669179
5g 330
BJ-CN
中国国内现货
Innochem 669179
10g 535
BJ-CN
中国国内现货
Innochem 669179
25g 2,035
BJ-CN
中国国内现货
Alfa 243411
(±)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%
98% 5g 1,148
SH-CN BJ-CN CN
中国国内现货 99
Alfa 243411
(±)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%
98% 25g 3,836
SH-CN CN
中国国内现货 99
Alfa 243411
(±)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%
98% 100g 7,868
SH-CN CN
中国国内现货 99
TCI 279183
(+/-)-BINAP
97.0%(GC) 5g 1,270
SH-CN TJ-CN TK-JP
中国国内现货 99
TCI 279183
(+/-)-BINAP
97.0%(GC) 25g 3,450
SH-CN TJ-CN TK-JP
中国国内现货 99
J&K 290144
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%
98% 1g 300
HB SH
中国国内现货 99
J&K 290144
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%
98% 5g 1,197
HB
中国国内现货 99
J&K 290144
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%
98% 25g 3,468
HB SH
中国国内现货 99
J&K 290144
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%
98% 100g 7,101
SH
中国国内现货 99
Wylton 528826
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl R-(+)-1,1'-联萘-2,2'-双二苯膦 (R)-(+)-BINAP
0.98 1g 179
CN
中国国内现货 0
Wylton 528826
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl R-(+)-1,1'-联萘-2,2'-双二苯膦 (R)-(+)-BINAP
0.98 5g 348
CN
中国国内现货 0
Wylton 528826
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl R-(+)-1,1'-联萘-2,2'-双二苯膦 (R)-(+)-BINAP
0.98 25g 1,820
CN
中国国内现货 0
Wylton 528827
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl S-(-)-1,1'-联萘-2,2'-双二苯膦 (S)-(-)-BINAP
0.98 1g 108
CN
中国国内现货 0
Wylton 528827
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl S-(-)-1,1'-联萘-2,2'-双二苯膦 (S)-(-)-BINAP
0.98 5g 462
CN
中国国内现货 0
Wylton 528827
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl S-(-)-1,1'-联萘-2,2'-双二苯膦 (S)-(-)-BINAP
0.98 10g 882
CN
中国国内现货 0
Acros 274441
(±)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%
98% 1g 470
SH-CN BJ-CN
中国国内现货 99
Acros 274441
(±)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%
98% 5g 2,125
SH-CN BJ-CN
中国国内现货 99
Acros 274441
(±)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%
98% 25g 4,023
99
Acros 274441
(±)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%
98% 100g 26,174
99
Shao Yuan 385332
2,2’-Bis(diphenylphosphino)-1,1’-binaphthalene (BINAP) 2,2’-双(二苯基膦)-1,1’-联萘 (BINAP)
95+% 1g 116
SH-CN
中国国内现货 99
Shao Yuan 385332
2,2’-Bis(diphenylphosphino)-1,1’-binaphthalene (BINAP) 2,2’-双(二苯基膦)-1,1’-联萘 (BINAP)
95+% 2g 284
SH-CN
中国国内现货 99
Shao Yuan 385332
2,2’-Bis(diphenylphosphino)-1,1’-binaphthalene (BINAP) 2,2’-双(二苯基膦)-1,1’-联萘 (BINAP)
95+% 5g 297
SH-CN
中国国内现货 99
Shao Yuan 385332
2,2’-Bis(diphenylphosphino)-1,1’-binaphthalene (BINAP) 2,2’-双(二苯基膦)-1,1’-联萘 (BINAP)
95+% 10g 581
SH-CN
中国国内现货 99
Shao Yuan 385332
2,2’-Bis(diphenylphosphino)-1,1’-binaphthalene (BINAP) 2,2’-双(二苯基膦)-1,1’-联萘 (BINAP)
95+% 25g 1,097
SH-CN
中国国内现货 99
Shao Yuan 385332
2,2’-Bis(diphenylphosphino)-1,1’-binaphthalene (BINAP) 2,2’-双(二苯基膦)-1,1’-联萘 (BINAP)
95+% 50g -
99
Shao Yuan 385332
2,2’-Bis(diphenylphosphino)-1,1’-binaphthalene (BINAP) 2,2’-双(二苯基膦)-1,1’-联萘 (BINAP)
95+% 100g 3,871
99
Matrix 396252
2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
95+% 5g 433
99
Matrix 396252
2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
95+% 25g 1,275
99
Apollo 396260
2,2'-Bis(diphenylphosphino)-[1,1']-binaphthyl 98%
1g 484
0
Energy-chemical 397731
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 1,1'-联萘-2,2'-双二苯膦
98% 1g 65
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 397731
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 1,1'-联萘-2,2'-双二苯膦
98% 5g 198
CN-BJ CN-SH
中国国内现货 99
Energy-chemical 397731
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 1,1'-联萘-2,2'-双二苯膦
98% 25g 745
CN-BJ
中国国内现货 99
Energy-chemical 397731
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 1,1'-联萘-2,2'-双二苯膦
98% 100g 2,570
CN-BJ CN-SH
中国国内现货 99
Aladdin 397732
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene (±)-2,2'-双-(二苯膦基)-1,1'-联萘
98% 1g 188
CN-SH
中国国内现货 99
Aladdin 397732
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene (±)-2,2'-双-(二苯膦基)-1,1'-联萘
98% 5g 470
CN-SH
中国国内现货 99
Aladdin 397732
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene (±)-2,2'-双-(二苯膦基)-1,1'-联萘
98% 25g 2,297
CN-SH
中国国内现货 99
Aladdin 397732
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene (±)-2,2'-双-(二苯膦基)-1,1'-联萘
98% 100g 5,362
CN-SH
中国国内现货 99
Acros 403004
98% 1g 641
99
Acros 406861
99+% 1g 1,096
99
Adamas 410138
98%+ 1g 200
SH-CN
中国国内现货 99
Adamas 410139
98%+ 5g 500
SH-CN
中国国内现货 99
HY 522853
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)- 2,2'-双(二苯基膦)-1,1'-联萘
98% 250mg -
99
HY 522853
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)- 2,2'-双(二苯基膦)-1,1'-联萘
98% 1g -
99
HY 522853
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)- 2,2'-双(二苯基膦)-1,1'-联萘
98% 5g -
99
HY 523704
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene (R)-(+)-2,2′-双(二苯基膦)-1,1′-联萘
98% 250mg -
99
HY 523704
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene (R)-(+)-2,2′-双(二苯基膦)-1,1′-联萘
98% 1g -
99
HY 523704
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene (R)-(+)-2,2′-双(二苯基膦)-1,1′-联萘
98% 5g -
99
Ark 545798
97% 1g 80
SH-CN
中国国内现货 99
Ark 545798
97% 5g 176
SH-CN
中国国内现货 99
Ark 545798
97% 10g 320
SH-CN
中国国内现货 99
Ark 545798
97% 25g 760
SH-CN
中国国内现货 99
Ark 545798
97% 100g 2,800
SH-CN
中国国内现货 99
Strem 545802
racemic-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98% rac-BINAP
98% 1g 600
0
Strem 545802
racemic-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98% rac-BINAP
98% 5g 1,470
0
Strem 545802
racemic-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98% rac-BINAP
98% 25g 4,425
0
Strem 545802
racemic-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98% rac-BINAP
98% 100g 8,985
0
TRC 545809
2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene
5g 1,540
0
TRC 545809
2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene
25g 6,300
0
TRC 545809
2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene
100g 18,900
0
Matrix 568723
97% 1g 1,001
96-99 %
Matrix 568723
97% 10g 6,630
96-99 %
Matrix 568723
97% 50g 15,145
96-99 %
HY 574332
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene (R)-(+)-2,2′-双(二苯基膦)-1,1′-联萘
97% 250mg -
96-99 %
HY 574332
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene (R)-(+)-2,2′-双(二苯基膦)-1,1′-联萘
97% 1g -
96-99 %
HY 574332
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene (R)-(+)-2,2′-双(二苯基膦)-1,1′-联萘
97% 5g -
96-99 %
Key Organic 574336
2,2'-Bis(diphenylphosphino)-[1,1']-binaphthyl
>95% 1g 416
90+ %
Key Organic 574336
2,2'-Bis(diphenylphosphino)-[1,1']-binaphthyl
>95% 5g 1,871
90+ %
Key Organic 574336
2,2'-Bis(diphenylphosphino)-[1,1']-binaphthyl
>95% 10g 3,326
90+ %
Key Organic 574336
2,2'-Bis(diphenylphosphino)-[1,1']-binaphthyl
>95% 20g 6,237
90+ %
Key Organic 574336
2,2'-Bis(diphenylphosphino)-[1,1']-binaphthyl
>95% 25g 7,484
90+ %
Shao Yuan 590277
95% 1g 750
90+ %
Shao Yuan 590277
95% 5g 2,890
90+ %
3A 635033
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene 2,2′-双(二苯基膦)-1,1′-联萘
98% 1g -
96-99 %
3A 635033
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene 2,2′-双(二苯基膦)-1,1′-联萘
98% 5g -
96-99 %
3A 635033
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene 2,2′-双(二苯基膦)-1,1′-联萘
98% 25g -
96-99 %
Aladdin 669195
100g 5,473
Aladdin 669196
1g 273
Aladdin 669197
25g 2,344
Aladdin 669198
5g 869

分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Phosphine Compounds, Polydentate Phosphine Ligands
  • {SNA} Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Development Quantities for Research, Phosphine Compounds, Polydentate Phosphine Ligands, Related Palladacycles
  • {SNA} Related Palladacycles, Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis,

产品应用

  • 用作非对称反应催化的过渡金属配体。

相关文献及参考

  • The combination with Tris(dibenzyl­ideneacetone)­dipalladium(0)­, 12760, catalyzes the asymmetric arylation of ketone enolates with aryl bromides: J. Am. Chem. Soc., 120, 1918 (1998).
  • For use in the Ru-catalyzed homogeneous enantioselective reduction of ketones to secondary alcohols, see: J. Am. Chem. Soc., 117, 2675, 10417 (1995); Org. Synth., 77, 1 (1999).
  • Lam, K., et al.: Eur. J. Med. Chem., 45, 5527 (2010),
  • {
  • Reviews: BINAP catalysis: Acc. Chem. Res., 23, 345 (1990); binaphthylic derivatives as chiral auxiliaries: Synthesis, 503 (1992); advances in biaryl-type biphosphne ligands: Tetrahedron, 61, 5405 (2005).
  • Chiral chelating ligand which is the basis of a number of homogeneous catalysts which promote hydrogenation reactions with very high enantiomeric excesses. Rh complexes catalyze the asymmetric hydrogenation of ɑ-acylaminoacrylic acids: J. Am. Chem. Soc., 102, 7932 (1980), and the isomerization of allylamines to chiral
  • Ito, H., et al.: Nat. Chem., 2, 972 (2010),
  • See also previous entry.
  • Chiral chelating ligand which is the basis of a number of homogeneous catalysts which promote hydrogenation reactions with very high enantiomeric excesses. Rh complexes catalyze the asymmetric hydrogenation of ɑ-acylaminoacrylic acids: J. Am. Chem. Soc., 102, 7932 (1980), and the isomerization of allylamines to chiral enamines: J. Chem. Soc., Chem. Commun., 600 (1982); Synthesis, 665 (1991). Asymmetric hydrogenation of ß-keto esters is achieved with a Ru based catalyst: J. Org. Chem., 57, 6691 (1992). For preparation of a cycloocta-1,5-diene Rh complex and use in enantioselective hydrogenation reaction, see: Org. Synth. Coll., 8, 183 (1993). For a review of the use of Ru BINAP complexes in asymmetric hydrogenation, see: Acta Chem. Scand., 50, 380 (1996).
  • Merck: 14,1223

安全信息

Warnings
  • IRRITANT
WGK Germany3
Personal Protective Equipment
  • Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition
  • Air Sensitive
Signal word
  • Warning
GHS Symbol
Precautionary statements
  • P261305+351+338
Hazard Codes
  • Xi

其他信息

  • Acros Organics:双二苯基磷酰联萘/BINAP (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 99+%(76189-55-4)
  • 下游产品:3-码啉苯硼酸四甲基二酯 --> 3-吗啉基苯甲醛 --> 3-吗啉苯酚
  • MSDS 信息:2,2'-Bis(diphenylphosp
  • Alfa Aesar:(R)-(+)-2,2'-联(二苯基膦基)-1,1'-联萘,98% (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%(76189-55-4)
  • 1,1'-联萘-2,2'-双二苯膦价格(试剂级):更新日期 产品编号 产品名称 包装 价
  • 上游原料:乙醇 --> 乙酸乙酯 --> 甲醇 --> 二氯甲烷 --> N,N-二甲基甲酰胺 --> 吡啶 --> 三苯基膦 --> 三氟乙酸酐 --> 六水合氯化镍 --> 三乙烯二胺 --> 1,2-双(二苯基膦)乙烷 --> R-1,1'-联-2-萘酚 --> 二苯基膦
  • TCI Shanghai
  • R-(+)-1,1'-联萘-2,2'-双二苯膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B1406 (R)-(+)-2,2'-双(二苯膦)-1,1'-联萘 (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 1G 1370元 2011/04/16 B1406 (R)-(+)-2,2'-双(二苯膦)-1,1'-联萘 (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 5G 4780元 2010/06/21 265530050 R-(+)-1,1'-联萘-2,2'-双二苯膦 (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 99+% 5 GR 4500元
  • This product and its derivatives, rhodium and ruthenium are highly selective homogeneous catalysts used for the reduction of aryl ketones, β-keto esters, and α-amino ketones. They have also been used for asymmetric hydrogenation and hydroformylation of olefins, asymmetric Heck reactions, and asymmetric isomerizations of allyls. Ligand used in a palladium-catalyzed, asymmetric, tandem Heck reaction-carbanion capture process leading to a synthesis of a tricyclic sesquiterpene. Also used in a ruthenium-catalyzed asymmetric hydrogenation of α,β-unsaturated acids.
  • 1,1'-联萘-2,2'-双二苯膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B2383 (+/-)-2,2'-双(二苯基膦)-1
  • MOL 文件:76189-55-4.mol
  • TCI Shanghai:(R)-(+)-1,1'-联萘-2,2'-双苯基膦 (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl,>;98.0%(GC)(76189-
  • Alfa Aesar:(±)-2,2'-双(二苯基膦基)-1,1'-联萘,98% (+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%(98327-87-8)
  • 用途一:用于不对称氢化催化,羰基还原等。
  • 外消旋型

化学结构图

CAS 98327-87-8  MFCD00010805
SMILES: C1=CC=CC2=C(C3C(=CC=C4C=CC=CC4=3)P(C3C=CC=CC=3)C3C=CC=CC=3)C(=CC=C21)P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. Formula[(C6H5)2PC10H6-]2
Mol. Weight622.67
Melting Point283-286 °C(lit.)
TSCANo
Density1.422
Solubilityinsoluble
Refractive index235 ° (C=0.3, Toluene)

别名和识别编码

Chemical Name2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
CAS Number98327-87-8
Alfabeta NameBISDIPHENYLPHOSPHINOBINAPHTHYL 2211()---,,''
MDL NumberMFCD00010805
Synonym
  • R-(+)-1,1'-联萘-2,2'-二苯膦
  • (±)-BINAP (±)-2,2′-双(二苯基膦)-1,1′-联萘 [1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine]
  • (R)-联萘二苯基磷
  • {Chem
  • (R)-(+)
  • (+/-)-BINAP(+/-)-(1,1'-Binaphthalene-2,2'-diyl)bis(diphenylphosphine)
  • 1
  • RAC-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL
  • S-(+)-1,1'-联萘-2,2'-双二苯膦,S-联萘二苯磷
  • {Chemicalbook}
  • 1,1
  • 2,2′-双(二苯基膦)-1,1′-联萘
  • (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL
  • (S)-(-)-2,2′-双(二苯膦基)-1,1′-联萘
  • R-(+)-1,1'-BINAPHTHYL-2,2'-DIPHENYL PHOSPHINE
  • (S)-(-)-BINAP (S)-(-)-1,1′-联萘-2,2'-双二苯膦 (S)-(-)-2,2′-双(二苯膦基)-1,1′-联萘
  • {Chemi
  • (S)-(-)-BINAP (S)-(-)-1,1′-联萘-2,2'-双二苯膦
  • (R)-(
  • R-(+)-1.1'-联萘-2.2'-二苯膦
  • (R)-(+)-2,2BIS(DIPHENYLPHOSPHINO)-1,1-BINAPHTHYL
  • RAC-2,2-BIS(DIPHENYLPHOSPHINO)-1,1-BINAPHTHYL
  • (±)-2,2'-双(二苯基瞵)-1,1‘联萘
  • (+/-
  • (R)-(+)-2,2′-双(二苯膦基)-1,1′-联萘
  • 双二苯基磷酰联萘
  • R-(+)-1,1'-联萘-2,2'-双二苯膦,R-联萘二苯磷
  • S(-)-(1,1'-BINAPHT
  • B
  • R(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENE
  • (R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL
  • (+)-(1R)-[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosph
  • (±)-2,2'-双(二苯基膦基)-1,1'-联萘,98%
  • (R)-(+)-2,2'-双(二苯基膦)-1,1'-联萘
  • (R)-(+)-2,2`-双
  • R(+)-(1,1'-BINAPHTHALENE-2,2'-DIYL)BIS(DIPHENYLPHOSPHINE)
  • -(+)-(1,
  • (R)-(+)-BINAP (R)-(+)-(1,1′-联萘-2,2′-二基)双(二苯膦)
  • RACEMIC-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL
  • 1'-联萘-2
    Beilstein Registry Number5321443
    PubChem Substance ID 24871738
    Reaxys-RN5321443
    Merck Number1223
    EC NumberNone
    Chemical Name Translation2,2'-双(二苯基膦基)-1,1'-联萘
    InChIKeyMUALRAIOVNYAIW-UHFFFAOYSA-N
    LabNetwork Molecule IDLN00154548

    系列性分类


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