(S)-1-[(S)-Tert-Butylphosphinoyl]-2-[(S)-1-(Diphenylphosphino)Ethyl]Ferrocene (S)-1-[(S)-叔丁基膦酰基]-2-[(S)-1-(二苯基膦基)乙基]二茂铁
CAS 1221746-31-1 MFCD321746311
化学结构图
SMILES: CC(C1=CC=CC1=[P+]([O-])C(C)(C)C)P(c1ccccc1)c1ccccc1.[Fe+2].c1cc[cH-]c1
化学属性
| Mol. Formula | C28H32FeOP2 |
|---|---|
| Mol. Weight | 502.35 |
| Appearance | orange pwdr. |
| Stability | store cold |
别名和识别编码
| Synonym | (1S)-1-[(S)-(1,1-Dimethylethyl)phosphinyl]-2-[(1S)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS) (1S)-1-[(S)-(1,1-Dimethylethyl)phosphinyl]-2-[(1S)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS) JoSPOphos SL-J681-2 JoSPOphos SL-J681-2 |
|---|---|
| Chemical Name | (S)-1-[(S)-Tert-Butylphosphinoyl]-2-[(S)-1-(Diphenylphosphino)Ethyl]Ferrocene |
| PubChem Substance ID | 71311013 |
| Chemical Name Translation | (S)-1-[(S)-叔丁基膦酰基]-2-[(S)-1-(二苯基膦基)乙基]二茂铁 |
| MDL Number | MFCD18827473 |
| CAS Number | 1221746-31-1 |
| InChI | InChI=1S/C23H26OP2.C5H5.Fe/c1-18(21-16-11-17-22(21)26(24)23(2,3)4)25(19-12-7-5-8-13-19)20-14-9-6-10-15-20;1-2-4-5-3-1;/h5-18H,1-4H3;1-5H;/q;-1;+2/t18-;;/m0../s1 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, JoSPOphos, Privileged Ligands and Complexes, Solvias Ligands and Complexes
相关文献及参考
- Landert, H., et al., Chiral Mixed Secondary Phosphine-Oxide-Phosphines: High-Performing and Easily Accessible Ligands for Asymmetric Hydrogenation Angew. Chem. Int. Ed. Engl. 49 , 6873-6876, (2010)
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