Phenylmagnesium Bromide 苯基溴化镁
CAS 100-58-3 MFCD00000038
化学结构图
SMILES: Br[Mg]c1ccccc1
化学属性
| TSCA | Yes |
|---|---|
| Flash Point | -11 ºC |
| Solubility | 起反应 |
| Appearance | liq. |
| Stability | air sensitive, moisture sensitive |
| Density | 1.004 |
| Mol. Formula | C6H5BrMg |
| Mol. Weight | 181.31 |
| Danger-Level | - |
| pH | -:- |
| Redox | - |
别名和识别编码
| Chemical Name | Phenylmagnesium Bromide |
|---|---|
| EC Number | 250-023-7 |
| Beilstein Registry Number | 3588849 |
| Reaxys-RN | 606081 |
| PubChem Substance ID | 160871258 |
| Synonym | 苯基溴化镁, 3M IN ETHER, PACKAGED UNDER ARGON IN RESEALABL 苯基溴化镁[浸在乙醚中的] PHENYLMAGNESIUM BROMIDE SOL., ~3 M IN DI ETHYL ETHER phenylmagnesium bromide, 3m in ether, packaged under argon in resealable chemseal Phenylmagnesium bromide, 1M solution in THF 苯基溴化镁; 溴化苯基镁 Phenylmagnesium Bromide (32% in Tetrahydrofuran, ca. 2mol/L) Phenylmagnesium Bromide 3.0 M In Diethyl Ether bromophenylmagnesium Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSealTM bottles Magnesium, bromophenyl- PHENYLMAGNESIUM BROMIDE, 3.0M SOLUTION I N DIETHYL ETHER Phenyl magnesium bromide(in ethyl ether) 溴化苯基镁 phenylmagnesiumbromidesolution PhMgBr solution Phenylmagnesium bromide, 2.8M solution in Diethyl ether PHENYLMAGNESIUM BROMIDE, 1.0-1.2M in TETRAHYDROFURAN PHENYLMAGNESIUM BROMIDE, 1.0M SOLUTION I N TETRAHYDROFURAN 溴化苯鎂 苯基溴化镁 溶液 苯基溴化镁, 3M IN ETHER PHENYLMAGNESIUM BROMIDE SOLUTION, ~1 M I N THF PHENYLMAGNESIUM BROMIDE Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal bottles Phenylmagnesiumbromide,3Minether bromophenyl-magnesiu Phenylmagnesium Bromide 1.0 M In Tetrahydrofuran 苯基溴化镁 |
| Chemical Name Translation | 苯基溴化镁 |
| InChIKey | ANRQGKOBLBYXFM-UHFFFAOYSA-M |
| LabNetwork Molecule ID | LN00222974 |
| InChI | InChI=1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q-1;;+2/p-1 |
| MDL Number | MFCD00000038 |
| CAS Number | 100-58-3 |
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分类
- {SNA} 12 Principles Aligned Products, Aryl, Chemical Synthesis, Greener Alternative Products, Grignard Reagents, Organometallic Reagents, Synthetic Reagents
- {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
产品应用
- 用作芳基格利雅试剂。
- 相关化学反应 (1)苯基溴化镁与三氯化铁反应，得到偶联产物.环戊二烯基溴化镁与三氯化铁反应得到二茂铁。
- (2)与三氯化铬在乙醚中反应生成二苯铬。
- (3)六苯基二铅用作聚苯醚润滑剂的抗氧剂，可由氯化铅与苯基锂或苯基溴化镁反应而得。
- (4)以四氢呋喃为溶剂，将溴化苯基镁和氯化锗反应而得四苯基锗烷。
- (5)由氯化铅与苯基溴化镁（或苯基锂）在碘代苯存在下经低温反应而得四苯基铅。
- (6)四苯硼钠主要用于钾离子、铵离子、铷离子和铯离子的测定，可由苯基溴化镁与三氟化硼/乙醚作用先生成溴化四苯硼镁。
安全信息
GHS Symbol
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S8 Keep container dry 保持容器干燥；
- R11 Highly flammable 非常易燃
- R14 Reacts violently with water 遇水会猛烈反应
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R22 Harmful if swallowed 吞咽有害
- R34 Causes burns 会导致灼伤
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P231+P232
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P308+P311
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P403+P233
- P405 Store locked up. 上锁保管。
- P422 Store contents under… 存储目录在…之下。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
- H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
- H302 Harmful if swallowed 吞食有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H351 Suspected of causing cancer 怀疑致癌
其他信息
- 避免与氧化剂、酸、光、水接触。 储存于阴凉、通风的库房。远离火种、热源、水源、防静电。应与氧化剂、酸性物质分开存放，切忌混储。密封保存。储存在暗处。采用防爆型 照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备和合适的收容材料。
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