Hexabromobenzene 六溴苯

CAS 87-82-1 MFCD00000058

化学结构图

87-82-1
SMILES: Brc1c(Br)c(Br)c(Br)c(Br)c1Br

化学属性

Mol. FormulaC6Br6
Mol. Weight551.49
Density2.956
Melting Point>300 °C
TSCAYes
Flash Point-18 °C
Appearance 白色针状结晶。熔点322-324℃，溶于苯，微溶于乙醇、乙醚，不溶于水。
Boiling Point405.75 °C at 760 mmHg

别名和识别编码

Chemical NameHexabromobenzene
CAS Number87-82-1
EC Number201-773-9
Beilstein Registry Number1912586
MDL NumberMFCD00000058
Reaxys-RN1912586
PubChem Substance ID87570777
Synonym Hexabromobenzene {LY} Hexabromobenzene {} {LY} Hexabromobenzene {} {} {LY} Hexabromobenzene {} {} {} {LY} Hexabromobenzene {} {} {} {} {LY} Hexabromobenzene {} {} {} {} {} {LY} Hexabromobenzene {} {} {} {} {} {} {LY} Hexabromobenzene {} {} {} {} {} {} {} {LY} Hexabromobenzene {} {} {} {} {} {} {} {} {LY} Hexabromobenzene {} {} {} {} {} {} {} {} {} {LY} Hexabromobenzene {} {} {} {} {} {} {} {} {} {} {LY} Hexabromobenzene {} {} {} {} {} {} {} {} {} {} {} {LY} Hexabromobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Hexabromobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Hexabromobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Hexabromobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Hexabromobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation六溴苯
LabNetwork Molecule IDLN00223081
InChIInChI=1S/C6Br6/c7-1-2(8)4(10)6(12)5(11)3(1)9
Canonical SMILESC1(=C(C(=C(C(=C1Br)Br)Br)Br)Br)Br
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分类

  • {SNA} Aryl, Building Blocks, C6, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Envi

产品应用

  • 六溴苯为添加型阻燃剂，适用于聚乙烯、聚丙烯、聚苯乙烯、ABC树脂、环氧树脂、聚酰胺、聚酯等。与三氧化二锑以（2-3）：1并用，有协同效应。六溴苯耐火焰效果好，对树脂物性影响小。该品耐热性好，对南非要高温成型的塑料也能有效地使用。与树脂的相；容性好，熔点高，成型品外观光滑。该品还有可用作填料。

相关文献及参考

  • Short: II/25D
  • Short: III/20b
  • Beilstein:5(4)687

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R50/53
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
Hazard Codes Xn Xn,N,F
RTECSDA2200100
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition 2-8°C {LY} 2-8°C APPROX 4°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
UN Number UN 3077 9/PG 3

其他信息

  • 上游原料:铁粉 --> 铝
  • 溶于苯，微溶于乙醇、乙醚，不溶于水
  • Sigma Aldrich:87-82-1(sigmaaldrich)
  • 用途二:六溴苯为添加型阻燃剂，适用于聚乙烯、聚丙烯、聚苯乙烯、ABC树脂、环氧树脂、聚酰胺、聚酯等。与三氧化二锑以（2-3）：1并用，有协同效应。六溴苯耐火焰效果好，对树脂物性影响小。该品耐热性好，对南非要高温成型的塑料也能有效地使用。与树脂的相；容性好，熔点高，成型品外观光滑。该品还有可用作填料。
  • MOL 文件:87-82-1.mol
  • Acros Organics:六溴苯 Hexabromobenzene, 98%(87-82-1)
  • 方法一:由苯与过量的溴反应而得。将苯滴加入铁粉或铝粉作催化剂。苯滴加完后继续回流反应至不再逸出溴化氢。将溴蒸出，加入少量水，搅拌下用碱中和未反应的溴。过滤、洗涤、干燥，即得六溴苯。
  • 图谱信息:六溴苯(87-82-1)Raman光谱 六溴苯(87-82-1)红外图谱(IR1) 六溴苯(87-82-1)质谱(MS) 六溴苯(87-82-1)红外图谱(IR2)
  • Alfa Aesar:六溴苯,97% Hexabromobenzene, 97%(87-82-1)
  • TCI Shanghai:六溴苯 Hexabromobenzene,>;99.0%(GC)(87-82-1)
  • 六溴苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0363 六溴苯 Hexabromobenzene 500G 1150元 2014/06/02 H0363 六溴苯 Hexabromobenzene 25G 209元 2010/06/21 148060250 六溴苯 Hexabromobenzene 98% 25 GR 532元
  • 用途一:用作化学试剂

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C6 - Aryl
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. H-M - Alpha sort
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Bromo 溴化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. H - Alphabetic
  5. HA -HT - H

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