Propionyl Bromide 丙酰溴
CAS 598-22-1 MFCD00000116
化学结构图
SMILES: CCC(=O)Br
化学属性
| Mol. Formula | C3H5BrO |
|---|---|
| Mol. Weight | 136.98 |
| Density | 1.521 g/mL at 25 °C(lit.) |
| Refractive index | 1.4540 to 1.4580 |
| Boiling Point | 104°C |
| Flash Point | 52°C(lit.) |
| Solubility | 溶于乙醚。 |
| Stability | 对光和湿度敏感 |
别名和识别编码
| Chemical Name | Propionyl Bromide |
|---|---|
| Synonym | Propionic acid bromide Propanoyl bromide Propionyl bromide PROPIONYL BROMIDE 丙酰溴;溴丙酰;溴化丙酰 溴(化)丙酰 溴丙酰 溴化丙酰 Propanoic acid bromide 丙醯溴 丙酰溴 Propionylbromid 丙酰溴 PROPIONYL BROMIDE 1-Bromo-1-propanone |
| MDL Number | MFCD00000116 |
| CAS Number | 598-22-1 |
| Beilstein Registry Number | 2(4)724 |
| EC Number | 209-924-0 |
| PubChem Substance ID | 87574698 |
| Reaxys-RN | 1736651 |
| Chemical Name Translation | 丙酰溴 |
| InChIKey | RIBFXMJCUYXJDZ-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01306964 |
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分类
- {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
- {uni_hamburg} no charge; carbonyl bromide; 1fragment
相关文献及参考
- Short: II/25C
- Beilstein:2(4)724
- Short: III/35E
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+
- P304+P340
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- P303+P361+P353
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P370+P378
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
- R14 Reacts violently with water 遇水会猛烈反应
- R10 Flammable 易燃
其他信息
- 外观性质:无色或浅黄色液体。
- Sigma Aldrich:598-22-1(sigmaaldrich)
- Acros Organics:Propionyl bromide, 95%(598-22-1)
- 用途一:用作医药中间体，用于有机合成
- 方法一:将无水丙酸在红磷的存在下与溴反应而得。
- 下游产品:萘丙胺 --> 硫普罗宁 --> 丙胺卡因
- 和水剧烈反应。
- 丙酰溴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0515 丙酰溴 Propionyl Bromide 25G 789元 2010/06/21 392360250 丙酰溴 Propionyl bromide 95% 25 GR 1095元 2010/06/21 392361000 丙酰溴 Propionyl bromide 95% 100 GR 3577元
- MSDS 信息:丙酰溴(598-22-1).msds
- 上游原料:红磷
- MOL 文件:598-22-1.mol
- TCI Shanghai:丙酰溴 Propionyl Bromide,>;98.0%(T)(598-22-1)
- 图谱信息:丙酰溴(598-22-1)质谱(MS) 丙酰溴(598-22-1)核磁图( 13 CNMR) 丙酰溴(598-22-1)核磁图( 1 HNMR) 丙酰溴(598-22-1)红外图谱(IR1)
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