2-Bromo-1-Phenyl-1-Propanone 2-溴苯丙酮(一类易制毒，不能销售)

CAS 2114-00-3 MFCD00000145

化学结构图

2114-00-3
SMILES: CC(Br)C(=O)c1ccccc1

化学属性

Mol. FormulaC6H5COCHBrCH3
Mol. Weight213.07
Density1.4 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.571(lit.)
Flash Point>110°(230°F)
TSCAYes
Boiling Point245-250 °C(lit.)
Solubility不溶
Stability对光敏感
Appearance 淡绿色液体。密度1.350-1.450。

别名和识别编码

Chemical Name2-Bromo-1-Phenyl-1-Propanone
CAS Number2114-00-3
Alfabeta NameBROMOPROPIOPHENONE 2-
MDL NumberMFCD00000145
Synonym Α-溴代苯丙酮 2-BROMOPROPIOPHENONE 2-Bromopropiophenone, 90-95% 2-Bromo-1-phenyl-1-propanone alpha-Methylphenacyl bromide tl336 2-BROMOPROPIOPHENONE, TECH., 90% 2-溴苯丙酮 A-BROMOPROPIOPHENONE α-溴苯丙酮 α-Bromopropiophenone 2-Brom-1-phenyl-1-propanon 2-溴代苯丙酮 BROMPROPIOPHENONE B-Bromopropiophenone α-Methylphenacyl bromide α-溴代苯丙酮 2-bromo-1-phenyl-propan-1-one 1-Bromoethyl phenyl ketone 2-Brompropiophenon 2-BROMO-1-PHENYL-1-PROPANONE LABOTEST-BB LT02085025 (±)-2-bromo-1-phenyl-1-propanone Propiophenone, 2-bromo- 2-Brom-propiophenon 1-Benzoyl-1-bromoethane 1-Propanone, 2-bromo-1-phenyl- alpha-Bromoethyl phenyl ketone 2-溴苯基丙酮 1-Bromoethyl Phenyl Ketone TL 336 dl-α-Bromopropiophenone ALPHA-BROMOPROPIOPHENONE dl-?-Bromopropiophenone Α-溴苯丙酮 2-Bromopropiophenone NSC 89689 -Bromopropiophenone α-Bromoethyl phenyl ketone alpha-Bromopropiophenone 2-bromo-propiophenon 2-bromo-1-phenyl-1-propanon A-BROMOPROPIOPHENONE 98%
EC Number218-307-5
Beilstein Registry Number508550
PubChem Substance ID16452
Chemical Name Translation2-溴苯丙酮(一类易制毒，不能销售)
InChIKeyWPDWOCRJBPXJFM-UHFFFAOYSA-N
Wiswesser Line NotationEY1&VR
LabNetwork Molecule IDLN00011284
InChIInChI=1S/C9H9BrO/c1-7(10)9(11)8-5-3-2-4-6-8/h2-7H,1H3
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分类

  • {SNA} Building Blocks, C9, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • Aromatics
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ketone; 1fragment
  • Miscellaneous Reagents

相关文献及参考

  • Short: EINECS
  • Short: III/38B
  • For a review of photoremovable protecting groups in organic synthesis, see: Synthesis, 1 (1980).
  • Reagent for the protection of carboxylic esters as their ɑ-methylphenacyl esters, which can be cleaved photochemically: J. Org. Chem., 38, 3771 (1973).
  • Beilstein:7(4)684

安全信息

Warnings IRRITANT
RTECSUG8400000
Packing GroupII
UN Number UN 2810 6.1/PG 2 UN2927 1693
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R23 Toxic by inhalation 吸入有毒
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard Codes Xn Xi Xi,Xn
Storage condition 密封避光保存 Refrigerator 
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1600 mg/m3/10M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NDRC** National Defense Research Committee, Office of Scientific Research
   and Development, Progress Report.  Volume(issue)/page/year:
   NDCrc-132,AUG1942

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02729

其他信息

  • F:19
  • MSDS 信息:2-Bromopropiophenone(2114-00-3).msds
  • 毒性分级:高毒
  • 下游产品:1,4-二[2-(4-甲基-5-苯基恶唑)]苯 --> 安非他酮
  • Alfa Aesar:2-溴苯丙酮,96% 2-Bromopropiophenone, 96%(2114-00-3)
  • 不溶于水，溶于醇、醚、丙酮和氯仿。
  • 可燃性危险特性:热分解排出有毒溴化物蒸汽
  • 急性毒性:静脉-小鼠LD50:56 毫克/公斤;吸入-小鼠LCL0:1600 毫克/立方米/10分
  • 海关编码:29147090
  • Sigma Aldrich:2114-00-3(sigmaaldrich)
  • 2-溴苯丙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2933 2-溴苯丙酮 2-Bromopropiophenone 25G 455元 2014/06/02 B2933 2-溴苯丙酮 2-Bromopropiophenone 250G 2660元 2010/05/25 A10661 2-溴苯丙酮, 96% 2-Bromopropiophenone, 96% 25g 610元
  • 用途一:用作医药、有机合成中间体
  • 灭火剂:泡沫、干粉、二氧化碳、雾状水
  • MOL 文件:2114-00-3.mol
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • TCI Shanghai:2-溴苯丙酮 2-Bromopropiophenone,>;96.0%(GC)(2114-00-3)
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C9 - Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic Ketones