Isopropyl Bromide 溴化异丙烷

CAS 75-26-3 MFCD00000147

化学结构图

75-26-3
SMILES: CC(C)Br

化学属性

Mol. FormulaC3H7Br
Mol. Weight122.99
Density1.31
Refractive index1.4240 to 1.4270
Boiling Point59
Melting Point-89
Flash Point19.44°C
TSCAYes
Solubility0.3 G/100 ML

别名和识别编码

Chemical NameIsopropyl Bromide
Synonym 2-Bromopropane {LY} 2-Bromopropane 2-Bromopropane, 98+% 2-BromopropaneForSynthesis 2-bromo-propan 2-bromo-propane 2-bromopropane 2-溴丙烷 2-溴丙烷(溴代异丙烷) 2-溴丙烷, 99% 2-溴代丙烷 sec-Propyl bromide C3H7Br (2-bromo-propane) ISOPROPYL BROMIDE ISOPROPYL BROMIDE pure Isopropyl bromide Isopropylbromide PropylBromide~98% iso-Propyl bromide isopropyl bromide propane, 2-bromo- propane,2-bromo- sec-propylbromide {} {LY} 2-Bromopropane {} {} {LY} 2-Bromopropane {} {} {} {LY} 2-Bromopropane {} {} {} {} {LY} 2-Bromopropane {} {} {} {} {} {LY} 2-Bromopropane {} {} {} {} {} {} {LY} 2-Bromopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromopropane {} {} {} {} {}
CAS Number75-26-3
EC Number200-855-1
Beilstein Registry Number741852
MDL NumberMFCD00000147
PubChem Substance ID87563647
Merck Number5210
Chemical Name Translation溴化异丙烷
Reaxys-RN741852
Wiswesser Line NotationEY1&1
LabNetwork Molecule IDLN00196585
InChIInChI=1S/C3H7Br/c1-3(2)4/h3H,1-2H3
Canonical SMILESCC(Br)C
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分类

  • {Chemicalbook} 农药中间体: 除草剂中间体: 酰胺类除草剂
  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment
  • {SNA} A-B,
  • {SNA} A-B, Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, B, BI - BZ, Bromo, Chemical Class, Chromatography, Environmental Standards, Halogenated, Solvents, Standards for Personal Care and Cosmetic Products, Volatiles/ Semivolatiles, neats, prohibited substances (EU-REGULATION No 1223/2009)
  • {SNA} A-B, Alpha Sort, Alphabetical Index of Analytical Standards,

产品应用

  • 用作Grignard试剂和原料，药物和染料的中间体，还用于农药（敌草胺）等的制造。

相关文献及参考

  • Merck: 14,5210 Beilstein:1,108
  • Merck: 14,5210
  • Can be used, (K2CO3 in DMF), to protect phenolic OH groups as their isopropyl ethers, more stable than benzyl ethers to Lewis acids: J. Chem. Soc., Perkin 1, 2593 (1979).
  • Short: II/19b
  • Short: II/19c

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R48/20
  • R60 May impair fertility 可能降低生殖能力
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P305+P351+P338
  • P308+P313
  • P332+P313
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECSTX4111000
Packing GroupII
UN Number 2344
Hazard Codes 3 F,T F;T
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class3
Warnings 危化品目录(2015) 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 36 gm/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 18(4),55,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4837 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 20(12),52,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 18900 mg/kg
SEX/DURATION            : female 14 day(s) pre-mating
                          female 7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - ovaries, fallopian tubes
   Reproductive - Maternal Effects - menstrual cycle changes or disorders
REFERENCE :
   INHEAO Industrial Health.  (National Institute of Industrial Health, 6-21-1
   Nagao, Tama-ku, Kawasaki, 213 Japan)  V.1-    1963- Volume(issue)/page/year:
   35,278,1997

Restrict 危险品

其他信息

  • 下游产品:氰戊菊酯 --> 残杀威 --> 2-二-叔丁膦基-2',4',6'-三异丙基联苯 --> 2-异丙氧基苯硼酸 --> 2,4,6-三异丙基苯磺酰氯 --> α-异丙基对氯苯基乙腈 --> 3-异丙基苯硼酸 --> 1,3,5-三异丙基苯 --> 莎稗磷 --> 杀虫菊酯 --> α-异丙基对氯苯基乙酸 --> 7-异丙氧基异黄酮 --> 氯唑磷 --> 3-甲基-2-(3,4-二甲氧基苯基)丁腈 --> 2-异丙氧基苯酚 --> 2-溴代异戊酸 --> 异丙基联苯膦,99% --> 维拉帕米 --> 灭锈胺 --> 4-异丙氧苯甲酸 --> 2,4-二氯-5-异丙氧基硝基苯 --> 异丙氧基乙醇 --> 3-甲基-2-丁醇
  • 能与醇、醚、苯、氯仿混溶，微溶于水。
  • Alfa Aesar:2-溴丙烷,99% 2-Bromopropane, 99%(75-26-3)
  • 毒性分级:中毒
  • MSDS 信息:溴化异丙烷(75-26-3).msds
  • 用途五:用作Grignard试剂和原料，药物和染料的中间体，还用于农药（敌草胺）等的制造。
  • 用途一:用于有机合成、医药、农药中间体
  • 储运特性:库房通风低温干燥; 与氧化剂分开存放
  • Acros Organics:2-溴丙烷 2-Bromopropane, 99%(75-26-3)
  • 上游原料:碳酸钠 --> 异丙醇 --> 氢溴酸 --> 浓硫酸
  • 方法一:其制备方法是由异丙醇与氢溴酸反应而得。反应方程式见：(CH 3 ) 2 CHOH+HBr[H 2 SO 4 ]→(CH 3 ) 2 CHBr+H 2 O 将异丙醇在冷却下慢慢加入浓硫酸中，控制温度在30℃以下，加完后再加入氢溴酸，慢慢加热回流4 h，然后蒸馏至出现油珠为止，将所得粗品，分别以浓硫酸、水和5％碳酸钠洗涤，再用无水碳酸钠干燥、过滤、分馏，收集58.5～60.5℃馏分，即为成品。
  • 灭火剂:泡沫、二氧化碳、砂土、干粉
  • 用途四:2-溴丙烷是杀虫剂氰戊菊酯、氟氰戊菊酯、残杀威，杀菌剂灭锈胺、氟酰胺及除草剂毒草胺、莎稗磷的中间体。
  • 可燃性危险特性:可燃; 高热分解有毒溴化物气体
  • 类别:易燃液体
  • 用途三:用于有机合成及医药、农药中间体
  • MOL 文件:75-26-3.mol
  • Sigma Aldrich:75-26-3(sigmaaldrich)
  • 用途二:用于有机合成及制药工业
  • 2-溴丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80110226 溴代异丙烷 100ml 48元 2011/04/16 B0639 2-溴丙烷 2-Bromopropane 500G 313元 2011/04/16 B0639 2-溴丙烷 2-Bromopropane 25G 117元
  • 图谱信息:2-溴丙烷(75-26-3)Raman光谱 2-溴丙烷(75-26-3)核磁图( 13 CNMR) 2-溴丙烷(75-26-3)质谱(MS) 2-溴丙烷(75-26-3)红外图谱(IR1) 2-溴丙烷(75-26-3)核磁图( 1 HNMR)
  • 海关编码:29033036
  • 外观性质:无色液体。
  • 急性毒性:腹腔- 小鼠 LD50: 4837 毫克/ 公斤
  • TCI Shanghai:2-溴丙烷 2-Bromopropane,>;99.0%(GC)(75-26-3)
  • 方法二:由异丙醇与氢溴酸反应而得。将异丙醇在冷却下慢慢加入浓硫酸中，控制温度在30℃以下，加完后再加入氢溴酸，慢慢加热回流4h，然后蒸馏至出现油珠为止，将所得的粗品，分别以浓硫酸、水和5%碳酸钠洗涤，再用无水碳酸钠干燥、过滤、分馏，收集58.5-60.5℃馏分即为成品。另外还有异丙醇-溴化钠法。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkanes 烷烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Bromo 溴化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. B - Alphabetic
  5. BI - BZ - B
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl

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