N-Methyl-N-(trimethylsilyl)trifluoroacetamide N-甲基-N-三甲基硅基三氟乙酰胺

CAS 24589-78-4 MFCD00000411

化学结构图

24589-78-4
SMILES: CN(C(=O)C(F)(F)F)[Si](C)(C)C

化学属性

Mol. FormulaCF3CON(CH3)Si(CH3)3
Mol. Weight199
Boiling Point130-132
TSCAT
Refractive index1.3780 to 1.3820
Density1.075
Flash Point26°C(lit.)
Vapor Density>;1 (vs air)
Vapor Pressure8.8 mmHg ( 27 °C)
pH:A

别名和识别编码

Chemical NameN-Methyl-N-(trimethylsilyl)trifluoroacetamide
CAS Number24589-78-4
Alfabeta NameMETHYLTRIMETHYLSILYLTRIFLUOROACETAMIDE NN---
MDL NumberMFCD00000411
Synonym Acetamide, 2,2,2-trifluoro-N-methyl-N-(trimethylsilyl)- N-Methyl-N-trimethylsilyltrifluoroacetamide trifluoroacetyl(trimethylsilyl)methyl-amine N-Methyl-N-(trimethylsilyl)trifluoracetamid N- N-三甲基硅基-N-甲基三氟乙酰胺 MSTFA N-methyl-N-trimethylsilyltrifluoroacetamide MSTFA N-Trimethylsilyl-N-methyltrifluoroacetamide 2,2,2-Trifluoro-N-methyl-N-(trimethylsilyl)acetamide N-methyl-n-trimethylsilyl-trifluoroacetamide 含 1% 三甲基氯硅烷的 N-甲基-N-(三甲基硅烷基)三氟乙酰胺 Mstfa N-三甲基硅基-N-甲基三氟乙酰胺 MSTFA 2,2,2-Trifluor-N-methyl-N-(trimethylsilyl)-acetam N-Methyl-N-trimethylsilyl-trifluoracetamid N-Methyl-N-(trimethylsilyl)trifluoroacetamide trifluoroacetyl(trimethylsilyl)methylamine
PubChem Substance ID87572684
EC Number246-331-6
Beilstein Registry Number1941550
Reaxys-RN1941550
Chemical Name TranslationN-甲基-N-三甲基硅基三氟乙酰胺
Wiswesser Line NotationFXFFVN1&-SI-1&1&1
InChIKeyMSPCIZMDDUQPGJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00118272
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Applications, Biodiesel, Biodiesel: Testing for Glycerin/Glyceride Contamination,
  • {SNA} Chemical Synthesis, Derivatization Reagents, Derivatization Reagents GC, Protecting and Derivatizing Reagents, Protection and Derivatization, Reagents for Silylation, Silicon-Based, Silylation Reagents, Synthetic Reagents, 分析/色谱, 分析试剂
  • {SNA} β-Glucuronidase Drug Analysis Bundle, Analytical and Industrial Enzymes, Chemical Synthesis, MSTFA - N-Methyl-N-(trimethylsilyl) trifluoroacetamide, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents,

产品应用

  • A new metabolite of Famprofazone in humans.

相关文献及参考

  • Oh, E., et al.: Xenobiotica, 22, 377 (1992),
  • Caldwell, J., et al.: Biochem. J., 129, 11 (1972),
  • Short: III/35F
  • 4. J. Heberle, G. Simchen Silylating Agents, 2nd ed. Buchs , (1995)
  • Powerful silylating agent for a wide range of functional groups: J. Chromat., 115, 591 (1975); 134, 387 (1977); Chromatographia, 9, 440 (1976). See Appendix 4.

安全信息

Warnings MOISTURE SENSITIVE, FLAMMABLE
GHS Symbol
WGK Germany3
Hazard Codes
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSAC9800000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P305+P351+P338+P337+P313
Signal word
UN Number
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S37 Wear suitable gloves 戴适当手套；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Storage condition Moisture Sensitive
Packing GroupIII
Hazard Class3 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Immunological Including Allergic - decreased immune response
REFERENCE :
   StoGD# Personal Communication from G.D. Stoner, Dept. of Community Medicine,
   School of Medicine, Univ. of California, La Jolla, CA 92037, May 25, 1975 
   Volume(issue)/page/year: 27MAY1975

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Silylation - Derivatization Reagents GC
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Enzymes, Inhibitors, and Substrates - Biochemicals and Reagents
  4. Analytical Enzymes - Enzymes, Inhibitors, and Substrates
  5. β-Glucuronidase - Analytical Enzymes
  6. β-Glucuronidase Drug Analysis Bundle - β-Glucuronidase
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Silicon-Based - Protecting and Derivatizing Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Silicon-Based - Protecting and Derivatizing Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. GC Derivatization Reagents, by Application - Derivatization Reagents GC
  6. Biofuels - GC Derivatization Reagents, by Application
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Fluka Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Fluorescent agents, general
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents GC
  4. Reagents for Alkylation & Esterification
  1. Analytical & Chromatography 分析化学与色谱
  2. Gas Chromatography (GC) 气相色谱
  3. Derivatization Reagents
  4. Reagents for Alkylation & Esterification
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents GC
  4. GC Derivatization Reagents, by Application
  5. Amines
  1. Analytical & Chromatography 分析化学与色谱
  2. Gas Chromatography (GC) 气相色谱
  3. Derivatization Reagents
  4. GC Derivatization Reagents, by Application
  5. Amines

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