Diethylaluminum Chloride 氯化二乙基铝

CAS 96-10-6 MFCD00000459

化学结构图

96-10-6
SMILES: CC[AlH3](Cl)CC

化学属性

Boiling Point125-126°C
Vapor Pressure3 mmHg ( 60 °C)
Melting Point-50°C
Flash Point-18°(-1°F)
TSCAYes
Stability对湿度敏感
Solubility溶于二甲苯、汽油。
Density0.867
Mol. Formula(C2H5)2AlCl
Mol. Weight121.00

别名和识别编码

Chemical NameDiethylaluminum Chloride
CAS Number96-10-6
EC Number202-477-2
Beilstein Registry Number4123259
MDL NumberMFCD00000459
Synonym Aluminiumdiethylmonochlorid Aluminum, chlorodiethyl- Chlorodiethylaluminum Chlorodiethylaluminum (also called Diethylaluminum Chloride) DEAC DIETHYLALUMINIUM CHLORIDE DIETHYLALUMINUM CHLORIDE, 25 WT. % (1.8M ) SOLUTION IN TOLUENE Diethylaluminium chloride Diethylaluminum Diethylaluminum chloride Diethylaluminum monochloride Diethylchloroaluminum Diethylchoroaluminum aluminiumdiethylchloride aluminum, chlorodiethyl- chlorodiethyl-al chlorodiethyl-aluminu dichlorotetraethyldi-aluminu diethylaluminummonochloride diethylchloroaluminum {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} 二乙基氯化铝 二乙基氯化铝, 25% W/W IN 庚烷, 95+% 氯代二乙鋁 氯化二乙基铝;二乙基氯化铝
PubChem Substance ID7277
Chemical Name Translation氯化二乙基铝
Merck Number326
LabNetwork Molecule IDLN00164172
InChIInChI=1S/2C2H5.Al.ClH/c2*1-2;;/h2*1H2,2H3;;1H/q;;+1;/p-1
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分类

  • {uni_hamburg} no charge; metal-organic; 1fragment
  • {SNA} 25mL Sure/Seal Reagents, Chemical Synthesis, Organoaluminum, Organometallic Reagents
  • {SNA} Chemical Synthesis, Organoaluminum, Organometallic Reagents

产品应用

  • ⑴.遇空气易自燃，遇水易爆炸。
  • ⑵.用作聚烯烃、丁基橡胶和乙丙橡胶的聚合催化剂。
  • ⑶.合成有机金属化合物和避孕药的中间体。
  • 丙烯聚合反应的助催化剂，低压聚乙烯催化剂；乙丙橡胶、聚异丁烯、芳烃加氢等反应催化剂；火箭，导弹燃料以及镀铝原料。

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: IV/20A Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20A Year: 1999 Keyword: organic compounds; vapor pressure ISBN: 3-540-64735-X ISBN: 978-3-540-64735-5 Internet Resource: DOI:10.1007/b71086 RefComment: VIII, 373 pages.

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R48/20
  • R50/53
  • R51/53
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P370+P378
  • P422 Store contents under… 存储目录在…之下。
Hazard statements
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSBD0558000
Packing GroupI
UN Number 3394
Storage condition 密封保存 Air & Moisture Sensitive 充氩保存 0-6°C
Hazard Codes 4.2 F,C,N
Hazard Class4.3 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 11 gm/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1215,1986

Warnings 危险化学品
Restrict 危险品

其他信息

  • ⑴. 应于干燥氮气下保存。储存于阴凉、干燥、通风良好的库房。远离火种、热源。库温不宜超过30℃。 ⑵. 保持容器密封。应与氧化剂、酸类、碱类、醇类、食用化学品分开存放，切忌混储。不宜大量储存或久存。 ⑶. 用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备和合适的收容材料。 ⑷. 遇空气易发生激烈燃烧，遇水发生剧烈反应。易燃，易爆，不得与空气和水接触。用钢瓶包装，精氮保护。或稀释到20％以下桶装并用氮封保护严防泄漏。用己烷或汽油配成15％～20％溶液较安全。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. M - Alphabetic
  5. META - METH - M
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organoaluminum
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organoaluminum
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organoaluminum
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organoaluminum
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organoaluminum

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