Trimethylchlorogermane 三甲基氯化锗

CAS 1529-47-1 MFCD00000462

化学结构图

1529-47-1
SMILES: C[Ge](C)(C)Cl

化学属性

Mol. Formula(CH3)3GeCl
Mol. Weight153
Refractive index1.4320 to 1.4350
Boiling Point102°C(lit.)
Density1.24 g/mL at 25 °C(lit.)
Melting Point-13 °C(lit.)
Flash Point1°C(lit.)
TSCANo

别名和识别编码

Chemical NameTrimethylchlorogermane
Synonym Trimethylgermanium chloride 三甲基氯锗烷 Germane, chlorotrimethyl- Chlortrimethylgerman Trimethylgermanyl chloride Chlorotrimethylgermane TRIMETHYLCHLOROGERMANE Chlorotrimethylgermanium 三甲基氯化锗 Trimethylgermanium chloride, min. 98% chlorotrimethylgermane TRIMETHYLGERMANIUM CHLORIDE Trimethylgermanium chloride Trimethylchlorogermane Trimethylgermyl chloride (CH3)3GeCl Trimethylchlorogermanium Trimethylchlorogermane, Trimethylgermanium chloride Trimethylgermaniumchloride,min.98% Chlorotrimethylgermanium; Trimethylchlorogermane; Trimethylchlorogermanium; Trimethylgermanyl chloride; Trimethylgermyl chloride CHLOROTRIMETHYLGERMANE
MDL NumberMFCD00000462
CAS Number1529-47-1
PubChem Substance ID87576948
EC Number216-214-4
Beilstein Registry Number3535109
Chemical Name Translation三甲基氯化锗
Reaxys-RN3535109
InChIKeyZZBNZZCHSNOXOH-UHFFFAOYSA-N
LabNetwork Molecule IDLN01746546
InChIInChI=1S/C3H9ClGe/c1-5(2,3)4/h1-3H3
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分类

  • {uni_hamburg} no charge; metal-organic; 1fragment
  • {SNA} Chemical Synthesis, Organogermanium, Organometallic Reagents

相关文献及参考

  • Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
  • Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Lando

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 2924 UN 2924 3/PG 2 UN2924
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
Storage condition Moisture Sensitive Flammables area
Hazard Codes F,C
Hazard Class3/8

其他信息

  • Sigma Aldrich:1529-47-1(sigmaaldrich)
  • Alfa Aesar:三甲基氯化锗 Trimethylgermanium chloride(1529-47-1)
  • TCI Shanghai:三甲基氯化锗 Trimethylchlorogermane,>;98.0%(GC)(1529-47-1)
  • 图谱信息:三甲基氯化锗(1529-47-1)核磁图( 1 HNMR)
  • F:8-10-13-21
  • MOL 文件:1529-47-1.mol
  • TSCA:No
  • 敏感性:Moisture Sensitive
  • 三甲基氯化锗价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1161 三甲基氯化锗 Trimethylchlorogermane 1G 638元 2010/05/25 34129 三甲基氯化锗 Trimethylgermanium chloride 5g 1974元 2010/05/25 34129 三甲基氯化锗 Trimethylgermanium chloride 25g 7840元

系列性分类