Dichloromethylvinylsilane 二氯甲基乙烯基硅烷

CAS 124-70-9 MFCD00000492

化学结构图

124-70-9
SMILES: C[SiH2]C=C(Cl)Cl

化学属性

Mol. FormulaC3H6Cl2Si
Mol. Weight141.07
Refractive index1.4280 to 1.4310
Vapor Density>;1 (vs air)
Boiling Point92 °C at 760 mmHg
Density1.08
Flash Point14°C(lit.)
TSCAYes
Melting Point-78 °C

别名和识别编码

Chemical NameDichloromethylvinylsilane
Synonym Dichloromethylvinylsilane {LY} Dichloromethylvinylsilane {} {LY} Dichloromethylvinylsilane {} {} {LY} Dichloromethylvinylsilane {} {} {} {LY} Dichloromethylvinylsilane {} {} {} {} {LY} Dichloromethylvinylsilane {} {} {} {} {} {LY} Dichloromethylvinylsilane {} {} {} {} {} {} {LY} Dichloromethylvinylsilane {} {} {} {} {} {} {} {LY} Dichloromethylvinylsilane {} {} {} {} {} {} {} {} {LY} Dichloromethylvinylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloromethylvinylsilane {} {} {} {} {} {} {} {} {} {} {LY} Dichloromethylvinylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloromethylvinylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloromethylvinylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloromethylvinylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloromethylvinylsilane {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00000492
CAS Number124-70-9
PubChem Substance ID87567063
EC Number204-710-3
Beilstein Registry Number1740822
Chemical Name Translation二氯甲基乙烯基硅烷
Reaxys-RN1740822
InChIKeyYLJJAVFOBDSYAN-UHFFFAOYSA-N
Wiswesser Line NotationG-SI-G1&1U1
LabNetwork Molecule IDLN00202118
InChIInChI=1S/C3H6Cl2Si/c1-3-6(2,4)5/h3H,1H2,2H3
Canonical SMILESC[Si](Cl)(Cl)C=C
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
  • Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables a

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSVV3533000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 2985 UN 2985 3/PG 2
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Moisture Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro
Hazard Codes 3 F,C
Hazard Class3/8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03620

其他信息

  • MSDS 信息:Dichloromethylvinylsilane(124-70-9).msds
  • Acros Organics:二氯甲基乙烯基硅烷 Dichloromethylvinylsilane, 97%(124-70-9)
  • 海关编码:29310095
  • Sigma Aldrich:124-70-9(sigmaaldrich)
  • Alfa Aesar:二氯甲基乙烯基硅烷,97% Dichloromethylvinylsilane, 97%(124-70-9)
  • 用途一:用作硅橡胶、硅树脂的原料
  • TCI Shanghai:甲基乙烯基二氯硅烷 Dichloromethylvinylsilane,>;97.0%(GC)(124-70-9)
  • 甲基乙烯基二氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0378 甲基乙烯基二氯硅烷 Dichloromethylvinylsilane 25ML 180元 2014/06/02 D0378 甲基乙烯基二氯硅烷 Dichloromethylvinylsilane 500ML 1900元 2010/06/21 147430100 甲基乙烯基二氯硅烷 Dichloromethylvinylsilane 97% 10 GR 310元
  • MOL 文件:124-70-9.mol
  • 图谱信息:甲基乙烯基二氯硅烷(124-70-9)质谱(MS) 甲基乙烯基二氯硅烷(124-70-9)核磁图( 13 CNMR) 甲基乙烯基二氯硅烷(124-70-9)红外图谱(IR1)
  • F:10-21
  • 甲基乙烯基二氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D0378 甲基乙烯基二氯硅烷 Dichloromethylvinylsilane 25ML 218元 2011/04/16 D0378 甲基乙烯基二氯硅烷 Dichloromethylvinylsilane 500ML 1540元 2010/06/21 147430100 甲基乙烯基二氯硅烷 Dichloromethylvinylsilane 97% 10 GR 310元
  • 敏感性:Moisture Sensitive
  • 蒸气密度:>;1 (vs air)
  • TSCA:Yes

系列性分类


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