Allyldimethylchlorosilane 丙烯基氯化二甲基硅烷

CAS 4028-23-3 MFCD00000506

化学结构图

4028-23-3
SMILES: C=CC[Si](C)(C)Cl

化学属性

Mol. FormulaC5H11ClSi
Mol. Weight134.68 g/mol
Refractive index1.4270 to 1.4310
Boiling Point113°C
Density0.891
Flash Point5°C(lit.)
TSCAYes

别名和识别编码

Chemical NameAllyldimethylchlorosilane
Synonym 3-(Dimethylchlorosilyl)-1-propene ADMCS ADMCS 烯丙基二甲基氯硅烷 ADMCS, Allyldimethylchlorosilane ALLYLCHLORODIMETHYLSILANE ALLYLCHLORODIMETHYLSILANE 97% ALLYLDIMETHYLSILYL CHLORIDE ALLYLDIMETHYLSILYLCHLORID Allylchlordimethylsilan Allylchlorodimethylsilane [Allyldimethylsilylating Reagent for GC/MS] {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00000506
CAS Number4028-23-3
PubChem Substance ID77646
EC Number 223-706-2
Beilstein Registry Number4(4)4080
Chemical Name Translation丙烯基氯化二甲基硅烷
Reaxys-RN1737978
InChIKeyKMVZWUQHMJAWSY-UHFFFAOYSA-N
LabNetwork Molecule IDLN01269334
Canonical SMILESC=CC[Si](C)(Cl)C
InChIInChI=1S/C5H11ClSi/c1-4-5-7(2,3)6/h4H,1,5H2,2-3H3
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Short: III/35F
  • Reagent for the derivatization of steroids for GC-MS: J. Chromat., 129, 384 (1976); J. Chromat. Sci., 17, 115 (1979). See Appendix 4.
  • Short: IV/18A

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 2985
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Storage condition Moisture Sensitive 0-10 0-10°C
Hazard Codes F,C 3
Hazard Class3/8

其他信息

  • MOL 文件:4028-23-3.mol
  • TCI Shanghai:烯丙基二甲基氯硅烷[用于气相色谱/质谱的烯丙基二甲硅烷基化剂] Allylchlorodimethylsilane [Allyldimethylsilylating Reagent for GC/MS],>;96.0%(GC)(4028-23-3)
  • 烯丙基二甲基氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1275 烯丙基二甲基氯硅烷[用于气相色谱/质谱的烯丙基二甲硅烷基化剂] Allylchlorodimethylsilane [Allyldimethylsilylating Reagent for GC/MS] 25ML 1540元 2014/06/02 A1275 烯丙基二甲基氯硅烷[用于气相色谱/质谱的烯丙基二甲硅烷基化剂] Allylchlorodimethylsilane [Allyldimethylsilylating Reagent for GC/MS] 10ML 792元 2010/05/25 B22237 丙烯基氯化二甲基硅烷, 97% Allylchlorodimethylsilane, 97% 25g 2226元
  • Sigma Aldrich:4028-23-3(sigmaaldrich)
  • Alfa Aesar:丙烯基氯化二甲基硅烷,97% Allylchlorodimethylsilane, 97%(4028-23-3)
  • 敏感性:Moisture Sensitive
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl - Halogenated Hydrocarbons
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl - Halogenated Hydrocarbons
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. B - Alphabetic
  5. BI - BZ - B
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents

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