1,1,1-Trichloroethane 1,1,1-三氯乙烷
CAS 71-55-6 MFCD00000806
化学结构图
SMILES: CC(Cl)(Cl)Cl
化学属性
| Mol. Formula | C2H3Cl3 |
|---|---|
| Mol. Weight | 133.40 |
| Autoignition Point | 998 °F |
| Refractive index | 1.43838 |
| Vapor Density | 4.6 (vs air) |
| Boiling Point | 74.1°C |
| Vapor Pressure | 100 mmHg ( 20 °C) |
| Density | 1.336 |
| Melting Point | 32.5°C |
| Solubility | 1.4 G/L (20 ºC) |
| Flash Point | 11 °C |
别名和识别编码
| Chemical Name | 1,1,1-Trichloroethane |
|---|---|
| Synonym | 1,1,1-Trichlorethan NCI-C04626 1,1,1-三氯乙烷 Chlorothene NU Chlorothene SM 1,1,1-trichloro-ethan 1,1,1-Trichlorethane alpha-T Chloroform, methyl- Chlorten HCC 140a 1,1,1-Trich α-T {ALD Trichloro-1,1,1-ethane F 140a {Ch 1,1,1-trichloro-ethane alpha-Trichloroethane Chloroethene NU 1,1,1-trichloroethane(tcea) 1,1,1-Trichloraethan Three One S 1,1,1穞richloroethane 偏三氯乙烷 甲基氯仿 'CHLOROTHEN {uni_ham {uni_hambu METHYLCHLOROFORM 1，1，1-三氯 Aerothene TT 1,1,1 Trichloroethane Chlorothene Three One A {C CH3-CCl3 (methylchloroform) Solvent 111 1,1,1-Trichloroethane Ethana NU Inhibisol {uni_ha Methylchloroform; Methyltrichloromet 1'1'1-Trichloroethane {Chemicalb 甲基氯仿 {un 三氯乙 ethane, 1,1,1-trichloro- Chlorothene, inhibited methylchloroform Tafclean 甲基三氯甲烷, {uni_h 1,1,1-trichloroethane(methylchloroform) 偏三氯乙烷 RCRA waste number U226 Methyltrichloromethane 'CHL 1,1,1-Trichloroethane-surfactant α-三氯乙烷 methyltrich R 140a 1,1,1-Trichloorethaan C2H3Cl3 (1,1,1-trichloro-ethane) ICI-CF 2 1,1,1-trichloroethane 1,1,1-TCE Methylchloroform 1,1,1-Trichloräthan |
| MDL Number | MFCD00000806 |
| CAS Number | 71-55-6 |
| PubChem Substance ID | 6278 |
| EC Number | 200-756-3 |
| Beilstein Registry Number | 1731614 |
| Chemical Name Translation | 1,1,1-三氯乙烷 |
| Merck Number | 13,9710 |
| Wiswesser Line Notation | GXGG1 |
| LabNetwork Molecule ID | LN02127156 |
| InChI | InChI=1S/C2H3Cl3/c1-2(3,4)5/h1H3 |
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
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分类
- {uni_hamburg} no charge; 1fragment
- {SA} ReagentPlus, ReagentPlus Solvent Grade Products, ACS and Reagent Grade Solvents, Amber Glass Bottles, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents
- {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Fumigants, Insecticides, Pesticides & Metabolites, Pesticides Standards
产品应用
- 1，1，1一三氯乙烷具有不燃不爆、微毒、溶解能力强、使用方便等特点，主要用作金属零件的脱脂洗净剂；精密仪器清洁剂、金属去油污、杀虫剂;印刷机、纤维的去污剂；有机物的革取剂、气溶胶添加剂；亦可用作耐火焰涂层材料，冷部乳胶液体及作为优良溶剂被广泛采用。
相关文献及参考
- Short: II/14a
- Merck: 14,9636 Beilstein: 1,IV,138
- Merck: 14,9636
- {uni_
- Short: II/19a
安全信息
GHS Symbol
- H332 Harmful if inhaled 吸入有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H420 Harmspublichealthandtheenvironmentbydestroyingozoneintheupperatmospere 通过破坏上层大气臭氧层而危害公众健康和环境。
- P305+P351+P338
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P273 Avoid release to the environment. 避免释放到环境中。
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S59 Refer to manufacturer/supplier for information on recovery/recycling 参考生产厂家/供货商提供的回收/再生利用信息；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R59 Dangerous for the ozone layer 对臭氧层有危害
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R20 Harmful by inhalation 吸入有害
- R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
- R11 Highly flammable 非常易燃
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 3593 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : ENVRAL Environmental Research. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1967- Volume(issue)/page/year: 40,411,1986
{hazard_cTYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 9470 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,353,1958
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhal
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - dog DOSE/DURATION : 750 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C310,1991
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Human DOSE/DURATION : 670 mg/kg TOXIC EFFECTS : Gastrointestinal - hypermotility, diarrhea Gastrointestinal - nausea or vomiting Gastrointestinal - other changes REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB257-185
TYPE OF
TYPE OF TEST : Morphological transformation TEST SYSTEM : Rodent - rat Embryo DOSE/DURATION : 99 umol/L REFERENCE : ITCSAF In Vitro. (Rockville, MD) V.1-20, 1965-85. For publisher information, see ICDBEO. Volume(issue)/page/year: 14,290,1978
TYPE OF TES
TYPE OF TEST : Morphological transformation TEST SYSTEM : Rodent - hamster Kidney DOSE/DURATION : 562 mg/L REFERENCE : PMRSDJ Progress in Mutation Research. (Elsevier Science Pub. Co., Inc., 52 Vanderbilt Ave., New York, NY 10017) V.1- 1981- Volume(issue)/page/year: 1,626,1981
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 10 ug/plate REFERENCE : TECSDY Toxicological and Environmental Chemistry. (Gordon & Breach Science Pub. Inc., 1 Park Ave., New York, NY 10016) V.3(3/4)- 1981- Volume(issue)/page/year: 15,101,1987
TYPE OF TEST : Morphological transformation TEST SYSTEM : Rodent - mouse Embryo DOSE/DURATION : 20 mg/L REFERENCE : CALEDQ Cancer Letters (Shannon, Ireland). (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1975-
TYPE OF TEST : Morphological transformation TEST SYSTEM : Rodent - hamster Embryo DOSE/DURATION : 100 uL/plate REFERENCE : EVSRBT Environmental Science Research. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) V.1- 1972- Volume(issue)/page/year: 25,75,1982
TYPE OF TEST : DNA repair TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 500 mg/L REFERENCE : PMRSDJ Progress in Mutation Research. (Elsevier Science Pub. Co., Inc., 52 Vanderbilt Ave., New York, NY 10017) V.1- 1981- Volume(issue)/page/year: 1,195,1981
TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE : 2100 ppm/6H SEX/DURATION : female 1-20 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) REFERENCE : JTEHD6 Journal of Toxicology and Environmental Health. (Hemisphere Pub., 1025 Vermont Ave., NW, Washington, DC 20005) V.1- 1975/76- Volume(issue)/page/year: 9,251,1982
TYPE OF TEST : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rat
DOSE : 43 mg/kg
SEX/DURATION : female 1-22 day(s) after conception
lactating female 21 day(s) post-birth
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - cardiovascular
(circulatory) system
REFERENCE :
TJADAB Teratology, The International Journal of Abnormal Development. (Alan
R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1968-
Volume(issue)/page/year: 29(2),25A,1984其他信息
- {Chem
- 1,1,1-三氯乙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xp400269 1.1.1-三氯乙烷 5ml 60元 2011/08/23 80133228 1.1.1-三氯乙烷 500ml 41元 2010/06/21 294932500 1,1,1-三氯乙烷 1,1,1-Trichloroethane 93.5%, extra pure, stabilized 250 ML 968元
- 毒性分级:低毒
- 储运特性:库房通风低温干燥; 与食品添加剂分开存放
- 刺激数据:皮肤-兔子20 毫克/24小时 中度; 眼睛-兔子2 毫克/24小时 重度
- 用途二:不燃性溶剂，可作清洗剂，清洗电子零部件，也可作金属脱脂的清洗剂。还可利用本品的低表面张力和高渗透能力的特性，测定金属焊接处的泄漏，也可用作气溶胶烟雾剂、耐火焰涂层材料、切削油冷却剂和制作低毒不燃的粘合剂。偏三氯乙烷的衍生物是有效的杀虫剂，制药工业的中间体。经氯化可制1,1,1,2-四氯乙烷。经脱氯化氢可制偏二氯乙烯。
- 用途四:1，1，1一三氯乙烷具有不燃不爆、微毒、溶解能力强、使用方便等特点，主要用作金属零件的脱脂洗净剂；精密仪器清洁剂、金属去油污、杀虫剂;印刷机、纤维的去污剂；有机物的革取剂、气溶胶添加剂；亦可用作耐火焰涂层材料，冷部乳胶液体及作为优良溶剂被广泛采用。校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。
- 灭火剂:雾状水、泡沫、二氧化碳。
- MOL 文件:71-55-6.mol
- 无色透明液体，有醚的气味。粘度（20℃）0.058mPa·s。不溶于水，水中溶解度：1.4 g/kg，溶于大多数常规有机溶剂。
- 下游产品:马洛替酯 --> 1,1-二氟乙烯(偏氟乙烯)
- 挥发性有机化合物(VOCs)单组分标准液
- Acros Organics:1,1,1-三氯乙烷 1,1,1-Trichloroethane, 90%(71-55-6)
- 蒸气压:100 mm Hg ( 20 °C)
- 外观性质:无色液体。
- 方法一:1.乙烷氯化法由乙烷（或乙烯）氯化制得。2.偏二氯乙烯氢氯化法由偏二氯乙烯与氯化氢经催化加成而得。3.氯乙烯氢氯化法由氯乙烯与氯化氢作用，制得偏二氯乙烯，再经氯化而得。
- 类别:农药
- 图谱信息:1,1,1-三氯乙烷(71-55-6)核磁图( 13 CNMR) 1,1,1-三氯乙烷(71-55-6)红外图谱(IR1) 1,1,1-三氯乙烷(71-55-6)Raman光谱 1,1,1-三氯乙烷(71-55-6)质谱(MS)
- 常规方法:工业品用白铁桶装，有100、200、250kg三种。试剂用500g玻璃瓶装。
- 职业标准:TWA 1900 毫克/立方米STEL 2400 毫克/立方米
- 可燃性危险特性:可燃, 燃烧时分解有毒氯化物气体
- 用途三:1，1，1一三氯乙烷具有不燃不爆、微毒、溶解能力强、使用方便等特点，主要用作金属零件的脱脂洗净剂；精密仪器清洁剂、金属去油污、杀虫剂;印刷机、纤维的去污剂；有机物的革取剂、气溶胶添加剂；亦可用作耐火焰涂层材料，冷部乳胶液体及作为优良溶剂被广泛采用。
- Sigma Aldrich:71-55-6(sigmaaldrich)
- 急性毒性:口服-大鼠 LD50 :9600 毫克/公斤;口服-小鼠 LD50: 6000 毫克/公斤
- 蒸气密度:4.6 (vs air)
- 爆炸物危险特性:与空气混合受热后遇火星会爆炸
- 防护措施:低毒。
- 用途一:主要用作金属清洗剂、纺织品的干洗剂，还可用作粘接剂和金属切削添加剂及DAP树脂的聚合溶剂等
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