1,4-Dichloro-2-butene (cis+trans) 1,4-二氯-2-丁烯

CAS 764-41-0 MFCD00000988

化学结构图

764-41-0
SMILES: ClCC=CCCl

化学属性

Mol. FormulaC4H6Cl2
Mol. Weight124.99
Density1.19
Refractive index1.4860 to 1.4920
Boiling Point159°C(lit.)
Vapor Pressure10 mmHg ( 20 °C)
Melting Point1-3°C
Flash Point54°C(lit.)
Solubility能与苯、乙醇和四氯化碳混溶，不与乙二醇、丙三醇和水混溶。

别名和识别编码

Chemical Name1,4-Dichloro-2-butene (cis+trans)
CAS Number764-41-0
EC Number203-779-7
Beilstein Registry Number1(4)787
MDL NumberMFCD00000988
Synonym 1,4-dichlorobutene (E)-1,4-Dichlor-2-buten 二氯-2-丁烷 1,4-二氯-2-丁烯(顺反混合) 1 4-DICHLORO-2-BUTENE (CIS+TRANS) 1,4-dichloro 2-BUTYLENE DICHLORIDE rcrawastenumberu074 trans-2,3-dichlorobut-2-ene {Chemi 1,4-DICHLORO-2-BUTENE, 95% TECHNICAL 4-二氯-2-丁烯 1,4-DICHLORO-2-BUTYLENE trans-1,4-Dichlorobutene-2 2-Butene,1,4-dichloro-,(2E)- 1,4-Dichloro-trans-2-butene 1,4-Dichloro-2-trans-butene 1,4-dichloro-2-buten Dichlorobutene 1,4-Dichloro-2 butene (I,T) {uni RCRA waste number U074 (E)-1,4-Dichloro-2-butene 1,4-dichloro-but-2-ene 1,4-Dichlorobutene-2 trans-1,4-dichloro-but-2-ene 1,4-Dichloro-2-butene 1,4-dichloro-but-2t-ene 1,4-Dichlor-2-buten 1,4-Dichlorbuten trans 反-1 TRANS-1,4-DICH {uni_h 1,4-DICHLORO-2-BUTENE 2-Butene, 1,4-dichloro- 1,4-Dichloro-trans-2-butene 2-Butene, 1,4-dichloro-, (2E)- trans-1,4-dichloro-2-butene DICHLORO(TRANS-1,4-)-2-BUTENE trans-1,4-dichloro-but-2-ene trans-1,4-Dichlorobuten-2-ene 反-1,4-二氯-2-丁烯 1,4-DICHLORO-2-BUTENE CIS AND TRANS trans-1,4-Dichlor-2-buten (E)-1,4-Dichloro-2-butene; trans-1,4-Dichlorobutene-2 1,4-Dichloro-2-Butene (Mixture Of Cis And Trans) 4-dichloro-trans-2-buten Rcra waste number U074 反式-1,4-二氯-2-丁烯 {Chemic 1,4-Dichloro-(E)-2-butene (2E)-1,4-Dichloro-2-butene 1，4-二氯-2-丁烯
PubChem Substance ID642197
Chemical Name Translation1,4-二氯-2-丁烯
Reaxys-RN1361446
Wiswesser Line NotationG2U2G
InChIKeyFQDIANVAWVHZIR-OWOJBTEDSA-N
InChIInChI=1S/C4H6Cl2/c5-3-1-2-4-6/h1-2H,3-4H2/b2-1+
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Beilstein:1(3)743
  • Short: IV/20A
  • Short: III/38B
  • Short: III/35C1

安全信息

Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R10 Flammable 易燃
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R11 Highly flammable 非常易燃
  • R34 Causes burns 会导致灼伤
  • R26 Very toxic by inhalation 吸入极毒
  • R25 Toxic if swallowed 吞咽有毒
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R45 May cause cancer 可能致癌
  • R50/53
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P304+P340+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P403+P233
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P308+P311
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P241+P242+P243
  • P303+P361+P353+P310+P363
  • P301+P310+P330
  • P301+P310
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H330 Fatal if inhaled 吸入致命
  • H312 Harmful in contact with skin 皮肤接触有害
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSEM4900000
Hazard Codes T+ T+,N T+,T,F
UN Number 3390 3489 UN 3390 6.1/PG 1
Storage condition 0-10 储存温度:2-8℃ 0-10°C 2-8°C 储存温度2-8°C
Packing GroupII
Hazard Class6.1/3, 8
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1 ppm/6H/82W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Sense Organs and Special Senses (Olfaction) - tumors
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History unknown.  Volume(issue)/page/year:
   8EHQ-0985-0567

TYPE OF TEST            : TC - Toxic concentration (other than lowest)
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 100 ppb/6H/82W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Sense Organs and Special Senses (Olfaction) - tumors
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History unknown.  Volume(issue)/page/year:
   8EHQ-0985-0567

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 89 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 4,119,1951

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 920 mg/m3
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 29(4),49,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 620 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 4,119,1951

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 190 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupati

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   41,249,1979

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 2 mmol/L/3D (Intermittent)
REFERENCE :
   35WYAM "In Vitro Metabolic Activation in Mutagenic Testing, Proceedings of
   the Symposium, Research Triangle Park, NC, 1976," De Serres, F.J., et al.,
   eds., New York, Elsevier Science Pub. Co., Inc., 1976
   Volume(issue)/page/year: -,63,1976

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 1700 ug/m3/30D (Intermittent)
REFERENCE :
   ZKMAAX Zhurnal Eksperimental'noi i Klinicheskoi Meditsiny.  Journal of
   Experimental and Clinical Medicine.  (V/O Mezhdunarodnaya Kniga, 113095
   Moscow, USSR)  V.2-    1962-  Volume(issue)/page/year: 25,335,1985

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 750 ug/kg
SEX/DURATION            : male 75 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(7),77,1986

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 5 ppm/6H
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   64,125,1982

其他信息

  • 可燃性危险特性:热分解排出有毒氯化物烟雾
  • 刺激数据:眼睛- 兔子 20 毫克/ 24小时
  • MSDS 信息:(E)-1,4-Dichloro-2-butene(110-57-6).msds
  • 检测方法:GC
  • Sigma Aldrich:110-57-6(sigmaaldrich)
  • 蒸气压:10 mm Hg ( 20 °C)
  • 外
  • 职业标准:STEL 0.1 毫克/ 立方米
  • 1,4-二氯-2-丁烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0352 1,4-二氯-2-丁烯 (顺反异构体混和物) 1,4-Dichloro-2-butene (cis- and trans- mixture) 500G 5720元 2014/06/02 D0352 1,4-二氯-2-丁烯 (顺反异构体混和物) 1,4-Dichloro-2-butene (cis- and trans- mixture) 25G 696元
  • 用途一:反式-1,4-二氯-2-丁烯（110-57-6）用于合成吡咯芬。同时也用于己二腈、丁二醇、六亚甲基二胺、氯丁二烯、四氢呋喃的生产。
  • TCI Shanghai:1,4-二氯-2-丁烯 (顺反异构体混合物
  • {Ch
  • 灭火剂:干粉、干砂、二氧化碳、泡沫
  • TCI Shanghai:反-1,4-二氯-2-丁烯 trans-1,4-Dichloro-2-butene,>;95.0%(GC)(110-57-6)
  • 图谱信息:1,4-二氯-2-丁烯(764-41-0)核磁图( 1 HNMR) 1,4-二氯-2-丁烯(764-41-0)核磁图( 13 CNMR) 1,4-二氯-2-丁烯(764-41-0)质谱(MS) 1,4-二氯-2-丁烯(764-41-0)红外图谱(IR1)
  • {Chemicalb
  • 类别:易燃液体
  • 急性毒性:口服- 大鼠 LD50: 89 毫克/ 公斤; 口服- 小鼠 LD50: 190 毫克/ 公斤
  • MOL 文件:764-41-0.mol
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 高热分解有毒氯化物气体
  • MOL 文件:110-57-6.mol
  • 图谱信息:反式-1,4-二氯-2-丁烯(110-57-6)核磁图( 1 HNMR) 反式-1,4-二氯-2-丁烯(110-57-6)红外图谱(IR1) 反式-1,4-二氯-2-丁烯(110-57-6)核磁图( 13 CNMR) 反式-1,4-二氯-2-丁烯(110-57-6)质谱(MS)
  • F:8-21
  • 类别:有毒物质
  • 反式-1,4-二氯-2-丁烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1624 反-1,4-二氯-2-丁烯 trans-1,4-Dichloro-2-butene 25G 1660元 2014/06/02 D1624 反-1,4-二氯-2-丁烯 trans-1,4-Dichloro-2-butene 5G 563元 2010/06/21 325930050 反式-1,4-二氯-2-丁烯 trans-1,4-Dichloro-2-butene 95% 5 GR 579元
  • MSDS 信息:1,4-二氯-2-丁烯(764-41-0).msds
  • Sigma Aldrich:764-41-0(sigmaaldrich)
  • 上游原料:氧氯化硫 --> 吡啶 --> N-溴代丁二酰亚胺 --> 氯化亚铜 --> 三氯化铁 --> 1-羟基苯并三唑 --> 1,4-丁烯二醇
  • Acros Organics:反式-1，4-二氯-2-丁烯 trans-1,4-Dichloro-2-butene, 95%(110-57-6)
  • 毒性分级:高毒

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl - Halogenated Hydrocarbons
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DIA - DIC - D
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DIA - DIC - D
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Aroclors, PCBs, and Dioxins - Environmental Standards
  6. PCBs - Aroclors, PCBs, and Dioxins

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