1,2,3,4-Tetrahydronaphthalene 1,2,3,4-四氢萘

CAS 119-64-2 MFCD00001733

化学结构图

119-64-2
SMILES: c1ccc2c(c1)CCCC2

化学属性

Refractive index1.5390 to 1.5430
Boiling Point207°C at 760 mmHg
Melting Point-35°C
Flash Point77.22°C
TSCAYes
Autoignition Point723 °F
Vapor Density4.55 (vs air)
Vapor Pressure0.18 mmHg ( 20 °C)
Solubility不溶
Stability对光敏感
Density0.973
Mol. FormulaC10H12
Mol. Weight132.20

别名和识别编码

Chemical Name1,2,3,4-Tetrahydronaphthalene
Synonym 1,2,3,4-Tetrahydronaphthalene {LY} 1,2,3,4-Tetrahydronaphthalene {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {} { {} {} {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {} {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {} {} {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {} {} {} {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {} {} {} {} {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {} {} {} {} {} {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {} {} {} {} {} {} {} {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2,3,4-Tetrahydronaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number119-64-2
EC Number204-340-2
Beilstein Registry Number1446407
MDL NumberMFCD00001733
Reaxys-RN1446407
Merck Number9221
PubChem Substance ID8404
Chemical Name Translation1,2,3,4-四氢萘
Wiswesser Line NotationL66&TJ
LabNetwork Molecule IDLN00164240
InChIInChI=1S/C10H12/c1-2-6-10-8-4-3-7-9(10)5-1/h1-2,5-6H,3-4,7-8H2
Canonical SMILESC12=C(CCCC2)C=CC=C1
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分类

  • {Chemicalbo
  • ACS and Reagent Grade Solvents, Amber Glass Bottles, Carbon Steel Cans with NPT Threads, Reagent, Reagent Grade Solvents, Semi-Bulk Solvents, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents
  • {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chemical Class, Chromatography, Environmental Standards, Hydrocarbons, Naphthalenes, Neats and Solutions, T, T-Z, TA - TE, Volatiles/ Semivolatiles
  • {SNA} Anhydrous Solvents, Solvent Bottles,

产品应用

  • 检验锰。脱脂剂。中间体。萘、油类和树脂的溶剂

相关文献及参考

  • Short: II/27B
  • Short: II/5
  • Merck: 14,9221 Beilstein: 5,IV,1388
  • Merck: 14,9221

安全信息

GHS Symbol
WGK Germany2
Hazard Codes 9
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H227 Combustible liquid 可燃液体
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H351 Suspected of causing cancer 怀疑致癌
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P305+P351+P338
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
RTECSQK3850000
UN Number 3082 UN3082
Risk Statements
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R51/53
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Packing GroupIII
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Class9 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1620 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 1/12/1972

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 275 ppm
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,47,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 17300 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 1/12/1972

其他信息

  • 用途一:用作溶剂及色谱分析试剂
  • 随储存时间而变暗。有似苯和甲醇的混合气味。能随水蒸气挥发。能与乙醇、丁醇、乙醚、丙酮 、苯、氯仿、萘烷和石油醚混溶，溶于甲醇(50.6%w/w),不溶于水。露置空气中能产生四氢萘过氧化物，蒸馏时能与四氢萘作用发生爆炸，可加对苯二酚抗氧剂。低毒，半数致死量(大鼠，经口)2.86g/kg。有刺激性。
  • 毒性分级:中毒
  • 刺激数据:皮肤- 兔子 500 毫克 重度; 眼睛- 兔子 500 毫克/ 24小时 轻度
  • Sigma Aldrich:119-64-2(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 加抗氧化剂如对苯二酚等
  • Acros Organics:1,2,3,4-四氢萘 1,2,3,4-Tetrahydronaphthalene, 98+%(119-64-2)
  • 方法一:其制备方法是用萘为原料，在钼酸镍催化剂存在下，压力2.9 MPa，温度300℃，于绝热反应装置中进行加氢反应，得到的粗品进行精馏得产品。
  • Alfa Aesar:1，2，3，4-四氢化萘,97% 1,2,3,4-Tetrahydronaphthalene, 97%(119-64-2)
  • 类别:易燃液体
  • 灭火剂:干粉、泡沫、砂土、水
  • TCI Shanghai:1,2,3,4-四氢萘 1,2,3,4-Tetrahydronaphthalene,>;98.0%(GC)(119-64-2)
  • 蒸气密度:4.55 (vs air)
  • 蒸气压:0.18 mm Hg ( 20 °C)
  • 可燃性危险特性:易燃; 燃烧产生刺激烟雾
  • 图谱信息:1,2,3,4-四氢萘(119-64-2)红外图谱(IR2) 1,2,3,4-四氢萘(119-64-2)Raman光谱 1,2,3,4-四氢萘(119-64-2)核磁图( 1 HNMR) 1,2,3,4-四氢萘(119-64-2)核磁图( 13 CNMR) 1,2,3,4-四氢萘(119-64-2)质谱(MS) 1,2,3,4-四氢萘(119-64-2)红外图谱(IR1)
  • 1,2,3,4-四氢萘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30175928 四氢萘 500ml 46.7元 2011/04/16 T0107 1,2,3,4-四氢萘 1,2,3,4-Tetrahydronaphthalene 25ML 150元 2011/04/16 T0107 1,2,3,4-四氢萘 1,2,3,4-Tetrahydronaphthalene 500ML 235元
  • MOL 文件:119-64-2.mol
  • 外观性质:无色液体, 具有与萘相似的气味。
  • 用途二:1，2，3，4-四氢化萘是制备甲萘酚的重要中间体，由此可以合成甲萘胺、敌草胺等农药。
  • MSDS 信息:四氢化萘(119-64-2).msds
  • 上游原料:钼酸
  • 下游产品:a-萘酚 --> 萘 --> 丁二酸酐 --> 四氢吡喃酮 --> 1-四氢萘酮 --> 3-吲哚丁酸 --> 11-溴十一酸 --> 氟鼠酮 --> 4-甲基-2,6-二氨基吡啶 --> alpha-四氢萘酚
  • 爆炸物危险特性:与空气混合可爆; 长期与空气接触产生可爆过氧化物
  • 急性毒性:口服- 大鼠 LD50: 1571 毫克/ 公斤
  • 用途三:检验锰。脱脂剂。中间体。萘、油类和树脂的溶剂。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent by Application - Solvents
  4. Anhydrous Solvents - Solvent by Application
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Arenes 芳烃
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent by Application - Solvents
  4. ACS and Reagent Grade Solvents - Solvent by Application
  5. ReagentPlus® Solvent Grade Products - ACS and Reagent Grade Solvents
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent by Application - Solvents
  4. ACS and Reagent Grade Solvents - Solvent by Application
  5. Reagent Grade Solvents - ACS and Reagent Grade Solvents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TA - TE - T
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TA - TE - T
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent Packaging Options - Solvents
  4. Semi-Bulk Solvents - Solvent Packaging Options
  5. Carbon Steel Cans with NPT Threads - Semi-Bulk Solvents
  6. Reagent - Carbon Steel Cans with NPT Threads
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents for HPLC & Spectrophotometry
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂