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分类

• {Chemicalbook} 农药中间体: 除草剂中间体: 取代脲类除草剂
• {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; isocyanate; 1fragment
• {SNA} Building Blocks, Chemical Synthesis, Isocyanates, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

• Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
• Short: IV/6 Title: Static Dielectric Constants of Pure Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch. Editor: Madelung, O. Source: Landolt-Börnstein, New Series Volume: IV/6 Year: 1991 Keyword: organic compounds; dielectric constant; liquids; mixtures ISBN: 3-540-54417-8 ISBN: 978-3-540-54417-3 Internet Resource: DOI:10.1007/b44266 RefComment: VIII, 521 pages.
• Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 975 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 20(3),53,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
RO

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 975 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 20(3),53,1976

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3300 mg/m3
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 20(3),53,1976

其他信息

• 可燃性危险特性:可燃; 燃烧产生有毒氟化物和氧化氮气体
• 用途一:3-三氟甲基苯基异氰酸酯是除草剂氟草隆的中间体。
• 毒性分级:中毒
• 3-(三氟甲基)异氰酸苯酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 I0340 异氰酸3-(三氟甲基)苯酯 3-(Trifluoromethyl)phenyl Isocyanate 5G 488元 2014/06/02 I0340 异氰酸3-(三氟甲基)苯酯 3-(Trifluoromethyl)phenyl Isocyanate 25G 1450元 2010/06/21 170350250 3-(三氟甲基)异氰酸苯酯 alpha,alpha,alpha-Trifluoro-m-tolyl isocyanate 98% 25 GR 1787元
• Alfa Aesar:3-(三氟甲基)异氰酸苯酯,98% 3-(Trifluoromethyl)phenyl isocyanate, 98%(329-01-1)
• 蒸气压:2.44 psi ( 20 °C)
• 存储注意事项:湿度敏感;氮气保护;热敏感
• F:10
• Acros Organics:alpha,alpha,alpha-三氟间甲苯异氰酸酯 alpha,alpha,alpha-Trifluoro-m-tolyl isocyanate, 98%(329-01-1)
• 类别:有毒物品
• MOL 文件:329-01-1.mol
• TCI Shanghai:3-三氟甲基异氰酸苯酯 3-(Trifluoromethyl)phenyl Isocyanate,>;96.0%(GC)(329-01-1)
• 图谱信息:3-(三氟甲基)异氰酸苯酯(329-01-1)核磁图( 1 HNMR) 3-(三氟甲基)异氰酸苯酯(329-01-1)Raman光谱 3-(三氟甲基)异氰酸苯酯(329-01-1)质谱(MS) 3-(三氟甲基)异氰酸苯酯(329-01-1)核磁图( 13 CNMR) 3-(三氟甲基)异氰酸苯酯(329-01-1)红外图谱(IR1)
• Sigma Aldrich:329-01-1(sigmaaldrich)
• 急性毒性:口服-大鼠 LD50: 975 毫克/公斤; 口服-小鼠 LD50: 975 毫克/公斤
• 上游原料:氢氧化钠 --> 盐酸 --> 乙酸乙酯 --> 四氢呋喃 --> 二氯甲烷 --> 三乙胺 --> 碳酸氢钠 --> 氮 --> 氯苯 --> 二(三氯甲基)碳酸酯 --> 间氨基三氟甲苯 --> 氯代异丁烷
• 用途二:主要用作医药，农药中间体。
• 方法一:其制备方法是在反应瓶中加入3-三氟甲基苯胺与氯苯搅拌，使其混合溶解，冷却至0～10℃，通入干燥氯化氢使其饱和，然后再加入N，N-二异丁基氯甲基酰胺，加热至50℃保温30 min，然后再通入光气，通入一定量光气后反应结束，通入氮气赶尽物料中的氯化氢和余量的光气，赶光后再将物料蒸馏并脱溶得成品。
• Hazard Note:Toxic/Lachrymatory/Keep Cold
• 储运特性:库房通风低温干燥; 与氧化剂, 酸类, 食品分开储运
• MSDS 信息:异氰酸三氟甲苯酯(329-01-1).msds
• 灭火剂:干粉, 砂土, 泡沫, 二氧化碳
• 外观性质:无色或淡黄色液体，具有刺激性气味。
• 敏感性:Lachrymatory