4-Nitrosodiphenylamine 4-亚硝基二苯胺
CAS 156-10-5 MFCD00002062
化学结构图
SMILES: O=Nc1ccc(Nc2ccccc2)cc1
化学属性
| Mol. Formula | C12H10N2O |
|---|---|
| Mol. Weight | 198.23 |
| Melting Point | 140.0 to 145.0 deg-C |
| Appearance | 绿色结晶。熔点144℃（分解）。易溶于乙醇、醚、氯仿、苯，微溶于水。 |
别名和识别编码
| Chemical Name | 4-Nitrosodiphenylamine |
|---|---|
| MDL Number | MFCD00002062 |
| CAS Number | 156-10-5 |
| PubChem Substance ID | 9074 |
| EC Number | 205-848-7 |
| Chemical Name Translation | 4-亚硝基二苯胺 |
| Synonym | 4-NITROSO-N-PHENYLANILINE 4-NITROSODIPHENYLAMINE 4-Niinylamine 4-Nitroso-N-phenylbenzenamine 4-nitroso-N-phenylaniline 4-nitroso-N-phenylaniline, monohydrochloride 4-nitroso-diphenylamin 4-nitroso-n-phenyl-benzenamin 4-亚硝基二苯基胺 4-亚硝基二苯胺 Diphenylamine, 4-nitroso- N-(4-Nitrosophenyl)-N-phenylamine N-Phenyl-p-nitrosoaniline NCI-C02244 Naugard tkb P-NITROSODIPHENYLAMINE diphenyl,4-nitroso-amin n-phenyl-para-nitrosoaniline naugardtkb nitrousdiphenylamide p-Nitroso-N-phenylaniline p-Nitrosodifenylamin p-nitroso-N-phenylaniline p-nitrosodifenylamin(czech) para-nitroso-N-phenylaniline para-nitroso-n-phenylaniline { |
| Reaxys-RN | 1952651 |
| Merck Number | 6639 |
| LabNetwork Molecule ID | LN00238197 |
| InChI | InChI=1S/C12H10N2O/c15-14-12-8-6-11(7-9-12)13-10-4-2-1-3-5-10/h1-9,13H |
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分类
- {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Nitroso Compounds, Organic Building Blocks
安全信息
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P302+P350
- P302+P352
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 204 gm/kg/57W-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors REFERENCE : NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD) No.0-205. For publisher information, see NTPTR*. Volume(issue)/page/year: NCI-TR-190,1979
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1365 gm/kg/78W-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors REFERENCE : IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 27,227,1982
其他信息
- 下游产品:对氨基二苯胺 --> 蓝色基 RT
- TCI Shanghai:4-亚硝基二苯胺 4-Nitrosodiphenylamine,>;95.0%(T)(156-10-5)
- 用途一:橡胶硫化促进剂。
- 方法一:将30g苯胺、30g硝基苯和120g干燥的氢氧化钠粉末混匀，加热至110-120℃，搅拌后变成稀液，再升温至120-125℃，反应液颜色变深并浓筒，当反应液固化时，反应即达终点。冷却，溶于热水，冷却，过滤，滤液通二氧化碳后滤出蓝黑色针状晶体。滤液再通二氧化碳，滤取第二批产物。合并两批产物，用乙醇重结晶，得纯品对业硝基二苯胺。
- MOL 文件:156-10-5.mol
- 4-亚硝基二苯基胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0263 4-亚硝基二苯胺 4-Nitrosodiphenylamine 25G 1130元 2010/06/21 214310050 4-亚硝基二苯基胺 4-Nitrosodiphenylamine 75%, tech. 5 GR 254元 2010/06/21 214311000 4-亚硝基二苯基胺 4-Nitrosodiphenylamine 75%, tech. 100 GR 579元
- Sigma Aldrich:156-10-5(sigmaaldrich)
- 上游原料:二氧化碳 --> 二苯胺
- Acros Organics:4-亚硝基二苯胺 4-Nitrosodiphenylamine, tech., 75%(156-10-5)
- 图谱信息:4-亚硝基二苯基胺(156-10-5)质谱(MS) 4-亚硝基二苯基胺(156-10-5)核磁图( 1 HNMR) 4-亚硝基二苯基胺(156-10-5)红外图谱(IR2) 4-亚硝基二苯基胺(156-10-5)核磁图( 13 CNMR) 4-亚硝基二苯基胺(156-10-5)红外图谱(IR1)
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