Dimethylarsinic Acid 二甲基砷

CAS 75-60-5 MFCD00002095

化学结构图

75-60-5
SMILES: C[As](C)(=O)O

化学属性

Mol. FormulaC₂H₇AsO₂
Mol. Weight138
Density1.1
Melting Point197 - 198°C
TSCAYes
Solubility溶于水，易溶于乙醇，溶于乙酸，不溶于乙醚。
Stability易吸湿
Boiling Point

别名和识别编码

Chemical NameDimethylarsinic Acid
CAS Number75-60-5
Synonym ANSAR(R) Acide cacodylique Acide dimethylarsinique Agent blue Ansar Ansar 138 Arsan Arsine oxide, hydroxydimethyl- Arsinic acid, dimethyl- As,As-Dimethylarsinic Acid Bolls-Eye CACODYLIC ACID Cacodylic Acid {} {} {} {} {TRC} NSC 71157 {} {} {} {} {} {} {} {} {} {} {TRC} NSC 711 {} {} {} {} {} {} {hazard_com} Kyselina kakodylova {} {} {} {} {} {} {} {uni_hamburg} Kakodylsäure {} {} {} {} {} {} {} {} {uni_hamburg} Hydroxydimethylarsine oxide {} {} {} {} {} {} {} {} {} {uni_hamburg} Hyd {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} HYDROXYDIMETHYLARSINE OXIDE {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} Dimethylarsinsäure {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {ALF} Dimethylarsinic aci
Beilstein Registry Number4,160
PubChem Substance ID87566105
EC Number200-883-4
MDL NumberMFCD00002095
Reaxys-RN1736965
Merck Number1604
Chemical Name Translation二甲基砷
Wiswesser Line NotationQ-AS-O&1&1
LabNetwork Molecule IDLN00194881
InChIInChI=1S/C2H7AsO2/c1-3(2,4)5/h1-2H3,(H,4,5)
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分类

  • Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Arsenic, Chromatography, D, DID - DIN, Environmental Standards, Herbicides, Pesticides & Metabolites
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Biological Buffers, Buffers A to Z

产品应用

  • 非选择性除草剂。

相关文献及参考

  • Short: III/35E
  • Mandal, B., et al.: Talanta, 58, 201 (2002),
  • Naranmandura, H., et al.: Chem. Res. Toxicol., 20, 616 (2007),
  • Short: III/20b
  • Merck: 14,1604 Beilstein:4,160
  • Short: III/10a
  • Merck: 14,1604
  • Naranmandura, H., et al.: Toxicol. Appl. Pharmacol., 227, 390 (2008),

安全信息

Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H331 Toxic if inhaled 吸入中毒
  • H301 Toxic if swallowed 吞食有毒
RTECSCH7525000
Signal word Danger Warning
GHS Symbol
Hazard Codes T,N
WGK Germany3
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P308+P313
  • P304+P340+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P301+P310
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P403+P233
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P304+P340+P311
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S20/21 When using do not eat, drink or smoke 使用时，不得进食，饮水或吸烟；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R50/53
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 1572 UN1572 UN 1572 6.1/PG 2
Storage condition 20 Hygroscopic Store at RT. 充氩储存
Packing GroupII
Hazard Class6.1
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 464 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1953-  Volume(issue)/page/year: 45,449,1997

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >2600 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   37,165,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 185 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,393,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD295-864

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 2 pph
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB84-138973

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Fibroblast
DOSE/DURATION           : 700 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 357,123,1996

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 7900 mg/kg/24H
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB84-138973

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 5 pph
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB268-647

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 1080 mg/L
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB84-138973

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 500 mg/kg
SEX/DURATION            : female 7-16 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   DCTODJ Drug and Chemical Toxicology.  (Marcel Dekker, 270 Madison Ave., New
   York, NY 10016) V.1-    1977/78-  Volume(issue)/page/year: 4,49,1981

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 300 mg/kg
SEX/DURATION            : female 7-16 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - craniofa

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 400 mg/kg
SEX/DURATION            : female 7-16 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   DCTODJ Drug and Chemical Toxicology.  (Marcel Dekker, 270 Madison Ave., New
   York, NY 10016) V.1-    1977/78-  Volume(issue)/page/year: 4,49,1981

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 1600 mg/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   5,3,1985

TYPE OF TEST

其他信息

  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 可燃性危险特性:受热分解有毒的砷化物气体
  • 毒性分级:中毒
  • 二甲次胂酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1072 二甲基胂酸 Cacodylic Acid 5G 288元 2014/06/02 C1072 二甲基胂酸 Cacodylic Acid 25G 981元 2010/06/21 318150500 二甲次胂酸 Cacodylic acid 98% 50 GR 3369元
  • TCI Shanghai:二甲基胂酸 Cacodylic Acid,>;98.0%(T)(75-60-5)
  • Acros Organics:二甲基胂酸 Cacodylic acid, 98%(75-60-5)
  • 外观性质:无色结晶，无臭，有吸湿性。
  • Sigma Aldrich:75-60-5(sigmaaldrich)
  • 刺激数据:皮肤-兔子2600毫克/立方米/2小时中度;眼睛-兔子2600毫克/立方米/2小时中度
  • 急性毒性:口服-大鼠 LD50: 644 毫克/公斤; 腹腔-小鼠 LD50: 500 毫克/公斤
  • Alfa Aesar:二甲次胂酸,98% Cacodylic acid, 98%(75-60-5)
  • MSDS 信息:羟基二甲基氧化胂(75-60-5).msds
  • 图谱信息:二甲次胂酸(75-60-5)质谱(MS) 二甲次胂酸(75-60-5)红外图谱(IR2) 二甲次胂酸(75-60-5)核磁图( 13 CNMR) 二甲次胂酸(75-60-5)红外图谱(IR1) 二甲次胂酸(75-60-5)核磁图( 1 HNMR)
  • F:3-10
  • 职业标准:TWA 0.2 毫克 (砷)/立方米; STEL 0.5 毫克 (砷)/立方米
  • MOL 文件:75-60-5.mol
  • 用途一:用于制药
  • 25℃时在水中溶解度为200g/100g,可溶于低碳醇。大鼠急性经口LD501350mg/kg,对家兔的皮肤和眼睛无刺激作用。制剂有可湿性粉剂,水溶性液剂及乳油。用于防除非作物地的杂草,用量10～15kg/ha。
  • 类别:有毒物品
  • 灭火剂:二氧化碳、砂土、水
  • 敏感性:Hygroscopic

系列性分类

  1. Life Science 生命科学
  2. Biological Buffers 生理缓冲剂
  3. Buffers A to Z - Biological Buffers
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Arsenic - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Acids - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids - Carbonyl Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DID - DIN - D
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物

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