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分类

• {SNA} Alphabetical
• {SNA} Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
• {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Q-Z, T, TP - TZ, 农残和代谢标准品, 按照字母排序
• {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Pesticides & Metabolites, Q-Z, T,

产品应用

• 用作杀霉菌剂、气相色谱对比样品。

相关文献及参考

• Merck: 14,9643 Beilstein:6(2)180
• Short: III/20a
• 2,4,5-Trichlorophenyl esters are more reactive than p-nitrophenyl esters in peptide coupling: Helv. Chim. Acta, 46, 1609 (1963); J. Chem. Soc., 6130 (1964). See Appendix 6.
• Merck: 14,9643
• Short: III/35D2

安全信息

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 6700 mg/kg/16W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   19,413,1959

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 820 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FEPRA7 Federation Proceedings, Federation of American Societies for
   Experimental Biology. (Bethesda, MD)  V.1-46, 1942-87.
   Volume(issue)/page/year: 2,76,1943

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03492

TYPE OF TEST            :

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C310,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 355 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
   Nutritional and Gross Metabolic - body temperature increase
REFERENCE :
   BJPCAL British Journal of Pharmacology and Chemotherapy.  (London, UK)
   V.1-33, 1946-68.  For publisher information, see BJPCBM.
   Volume(issue)/page/year: 13,20,1958

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 150 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 303,101,1993

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   TECSDY Toxicological and Environmental Chemistry.  (Gordon & Breach Science
   Pub. Inc., 1 Park Ave., New York, NY 10016)  V.3(3/4)-    1981-
   Volume(issue)/page/year: 14,143,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 4 gm/kg
SEX/DURATION            : female 8-12 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - live birth index (measured after birth)
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 10,541,1982

其他信息

• 可燃性危险特性:可燃; 燃烧释放有毒氯化物烟雾
• 方法一:将2,3,5,6-四氯苯、固碱、甲醇投入高压釜，控制温度在135-152℃，压力为0.5-1.4MPa，保持14h。将反应液冷至60℃，蒸馏回收甲醇，放出残液，冷却结晶，过滤。将结晶溶于水，加热至70℃，加入保险粉，调节pH=9.2-9.6，加入活性炭，于95℃脱色半小时。过滤，滤液冷至15℃以下，加盐酸至pH=2-3，滤取2,4,5-三氯酚，于45℃干燥得成品。
• 外观性质:无色针状结晶或灰色片状物，有强烈的苯酚气味。
• MOL 文件:95-95-4.mol
• 图谱信息:2,4,5-三氯苯酚(95-95-4)核磁图( 1 HNMR) 2,4,5-三氯苯酚(95-95-4)质谱(MS) 2,4,5-三氯苯酚(95-95-4)核磁图( 13 CNMR) 2,4,5-三氯苯酚(95-95-4)红外图谱(IR2) 2,4,5-三氯苯酚(95-95-4)红外图谱(IR1) 2,4,5-三氯苯酚(95-95-4)红外图谱(IR3)
• 有强烈的苯酚气味,不溶于水，溶于四氯化碳、醇、苯、醚。蒸汽压0.133kPa(72℃)
• TCI Shanghai:2,4,5-三氯苯酚 2,4,5-Trichlorophenol,>;95.0%(GC)(95-95-4)
• Sigma Aldrich:95-95-4(sigmaaldrich)
• 2,4,5-三氯苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0389 2,4,5-三氯苯酚 2,4,5-Trichlorophenol 500G 3890元 2014/06/02 T0389 2,4,5-三氯苯酚 2,4,5-Trichlorophenol 25G 423元 2010/05/25 43737 2,4,5-三氯苯酚, 95+% 2,4,5-Trichlorophenol, 96% 25g 382元
• 毒性分级:中毒
• 急性毒性:口服-大鼠 LD50: 820 毫克/公斤; 口服-小鼠LD50: 600 毫克/公斤
• 下游产品:六氯芬 --> 2,4,5-三氯苯基-Β-丙炔醚 --> 氯丙炔碘 --> 皮蝇磷
• Alfa Aesar:2,4,5-三氯苯酚,98+% 2,4,5-Trichlorophenol, 98%(95-95-4)
• 类别:农药
• MSDS 信息:2,4,5-三氯苯酚(95-95-4).msds
• 用途二:用作杀霉菌剂、气相色谱对比样品。
• 酚类单一化合物标准液
• 储运特性:库房通风低温干燥; 与酸类、氧化剂、食品添加剂分开存放
• 灭火剂:雾状水、泡沫、二氧化碳、砂土。
• 职业标准:TWA 0.5 毫克/立方米
• 用途一:可用于制备多种除草剂、杀虫剂、杀菌剂；作为抗菌和防腐剂，广泛用于制备粘合剂、橡胶制品及纺织工业的防腐乳液。它本身可用作消毒剂，它的钠盐也是杀菌剂和防腐剂，用于制造业和皮革工业；在医药上用于合成氯丙炔碘、灭菌酚等。
• 爆炸物危险特性:高温分解可爆炸
• 上游原料:氢氧化钠 --> 硫酸 --> 甲苯 --> 连二亚硫酸钠 --> 丙二醇 --> 四硼酸钠 --> 1,2,4,5-四氯苯 --> 1,2,3,5-四氯苯