Triphenyl phosphite 亚磷酸三苯酯

CAS 101-02-0 MFCD00003032

化学结构图

101-02-0
SMILES: c1ccc(OP(Oc2ccccc2)Oc2ccccc2)cc1

化学属性

Mol. FormulaC18H15O3P
Mol. Weight310
Density1.184
Refractive indexn20/D 1.59(lit.)
Vapor Density10.7 (vs air)
Boiling Point360
Vapor Pressure5 mmHg ( 205 °C)
Melting Point22-24
Flash Point206°C(lit.)
TSCAYes
Solubility不溶于水,溶于多数有机溶剂。
Stability对空气和湿度敏感

别名和识别编码

Chemical NameTriphenyl phosphite
CAS Number101-02-0
EC Number202-908-4
Beilstein Registry Number1079456
MDL NumberMFCD00003032
Synonym (PhO)3P P(OPh)3 Triphenoxyphosphine ADK Stab TPP EFED JP 360 Mellite 310 P 36 (stabilizer) Phenyl phosphite, (PhO)3P Phosclere T 36 Phosphorigsäuretriphenylester Phosphorous acid triphenyl ester Phosphorous acid, triphenyl ester Stabilizer P 36 Sumilizer TPP-R TPP (plasticizer) Triphenoxyphosphine Triphenylphosphit Tris(phenoxy)phosphine Weston TPP
PubChem Substance ID7540
Reaxys-RN1079456
Chemical Name Translation亚磷酸三苯酯
Wiswesser Line NotationROPOR&OR
LabNetwork Molecule IDLN00200476
InChIInChI=1S/C18H15O3P/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h1-15H
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分类

  • {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphite Ligands

产品应用

  • 螯合剂,广泛用于各种PVC制品中,能使制品保持其透明度并能抑制颜色的变化,同时它可增加主稳定剂的抗氧性和光、热稳定性。另外,本品还用于PE、PP、ABS、SBS等制品中,并可作农药中间体。合成醇酸树脂和聚酯和聚酯树脂的原料。

相关文献及参考

  • Short: III/35E
  • Short: IV/18A
  • Short: III/38A
  • Beilstein:6,177

安全信息

Signal word Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R50/53
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
RTECSTH1575000
Packing GroupIII
UN Number 3077 3082 UN3077
Storage condition Air & Moisture Sensitive 密封干燥保存。
Hazard Codes 9
Hazard Class9
Warnings 危化品目录(2015)
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0532280

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - spastic paralysis with or without sensory
   change
   Behavioral - somnolence (general depressed activity)
   Behavioral - tremor
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0570901

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Behavioral - ataxia
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0532280

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Pr

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1490 mg/k

Restrict 危险品

其他信息

  • 对湿敏感,遇潮气水解生成游离酚。能与醇、醚、苯和丙酮和等有机溶剂混溶,不溶于水。对紫外线有吸收作用,有刺激性

系列性分类