Hexacarbonylmolybdenum 六羰基钼
CAS 13939-06-5 MFCD00003466
化学结构图
SMILES: [Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
化学属性
| Boiling Point | 156 |
|---|---|
| Density | 1.960 |
| TSCA | Yes |
| Vapor Density | 9.1 (vs air) |
| Solubility | 不溶 |
| Mol. Formula | Mo(CO)6 |
| Mol. Weight | 264 |
| Appearance | white xtl. |
| Melting Point | 150-151°C dec. |
别名和识别编码
| Chemical Name | Hexacarbonylmolybdenum |
|---|---|
| Synonym | Mo(CO)6 Hexacarbonylmolybdenum(0) 六羰基钼 羰化鉬 MOLYBDENUM HEXACARBONYL, SUBLIMED, 99.9& NSC 215198 Molybdenum carbonyl (Mo2(CO)12) Molybdäncarbonyl Molybdenumhexacarbonyl MOLYBDENUM ( Molybdenumcarbonyl(Mo(CO)6) Molybdänhexacarbonyl Hexacarbonylmolybdenum Molybdenum hexacarbonyl (Mo(CO)6) Molybdaenhexacarbonyl Molybdenumcarbonyl,98% MOLYBDENUM HEXACARBONYL Molybdaencarbonyl (OC-6-11)-Molybdenumcarbonyl Molybdenumhexacarbonyl(Mo(CO)6) Molybdenum hexacarbonyl MOLYBDENUM CARBONYL Molybdenum carbonyl (Mo(CO)6), (OC-6-11)- Molybdenumcarbonyl(Mo(CO)6),(OC-6-11)- |
| PubChem Substance ID | 329766468 |
| EC Number | 237-713-3 |
| Chemical Name Translation | 六羰基钼 |
| MDL Number | MFCD00003466 |
| CAS Number | 13939-06-5 |
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分类
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Molybdenum, Vapor Deposition Precursors
- {uni_hamburg} n
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Molybdenum
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis,
相关文献及参考
- Short: III/35D5
- Short: II/25D
- Catalyst and reagent in a variety of applications. Alternative to Octacarbonyldicobalt, 13060 for the Pauson-Khand [2 + 2 + 1] cycloaddition of an alkyne, an alkene and carbon monoxide to form a cyclopentenone: Tetrahedron Lett., 34, 4027 (1993); Org. Lett., 7, 431 (2005). For a brief survey of uses in synthesis, see: Synlett, 1195 (2005).
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安全信息
GHS Symbol
- H300+H310+H330
- H330 Fatal if inhaled 吸入致命
- H310 Fatal in contact with skin 皮肤接触致命
- H300 Fatal if swallowed 吞食致命
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P302+P350
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P301+P310
- S22 Do not breathe dust 不要吸入粉尘；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
- R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
其他信息
- Sigma Aldrich:13939-06-5(sigmaaldrich)
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