(3-Phenoxyphenyl)methanol 3-苯氧基苄醇

CAS 13826-35-2 MFCD00004636

化学结构图

13826-35-2
SMILES: OCC1=CC(=CC=C1)OC1C=CC=CC=1

化学属性

Mol. FormulaC13H12O2
Mol. Weight200
Refractive index1.5910 to 1.5940
Boiling Point300°C(lit.)
Vapor Pressure0.1 mmHg ( 37.7 °C)
Density1.149
Flash Point186°(366°F)
Solubility不溶
TSCAYes
Melting Point4-7°
Appearance 1.5935，相对密度 1.1456，不溶于水，溶于苯、甲苯、乙醇等溶剂。 20 D 本品为无色油状液体，b.p.135～140℃/13.3pa，n

别名和识别编码

Chemical Name(3-Phenoxyphenyl)methanol
PubChem Substance ID87575093
EC Number237-525-1
Beilstein Registry Number6(3)4545
MDL NumberMFCD00004636
Synonym Phenoxybenzyl alcohol M-PHENOXYBENZYL ALCOHOL 间苯氧基苯甲醇 3-phenoxybenzyl 3-PBA m-phenoxy-benzylalcoho m-Phenoxybenzyl alcohol benzenemethanol,3-phenoxy-, 3-苯氧基苄基醇 3-苯氧基苯甲醇 间苯氧苄醇 Benzyl alcohol, m-phenoxy- 3-phenoxy-benzenemethano m-Phenoxy Benzalcohol 3-Phenoxy Benzalcohol 3-PhenoxyBenzalcohol 3-苯氧苄醇 3-苯氧基苄醇; 3-苯氧基苯甲醇 RARECHEM AL BD 0058 3-Phenoxybenzenemethanol 3-PHENOXYBENZYL ALCOHOL 3-(HYDROXYMETHYL)DIPHENYL ETHER HYDROXYMETHYLDIPHENYL m-Phenoxy Benzalcohol
CAS Number13826-35-2
Reaxys-RN475312
Chemical Name Translation3-苯氧基苄醇
LabNetwork Molecule IDLN00221267
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分类

  • {Chemicalbook} 农药中间体: 杀虫剂中间体: 拟除虫菊酯类杀虫剂
  • {SNA} Alcohols, Building Blocks, C11 to C30+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
  • {SA} Alcohols, Building Blocks, C11 to C30+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Beilstein:6(3)4545

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSDP0775400
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P305+P351+P338+P337+P313
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
Signal word
Hazard Codes
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
UN Number
Packing GroupIII 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 10 gm/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Behavioral - ataxia
   Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0537669

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 575 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1953-  Volume(issue)/page/year: 25,9,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2040 mg/kg
TOXIC EFFECTS :
   Brain and Coverings - other degenerative changes
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 35(1),47,1991

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >2 gm/m3/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Sci

其他信息

  • 蒸气压:0.1 mm Hg ( 37.7 °C)
  • Acros Organics:3-苯氧基苄醇 3-Phenoxybenzyl alcohol, 98%(13826-35-2)
  • Sigma Aldrich:13826-35-2(sigmaaldrich)
  • TCI Shanghai:3-苯氧基苯甲醇 3-Phenoxybenzyl Alcohol,>;97.0%(GC)(13826-35-2)
  • MOL 文件:13826-35-2.mol
  • 不溶于水。
  • 3-苯氧基苄醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 P0979 3-苯氧基苯甲醇 3-Phenoxybenzyl Alcohol 25G 549元 2011/04/16 P0979 3-苯氧基苯甲醇 3-Phenoxybenzyl Alcohol 500G 3680元 2010/06/21 183771000 3-苯氧基苄醇 3-Phenoxybenzyl alcohol 98% 100 GR 2222元
  • 用途二:间苯氧基苄醇是氯菊酯、苯醚菊酯和醚菊酯等杀虫剂的中间体。
  • Hazard Note:Irritant
  • 上游原料:乙醇 --> 氢氧化钠 --> 氢氧化钾 --> 苯 --> 氢化铝锂 --> 甲醛 --> 甲酸钠 --> 间苯氧基苯甲醛 --> 苯甲酸苄酯 --> 3-苯氧基苯甲酸 --> 3-苯氧基苄氯
  • 下游产品:溴氰菊酯 --> 氯氰菊酯 --> 高效氯氟氰菊酯 --> 三苯氧基苯甲醛 --> 乙氰菊酯 --> 杀虫菊酯 --> 四溴菊酯,溴氯氰聚酯 --> 氯醚菊酯 --> 氟胺氰菊酯 --> S-Α-氰基-3-苯氧基苄醇
  • Alfa Aesar:3-苯氧基苄基醇,98% 3-Phenoxybenzyl alcohol, 98%(13826-35-2)
  • 图谱信息:3-苯氧基苄醇(13826-35-2)核磁图( 1 HNMR) 3-苯氧基苄醇(13826-35-2)Raman光谱 3-苯氧基苄醇(13826-35-2)核磁图( 13 CNMR) 3-苯氧基苄醇(13826-35-2)质谱(MS) 3-苯氧基苄醇(13826-35-2)红外图谱(IR1)
  • 方法一:间苯氧基苄醇是由间苯氧基苯甲醛和甲醛在浓碱存在下进行康尼查罗反应，分别得到间苯氧基苄醇和甲酸钠，进行分离等后处理，蒸馏得到产品。 间苯氧基苄醇也可以用间苯氧基苯甲酸酯经氢化铝锂还原、间苯氧基苯甲醛催化加氢还原、间苯氧基氯苄进行水解或与乙酸钠反应生成相应的乙酸酯，再进行水解等方法均能制备产品。
  • 用途一:用作农药、医药中间体

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Alcohols - Oxygen Compounds
  6. C9 to C10 - Alcohols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Alcohols - Oxygen Compounds
  6. C11 to C30+ - Alcohols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Aromatic alcohols 芳香醇

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