3-Bromophenyl Isothiocyanate 3-溴苯基异硫氰酸酯

CAS 2131-59-1 MFCD00004803

化学结构图

2131-59-1
SMILES: S=C=Nc1cccc(Br)c1

化学属性

Mol. FormulaC7H4BrNS
Mol. Weight214.08 g/mol
Boiling Point256 °C(lit.)
Refractive index1.6850
Flash Point>110°(230°F)
TSCANo
Density1.50

别名和识别编码

Chemical Name3-Bromophenyl Isothiocyanate
CAS Number2131-59-1
Alfabeta NameBROMOPHENYLISOTHIOCYANATE 3-
MDL NumberMFCD00004803
PubChem Substance ID87571872
EC Number000-000-0
Beilstein Registry Number12(3)1427
Synonym 1-Bromo-3-isothiocyanatobenzene 1-bromo-3-isothiocyanato-benzen 3-BROMOPHENYL ISOTHIOCYANATE 3-BROMOPHENYL ISOTHIOCYANATE 97% 3-Bromophenyl Isothiocyanate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Reaxys-RN2081173
Chemical Name Translation3-溴苯基异硫氰酸酯
InChIKeyZMGMGHNOACSMQN-UHFFFAOYSA-N
InChIInChI=1S/C7H4BrNS/c8-6-2-1-3-7(4-6)9-5-10/h1-4H
LabNetwork Molecule IDLN00115806
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiocyanates/Isothiocyanates

安全信息

Warnings MOISTURE SENSITIVE, LACHRYMATOR, CORROSIVE
WGK Germany3
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下,戴呼吸防护。
  • P301+P312
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P312
  • P304+P340
  • P304+P340+P310
  • P304+P340+P312
  • P304+P341
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P342+P311
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H302+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSNX8350000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Packing GroupIII
UN Number 1759 2810 UN2922
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R42 May cause sensitisation by inhalation 吸入会产生过敏反应
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Storage condition Moisture Sensitive
Hazard Codes Xn Xn,C
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#01285

其他信息

  • 图谱信息:异硫氰的3-溴苯酯(2131-59-1)红外图谱(IR1) 异硫氰的3-溴苯酯(2131-59-1)质谱(MS) 异硫氰的3-溴苯酯(2131-59-1)核磁图( 13 CNMR) 异硫氰的3-溴苯酯(2131-59-1)核磁图( 1 HNMR)
  • Sigma Aldrich:2131-59-1(sigmaaldrich)
  • Acros Organics:异硫氰酸3-溴苯酯 3-Bromophenyl isothiocyanate, 97%(2131-59-1)
  • Alfa Aesar:3-溴异硫氰酸苯酯,97% 3-Bromophenyl isothiocyanate, 97%(2131-59-1)
  • MOL 文件:2131-59-1.mol
  • 异硫氰的3-溴苯酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 I0524 异硫氰酸3-溴苯酯 3-Bromophenyl Isothiocyanate 5G 443元 2014/06/02 I0524 异硫氰酸3-溴苯酯 3-Bromophenyl Isothiocyanate 25G 1440元 2010/06/21 S04141EA 异硫氰的3-溴苯酯 3-bromophenyl isothiocyanate 10 GR 630元
  • TCI Shanghai:3-溴苯基异硫氰酸酯 3-Bromophenyl Isothiocyanate,>;95.0%(GC)(2131-59-1)
  • 敏感性:Moisture Sensitive

系列性分类


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