乙基乙酸丙烯酯 乙基乙酸丙烯酯

CAS 542-85-8 MFCD00004820

化学结构图

542-85-8
SMILES: CCN=C=S

化学属性

Mol. FormulaCH3CH2NCS
Mol. Weight87
Density0.995
Refractive index1.5100 to 1.5150
Boiling Point132°C
Melting Point-6
Flash Point24°C(lit.)
TSCAYes
Solubility不溶于水。

别名和识别编码

Chemical Name乙基乙酸丙烯酯
Synonym 乙基芥子油 isothiocyanato-ethan ISOTHIOCYANIC ACID ETHYL ESTER 95+% AKOS BBS-00004372 Ethylsenföl Ethylisothiocyanat 异硫氰酸乙酯 Ethyl isithiocyanate Ethyl mustard oil isothiocyanatoethane 異硫氰酸乙酯 Isothiocyansäureethylester ethyl isorhodanate ethyl isorhoda 乙芥子油 ISOTHIOCYANIC ACID ETHYL ESTER Ethylisothiocyanate,97% Äthylisothiocyanat Ethyl isothiocyanate Isothiocyanatoethane ISOTHIOCYANATOETHANE isothiocyanato-ethane 乙基异硫氰酸酯 ethyl isothiocyanate 1-Isothiocyanatoethane Isothiocyanic acid, ethyl ester Ethane, isothiocyanato-
MDL NumberMFCD00004820
CAS Number542-85-8
EC Number208-831-2
Beilstein Registry Number4,123
PubChem Substance ID10966
Merck Number3815
Chemical Name Translation乙基乙酸丙烯酯
Reaxys-RN1737705
Wiswesser Line NotationSCN2
LabNetwork Molecule IDLN00007832
InChIInChI=1S/C3H5NS/c1-2-4-3-5/h2H2,1H3
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分类

  • {SNA} Armoracia rusticana (Horseradish), Building Blocks, Chemical Synthesis, Nutrition Research, Organic Building Blocks, Phytochemicals by Plant (Food/Spice/Herb), Sulfur Compounds, Thiocyanates/Isothiocyanates
  • {SNA} Armoracia rusticana (Hor
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alphabetical Listings, E-F, Flavors and Fragrances
  • {SNA} Armoracia rusticana (Horseradish), Building Blocks, Cell Biology, Chemical Synthesis, Nutrition Research,
  • {SNA} Armoracia rusticana (Horseradish), Building Blocks, Chemical Synthesis, Nutrition Research, Organic Building Blocks, Phytochemicals by Plant (Food/Spice/Herb), Sulfur Compounds, Thiocyanates/Isothiocyanates, 细胞生物学

相关文献及参考

  • Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
  • Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
  • Short: II/19c Title: Molecular Constants: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Constants of Diamagnetic Molecules Author: Demaison, J.; Hüttner, W.; Tiem

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R42/43
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R42 May cause sensitisation by inhalation 吸入会产生过敏反应
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P337+P313
  • P403+P233
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P302+P352+P333+P313+P362+P364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P305+P351+P338+P337+P313
  • P241+P242+P243
  • P301+P310+P330
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H301 Toxic if swallowed 吞食有毒
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSNX8590000
Packing GroupIII
UN Number UN2929 1992
Storage condition Moisture Sensitive Flammables area
Hazard Codes T,N
Hazard Class3/6.1
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   ABCHA6 Agricultural and Biological Chemistry.  (Maruzen Co. Ltd., POB 5050,
   Tokyo International, Tokyo 100-31, Japan)  V.25-    1961-
   Volume(issue)/page/year: 44,3017,1980

其他信息

  • 用途一:用于制药和杀虫剂。
  • Alfa Aesar:异硫氰酸乙酯,97% Ethyl isothiocyanate, 97%(542-85-8)
  • 图谱信息:乙基乙酸丙烯酯(542-85-8)红外图谱(IR1)
  • Sigma Aldrich:542-85-8(sigmaaldrich)
  • MOL 文件:542-85-8.mol
  • MSDS 信息:异硫氰酸乙酯(542-85-8).msds
  • 乙基乙酸丙烯酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 I0188 异硫氰酸乙酯 Ethyl Isothiocyanate 25ML 327元 2014/06/02 I0188 异硫氰酸乙酯 Ethyl Isothiocyanate 500ML 2710元 2010/06/21 376860050 乙基乙酸丙烯酯 Ethyl isothiocyanate 96% 5 GR 332元
  • 下游产品:头孢替安
  • TCI Shanghai:异硫氰酸乙酯 Ethyl Isothiocyanate,>;95.0%(GC)(542-85-8)
  • 外观性质:无色油状液体。
  • 敏感性:Moisture Sensitive
  • Acros Organics:异氰酸乙酯 Ethyl isothiocyanate, 96%(542-85-8)

系列性分类


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