Phenylphosphonothioic Dichloride 苯基硫代膦酰二氯

CAS 3497-00-5 MFCD00004916

化学结构图

3497-00-5
SMILES: S=P(Cl)(Cl)C1CCCCC1

化学属性

Mol. FormulaC6H5Cl2PS
Mol. Weight211.04
Refractive index1.6230 to 1.6260
Density1.43
Flash Point118 ºC
Boiling Point270°C(lit.)

别名和识别编码

Chemical NamePhenylphosphonothioic Dichloride
MDL NumberMFCD00004916
CAS Number3497-00-5
Reaxys-RN971247
PubChem Substance ID19016
Synonym AURORA KA-1408 BENZENE PHOSPHORUS THIODICHLORIDE Benzene phosphorus thiodichloride Benzene phosphorus thiodichloride,Phenyl phosphorus thiodichloride DICHLOROPHENYL PHOSPHINE SULFIDE Dichloro(phenyl)phosphine sulfide Dichloro(phenyl)phosphine sulphide Dichlorophenylphosphine sulfide PHENYL THIONO PHOSPHONYL CHLORIDE PHENYLPHOSPHONOTHIOIC DICHLORIDE PHENYLTHIOPHOSPHONIC DICHLORIDE Phenyl phosphorus thiodichloride Phenylphosphonothionodichloridate Phenylphosphonothioyl dichloride Phenylphosphorthiodichlorid Phenylthionophosphonic dichloride Phenylthiophosphonsäuredichlorid Phenylthiophosphonyl dichloride Phenylthiophosphoryl chloride Phosphine sulfide, dichlorophenyl- Phosphonodichloridothioic acid, phenyl- Phosphonothioic dichloride, phenyl- dichloro(phenyl)phosphine sulphide dichloro(phenyl)phosphinesulphide phenyl-phosphonothioic acid dichloride phenyl-phosphonothioicdichlorid phenyl-thiophosphonic acid-dichloride phenylphosphonothioic dichloride phenylphosphonothioyldichloride phenylphosphorusthiodichloride phenylthionophosphonic dichloride phenylthionophosphonicdichloride phenylthiophosphonyldichloride 苯基硫代磷酰二氯 苯硫代二氯化膦 苯硫代磷酰二氯
EC Number222-494-9
Chemical Name Translation苯基硫代膦酰二氯
LabNetwork Molecule IDLN01325765
InChIInChI=1S/C6H5Cl2PS/c7-9(8,10)6-4-2-1-3-5-6/h1-5H
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphonates/Phosphinates, Phosphorus Compounds
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume:
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.

安全信息

UN Number 2799 3265
Signal word Danger
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302+H312+H332
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P304+P340
  • P304+P340+P310
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P305+P351+P338
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Hazard Class8
GHS Symbol
Packing GroupII
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Warnings 危化品目录(2015) 危险化学品
WGK Germany3
Hazard Codes C

其他信息

  • MOL 文件:3497-00-5.mol
  • 可燃性危险特性:可燃; 遇水分解有毒氯化物气体; 燃烧产生有毒氯化物, 磷氧化物和硫氧化物烟雾
  • 灭火剂:砂土、二氧化碳
  • 类别:腐蚀物品
  • MSDS 信息:苯硫代磷酰二氯(3497-00-5).msds
  • TCI Shanghai:苯基硫代膦酰二氯 Phenylthiophosphonic Dichloride,>;98.0%(T)(3497-00-5)
  • 苯基硫代磷酰二氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1245 苯基硫代膦酰二氯 Phenylthiophosphonic Dichloride 500G 2330元 2014/06/02 P1245 苯基硫代膦酰二氯 Phenylthiophosphonic Dichloride 25G 319元
  • 外观性质:无色液体, 在空气中微发烟。
  • 图谱信息:苯基硫代磷酰二氯(3497-00-5)质谱(MS) 苯基硫代磷酰二氯(3497-00-5)核磁图( 1 HNMR) 苯基硫代磷酰二氯(3497-00-5)红外图谱(IR1) 苯基硫代磷酰二氯(3497-00-5)核磁图( 13 CNMR)
  • 储运特性:库房通风低温干燥; 与氧化剂、酚、醇、胺分开存放

系列性分类


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