Ethylene Sulfide 环硫乙烷

CAS 420-12-2 MFCD00005159

化学结构图

420-12-2
SMILES: C1CS1

化学属性

Mol. FormulaC2H4S
Mol. Weight60
Refractive index1.4930 to 1.4950
Boiling Point56°C
Density1.01 g/mL at 25 °C(lit.)
Vapor Pressure4.15 psi ( 20 °C)
Flash Point10 ºC
Melting Point207-209 ºC

别名和识别编码

Chemical NameEthylene Sulfide
Synonym ETHYLENE SULFIDE Thiirene, 2,3-dihydro- thiacyclopropane 環硫乙烷 thiirane Ethylensulfid Ethylene episulfide 2,3-dihydro-thiiren Ethylene sulfide; Ethylene episulfide; NSC 89690; Thiacyclopropane; 2,3-Dihydrothiirene 噻喃 ethyleneepisulphide 噻丙烷 dimethylene sulfide ethylenesulphide 2,3-Dihydrothiirene Ethylene sulphide epithioethane THIIRANE ethyleneepisulfide DIMETHYLENE SULFIDE Ethylene episulphide Thiacyclopropane Sulfurane ethylene sufide 环硫乙烷 Aethylensulfid Tyyranen thiiran Dimethylene sulfide, Thiirane Thiirane Ethylene Sulfide (stabilized with Butyl Mercaptan) 硫化伸乙基 aethylensulfid ETHYLENE SULFIDE, STAB. 噻丙烷 硫化伸乙基
CAS Number420-12-2
PubChem Substance ID87569430
EC Number206-993-9
Beilstein Registry Number17(2)12
MDL NumberMFCD00005159
Reaxys-RN102379
Chemical Name Translation环硫乙烷
Wiswesser Line NotationT3STJ
LabNetwork Molecule IDLN00162978
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfides/Disulfides, Sulfur Compounds
  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfides/Disulfides, Sulfur Compounds
  • {uni_hamburg} no charge; sulfur heterocycle; alicycle; 3ring; sulfide; 1fragment

相关文献及参考

  • Beil. 17 ,V,1,9
  • Fieser 1 ,378
  • Aldrich MSDS 1 , 905:D / Corp MSDS 1 (1), 1612:C / FT-IR 2 (1), 433:B / FT-IR 1 (1), 269:D / FT-NMR 1 (1), 433:A / IR-Spectra (2), 142:D / IR-Spectra (3), 159:A / NMR-Reference 2 (1), 231:C / RegBook 1 (1), 287:L / Sax 6 , 1348 / Structure Index 1 , 40:B:1 / Vapor Phase 3 , 354:C
  • Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
  • Short: II/22b Title: Theoretical Structures of Molecules: Small Rings Author: Hampel, F. Editor: von Ragué Schleyer, P. Source: Landolt-Börnstein, New Series Volume: II/22b Year: 1994 ISBN: 3-540-56332-6 ISBN: 978-3-540-56332-7 Internet

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,T
Hazard statements
  • H301+H331
  • H318 Causes serious eye damage 严重伤害眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECSKX3500000
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P310
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P403+P233
  • P305+P351+P338+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
Signal word Danger
UN Number UN 1992 3/PG 2 1992
Storage condition <;0 <0°C Freezer
Packing GroupII
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Hazard Class3/6.1
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 400 mg/kg/50W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   ZEKBAI Zeitschrift fuer Krebsforschung.  (Berlin, Fed. Rep. Ger.)  V.1-75,
   1903-71.  For publisher information, see JCROD7.  Volume(issue)/page/year:
   74,241,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 42 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   25,560,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 35600 ug/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Behavioral - ataxia
   Behavioral - muscle contraction or spasticity
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 13(8),47,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 178 mg/kg
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Lungs, Thorax, or Respiration - structural or functional change in trachea
   or bronchi
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   25,560,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 36 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than

其他信息

  • Sigma Aldrich:420-12-2(sigmaaldrich)
  • 蒸气压:4.15 psi ( 20 °C)
  • 图谱信息:环硫乙烷(420-12-2)质谱(MS) 环硫乙烷(420-12-2)红外图谱(IR1) 环硫乙烷(420-12-2)核磁图( 1 HNMR) 环硫乙烷(420-12-2)核磁图( 13 CNMR)
  • F:10-13-23
  • MOL 文件:420-12-2.mol
  • 环硫乙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0133 环硫乙烷(含稳定剂丁硫醇) Ethylene Sulfide (stabilized with Butyl Mercaptan) 10G 623元
  • TCI Shanghai:环硫乙烷 Ethylene Sulfide (stabilized with Butyl Mercaptan),>;98.0%(GC)(420-12-2)

系列性分类


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