2-Imidazolidinone 2-咪唑烷酮

CAS 120-93-4 MFCD00005257

化学结构图

120-93-4
SMILES: O=C1NCCN1

化学属性

Mol. FormulaC3H6N2O
Mol. Weight86
Density1.422
Melting Point129-132
Flash Point265 ºC
Solubility可溶

别名和识别编码

Chemical Name2-Imidazolidinone
CAS Number120-93-4
Alfabeta NameIMIDAZOLIDONE 2-
MDL NumberMFCD00005257
EC Number204-436-4
Beilstein Registry Number106252
Synonym 1,3-Ethyleneurea 2-IMIDAZOLIDINONE 2-Imidazolidinone; 2-Imidazolidone 2-Oxoimidazolidine 2-oxomidazolidine 2-咪唑啉酮二酮 半水合物, 98+% 2-咪唑烷酮 2-四氫咪唑酮 3-IMIDAZOLIDINONE ETHYLENEUREA Ethylene urea Ethylenurea Imidazolid-2-one Imidazolidin-2-on Imidazoline-2-one N,N'-ETHYLENEUREA N,N-Ethyleneurea N,N-Ethylenurea N,N′-Ethyleneurea SD 6073 Urea, 1,3-ethylene- imidazolidine-2-one n,n\’-(1,2-ethanediyl)-ure sd6073 乙撑脲 乙烯脲 亚乙基脲 伸乙脲 尿乙烯 环亚乙基脲 环亚乙烯脲
PubChem Substance ID8453
Chemical Name Translation2-咪唑烷酮
Reaxys-RN106252
Merck Number4914
Wiswesser Line NotationT5MVMTJ
LabNetwork Molecule IDLN00173167
InChIInChI=1S/C3H6N2O/c6-3-4-1-2-5-3/h1-2H2,(H2,4,5,6)
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分类

  • {SNA} Bioactive Small Mole
  • {SNA} Analytical Standards, H-M, Insecticides, Neonicotinoids, Other Insecticides, Pesticide Class, 农残和代谢标准品, 农残,疑似对蜜蜂有害, 分析/色谱, 按照字母排序
  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, H-M, I, Insecticides, Neonicotinoids, Others, Pesticide Class, Pesticides, Pesticides & Metabolites, Pesticides, suspected to harm bees
  • {SNA} Analytical Standards,
  • {SNA} Building Blocks,

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
RTECSNJ0570000
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Storage condition Store at RT.
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1000 mg/kg
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique.
   (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France)
   V.9-    1974-  Volume(issue)/page/year: 17,235,1982

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 15 mg/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - male fertility index (e.g. # males impregnating
   females per # males exposed to fertile nonpregnant females)
REFERENCE :
   85GUAJ "Antifertility Compounds in the Male and Female," Jackson, H.,
   Springfield, IL, Charles C. Thomas, 1966  Volume(issue)/page/year: -,37,1966

其他信息

  • 用途二:用作甲醛捕获剂,去除经2D-树脂、KB树脂、脲醛树酯、三聚氰胺甲醛树脂等整理后织物中残存的甲醛。该品也用作精细化学品的中间体,用于制造树脂、增塑剂、喷漆、胶粘剂等。
  • 用途三:2-咪唑烷酮【120-93-4】作为美洛西林钠,阿洛西林钠(azlocillin sodium)的中间体,以及抗血吸虫病、杀虫剂的原料,在印染工业中作为脱醛剂等。 降低自硬树脂里游离甲醛的含量,祛除织物甲醛
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • MSDS 信息:Ethyleneurea(120-93-4).msds
  • 2-咪唑烷酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 I0005 2-咪唑烷酮 2-Imidazolidinone 500G 723元 2014/06/02 I0005 2-咪唑烷酮 2-Imidazolidinone 25G 137元
  • 可燃性危险特性:燃烧产生有毒氮氧化物气体
  • 检测方法:GC
  • TCI Shanghai:2-咪唑烷酮 2-Imidazolidinone,>;97.0%(N)(120-93-4)
  • 毒性分级:中毒
  • 下游产品:柔软剂 VS --> 2-咪唑啉酮半水合物
  • Sigma Aldrich:120-93-4(sigmaaldrich)
  • 用途一:用作甲醛捕获剂,精细化学品的中间体,也用于制树脂和配制增塑剂、喷漆、胶粘剂等
  • MOL 文件:120-93-4.mol
  • 图谱信息:2-咪唑烷酮(120-93-4)核磁图( 13 CNMR) 2-咪唑烷酮(120-93-4)红外图谱(IR1) 2-咪唑烷酮(120-93-4)质谱(MS)
  • 灭火剂:干粉、泡沫、砂土
  • 急性毒性:腹注- 小鼠 LD50: 500 毫克/ 公斤
  • 方法一:由乙二胺与二氧化碳热压反应而得。也可将乙二胺、尿素和水进行缩合闭环制得该品。
  • 外观:白色至浅黄色结晶粉末或无色针状结晶。
  • 上游原料:乙二胺
  • 类别:农药

系列性分类


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